耐腐蚀超疏水超亲油不锈钢网的制备及其在油水分离过程中的应用

doi:10.13218/j.cnki.csdc.2018.05.006

日用化学工业 ›› 2018, Vol. 48 ›› Issue (5): 272-277.doi: 10.13218/j.cnki.csdc.2018.05.006

耐腐蚀超疏水超亲油不锈钢网的制备及其在油水分离过程中的应用

丁鹏¹, 台秀梅¹, 杜志平^1,2

1.中国日用化学工业研究院,山西太原 030001;
2.山西大学资源与环境工程研究所,山西太原 030006

收稿日期:2018-01-05 发布日期:2019-03-18
通讯作者: 杜志平,教授,电话:(0351)4084691,E-mail:duzhiping@sxu.edu.cn。
作者简介:丁鹏(1992-),男,硕士研究生,电话:17635369764,E-mail:17635369764@163.com。
基金资助:
国家重点研发计划经费资助项目(2017YFB0308704);伽蓝研究基金资助项目(Jala2015)

Preparation of anti-corrosion superhydrophobic/superoleophilic stainless steel mesh and its application in oil/water separation

DING Peng¹, TAI Xiu-mei¹, DU Zhi-ping^1,2

1.China Research Institute of Daily Chemical Industry,Taiyuan,Shanxi 030001,China;
2.Resources and Environment Engineering Research Institute,Shanxi University,Taiyuan,Shanxi 030006,China

Received:2018-01-05 Published:2019-03-18

摘要/Abstract

摘要： 以不锈钢网为基底,通过化学刻蚀法制备微米级粗糙表面,通过一步浸泡法将stöber法制得的疏水亲油纳米SiO₂颗粒沉积到粗糙的不锈钢网表面,制备了具有微纳二级粗糙结构的超疏水超亲油不锈钢网。利用扫描电子显微镜(SEM)、傅里叶变换红外光谱仪(FT-IR)和接触角测量仪(CA)表征了超疏水超亲油不锈钢网的表面形貌、化学组成和润湿性能,并将其用于油水分离过程中。结果表明,疏水亲油纳米SiO₂颗粒成功的沉积到不锈钢网表面;水滴在超疏水超亲油不锈钢网上的接触角最大为151°,煤油的接触角为0°;制备的超疏水超亲油不锈钢网不仅能高效的分离不同种类油和水的混合物,还能高效的分离油和腐蚀性液体(强酸或强碱水溶液)的混合物,其耐腐蚀特性可满足复杂环境下的油水分离要求。

关键词: 超疏水, 超亲油, 纳米SiO₂, 油水分离, 耐腐蚀

Abstract: Using stainless steel mesh as substrate,a superhydrophobic/superoleophilic stainless steel mesh with micro/nano hierarchical structure was prepared.The surface with micron-sized roughness was obtained through chemical etching and was then coated with hydrophobic/oleophilic nano-SiO₂ (the nano-SiO₂ was obtained by stöber method) through one step immersing method.The surface morphology,chemical composition and wettability of the superhydrophobic/superoleophilic stainless steel mesh were characterized by scanning electron microscopy (SEM),fourier transform infrared spectroscopy (FT-IR) and contact angle measurement (CA).The mesh was used in oil/water separation process.Results show that hydrophobic/oleophilic nano-SiO₂ was coated on the surface of chemical etched stainless steel mesh.The surface of the prepared mesh exhibited superhydrophobicity and superoleophilicity with a water contact angle of 151° and kerosene contact angle of 0°.The prepared mesh could efficiently separate not only the mixtures of water and different kinds of oil but also the mixtures of oil and corrosive aqueous solutions (containing strong acid or alkali).The anti-corrosion ability could meet the requirements of oil/water separation in complex environments.

Key words: superhydrophobic, superoleophilic, nano-SiO₂, oil/water separation, anti-corrosion

中图分类号:

TG178

丁鹏, 台秀梅, 杜志平. 耐腐蚀超疏水超亲油不锈钢网的制备及其在油水分离过程中的应用[J]. 日用化学工业, 2018, 48(5): 272-277.

DING Peng, TAI Xiu-mei, DU Zhi-ping. Preparation of anti-corrosion superhydrophobic/superoleophilic stainless steel mesh and its application in oil/water separation[J]. China Surfactant Detergent & Cosmetics, 2018, 48(5): 272-277.

