N-十二烷基聚氧乙烯醚(3)基-N,N-二甲基叔胺的CO2开关响应性能研究

doi:10.13218/j.cnki.csdc.2015.05.001

摘要/Abstract

摘要： 为获得耐无机盐的开关型表面活性剂,研究了在长链烷基和叔胺基之间嵌插聚氧乙烯(EO)片段的N-十二烷基聚氧乙烯醚(3)基-N,N-二甲基叔胺(C₁₂EO₃A)的CO₂开关响应性能。电导率和荧光探针实验结果表明C₁₂EO₃A具有明显的CO₂开关响应性能;与结构相近的N-十二烷基-N,N-二甲基叔胺碳酸氢盐([C₁₂AH]⁺HCO₃^-)相比,C₁₂EO₃A碳酸氢盐([C₁₂EO₃AH]⁺HCO₃^-)的临界胶束浓度更小,在饱和NaCl水溶液中仍可发挥出色的表面活性剂功能。

关键词: 开关型表面活性剂, CO₂响应, 乙氧基化叔胺, 耐盐性

Abstract: In order to obtain a switchable surfactant that has inorganic salt tolerance,CO₂-switching responsive performance of N-dodecyl polyoxyethylene (3)-N,N-dimethyl tertiary amine (C₁₂EO₃A),embedded with polyoxyethylene (EO) segment between the long-chain alkyl group and tertiary amino group was investigated.Results from conductivity test and uorescence probe test showed that C₁₂EO₃A displays conspicuous CO₂-swiching responsive efficacy.Comparing with bicarbonate of N-dodecyl-N,N-dimethyl tertiary amine ([C₁₂AH]⁺HCO₃^-),with bicarbonate of C₁₂EO₃A ([C₁₂EO₃AH]⁺HCO₃^-) that has similar structure,critical micelle concentration of the latter is smaller,and shows outstanding surfactant functions even in saturated NaCl aqueous solution.

Key words: switchable surfactant, CO₂-responsive, ethoxylated tertiary amine, salt tolerance

中图分类号:

TQ423

王铖, 张永民, 刘雪锋. N-十二烷基聚氧乙烯醚(3)基-N,N-二甲基叔胺的CO₂开关响应性能研究[J]. 日用化学工业, 2015, 45(5): 241-246.

WANG Cheng, ZHANG Yong-min, LIU Xue-feng. CO₂-switching responsive performance of N-dodecyl polyoxyethylene (3)-N,N-dimethyl tertiary amine[J]. China Surfactant Detergent & Cosmetics, 2015, 45(5): 241-246.

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N-十二烷基聚氧乙烯醚(3)基-N,N-二甲基叔胺的CO₂开关响应性能研究

CO₂-switching responsive performance of N-dodecyl polyoxyethylene (3)-N,N-dimethyl tertiary amine

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