参考文献

[1] Nordvik A B,Simmonset J L,Bitting K R,et al.Oil and water separation in marine oil spill clean-up operations [J].Spill Sci.& Technol.Bull,1996,3:107-122.
[2] Kwon G,Kota A K,Li Y,et al.On-demand separation of oil-water mixtures [J].Adv.Mater.,2012,24:3666-3671.
[3] Tirmizin P,Raghuraman B,Wiencek J.Demulsification of water/oil/solid emulsions by hollow-fiber membranes [J].Aiche Journal,1996,42:1263-1276.
[4] Shi Yanlong,Yang Wu,Feng Xiaojuan.Fabrication of superhydrophobic-superoleophilic cotton fabric and its application in water-oil separation [J].Chem.J.Chinese Universities,2015,36(9):1724-1729.
[5] Wu D,Yu Z,Wu W,et al.Continuous oil-water separation with surface modified sponge for clean-up of oil spills [J].Rsc Adv.,2014,4:53514-53519.
[6] Cortese B,Caschera D,Federici F,et al.Superhydrophobic fabrics for oil-water separation through a diamond like carbon (DLC) coating [J].J.Mater.Chem.A,2014,2:6781-6789.
[7] Gao C,Sun Z,Li K,et al.Integrated oil separation and water purification by a double-layer TiO₂-based mesh [J].Energy Environ.Sci.,2013,6:1147-1151.
[8] Lu Y,Sathasivam S,Song J L,et al.Creating superhydrophobic mild steel surfaces for water proofing and oil/water separation [J].J.Mater.Chem.A,2014,2:11628-11634.
[9] Rohrbach K,Li Y,Zhu H,et al.A cellulose based hydrophilic-oleophobic hydrated filter for water/oil separation [J].Chem.Commun.,2014,50:13296-13299.
[10] Su C,Xu Y,Zhang W,et al.Porous ceramic membrane with superhydrophobic and superoleophilic surface for reclaiming oil from oily water [J].Appl.Surf.Sci.,2012,258:2319-2323.
[11] Hou K K,Chen X H,Zhang W Q,Low cost preparation of superhydrophobic copper net and its application in oil and water separation [J].Modern Chemical Industry,2017,37:137-142.
[12] Li J,Li D,Hu W,et al.Stable superhydrophobic and superoleophilic silica coated polyurethane sponges for the continuous capture and removal of oils from the water surface [J].New J.Chem.,2015,39:9958-9962.
[13] Huang H,Li J S,Ge M Z,et al.Robust superhydrophobic TiO₂@ fabrics for UV shielding,self-cleaning and oil-water separation [J].J.Mater.Chem.A,2015,3:2825-2832.
[14] Li J,Yan L,Zhao Y,et al.One-step fabrication of robust fabrics with both-faced superhydrophobicity for separation and capture of oil from water [J].Phys.Chem.Chem.Phys.,2015,17:6451-6457.
[15] An Q,Zhang Y H,Lv K K,et al.A facile method to fabricate functionally integrated devices for oil/water separation [J].Nanoscale,2015,7:4553-4558.
[16] Sun M H,Luo C X,Xue L P,et al.Artificial lotus leaf by nanocasting [J].Langmuir,2005,21:8978-8981.
[17] Liu Y,Zhang K,Yao W,et al.A facile electrode position process for the fabrication of superhydrophobic and superoleophilic copper mesh for efficient oil-water separation [J].Ind.Eng.Chem.Res.,2016,55:2704-2712.
[18] Li J,Kang R M,Tang X H,et al.Superhydrophobic meshes that can repel hot water and strong corrosive liquids used for efficient gravity-driven oil/water separation [J].Nanoscale,2016,8(14):7638-7645.
[19] Wenzel R N.Resistance of solid surfaces to wetting by water [J].Ind.Eng.Chem.,1936,28:988-994.
[20] Cassie A B D,Baxter S.Wettability of porous surfaces [J].Trans.Faraday Soc.,1944,40:546-551.

耐腐蚀超疏水超亲油不锈钢网的制备及其在油水分离过程中的应用

Preparation of anti-corrosion superhydrophobic/superoleophilic stainless steel mesh and its application in oil/water separation

PDF (PC)

赞

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 5

Metrics

本文评价

推荐阅读 10

[1]	刘佩, 潘婷, 裴晓梅, 宋冰蕾, 蒋建中, 崔正刚, Bernard P. Binks. 非离子-阴离子Bola型表面活性剂和纳米SiO₂颗粒协同稳定的双重响应型O/W乳状液[J]. 日用化学工业（中英文）, 2024, 54(1): 1-15.
[2]	冯晓君,张鹏,李蕊蕊,赖璐. 基于十四烷基二乙烯三胺的CO₂响应性Pickering乳液的稳定性能研究[J]. 日用化学工业, 2020, 50(12): 842-847.
[3]	张婉晴,蒋建中,崔正刚. 表面活性剂-纳米颗粒相互作用与智能体系的构建（IV）非离子表面活性剂-纳米颗粒相互作用——氢键作用构建温度-响应性Pickering乳状液[J]. 日用化学工业, 2019, 49(10): 633-642.
[4]	黄威华, 邹华, 赖璐, 梅平. 双季铵盐改性纳米SiO₂的乳化性能研究[J]. 日用化学工业, 2017, 47(8): 430-434.
[5]	侯屹婷, 关茹群, 郝雅娟, 杨恒权. “干浓硫酸”的制备与性质研究[J]. 日用化学工业, 2017, 47(5): 246-250.