脂肪叔胺制备技术进展

doi:10.13218/j.cnki.csdc.2016.07.012

摘要/Abstract

摘要： 主要从3方面综述了脂肪叔胺制备技术的研发进展。介绍了脂肪叔胺的市场情况及主要用途,其主要作为制备阳离子表面活性剂和两性离子表面活性剂的重要中间体,这2类表面活性剂的主要品种可作为消毒杀菌剂、缓蚀剂、抗静电剂、织物整理剂以及个人护理用品中的活性成分等;重点阐述了脂肪叔胺的制备工艺过程,此工艺的技术关键是催化剂的制备,包括催化剂组分的筛选及其制备过程,目前主要采用的是多元金属复合催化剂,多以Cu与其他金属元素复合;简要回顾了脂肪醇催化胺化技术的发展概况,并对脂肪叔胺制备技术的进一步发展提出了建议。

关键词: 脂肪叔胺, 制备技术, 催化剂, 进展

Abstract: The progress in field of research and development for preparation of fatty tertiary amines was summarized from three aspects.The marketing and main applications of fatty tertiary amines were introduced,mainly for preparation of cationic surfactants and amphoteric surfactants as important intermediates.The main varieties of these two types of surfactants can be used as active ingredient of disinfectants,corrosion inhibitors,antistatic agents,fabric finishing agents,and personal care products,etc.The preparation process of fatty tertiary amines was emphatically described.The critical technology of this process is the preparation of catalysts,including screening of various components of the catalyst and its preparation conditions.At present,the multiple metallic composite catalyst are mainly adopted,with copper as the main active matter to blend with other metallic elements.A brief review of the development of the technology for catalytic amination of fatty alcohols was included,and the suggestion for the further development of preparation technology of fatty tertiary amines was mentioned.

Key words: fatty tertiary amine, preparation technology, catalyst, progress

中图分类号:

TQ226

李峰,王涛,张卫民,张国华. 脂肪叔胺制备技术进展[J]. 日用化学工业, 2016, 46(7): 419-422.

LI Feng,WANG Tao,ZHANG Wei-min,ZHANG Guo-hua. Progress of technology for fatty tertiary amine preparation[J]. China Surfactant Detergent & Cosmetics, 2016, 46(7): 419-422.

参考文献

[1] 谭平,李秋小.脂肪醇制脂肪叔胺胺化催化剂的研究与开发[J].日用化学工业,2002,32(6):39-43.
[2] 阳权富,冯浩,田丰硕.我国高级脂肪胺行业浅析[J].泸天化科技,2007(3):269-271.
[3] 表面活性剂和洗涤剂行业生产力促进中心.中国表面活性剂行业年鉴[M].太原:山西出版传媒集团,2014:251.
[4] 李秋小,张高勇.脂肪醇催化胺化制叔胺工艺技术现状及前景[J].日用化学工业,2001,31(4):21-25.
[5] BILLENSTEIN S.Industrial production of fatty amines and their deriva-tives [J].JAOCS,1984,61(2):353-356.
[6] BAIKER A,CAPREZ W,HOLSTEIN W L.Catalytic amination of aliphatic alcohols in the gas and liquid phases [J].Ind Eng Chem Res Dev,1983,22(2):217-225.
[7] BAIKER A,KIJJENSKI J.Catalytic synthesis of higher aliphatic amines form the corresponding alcohds [J].Catal Rev Sci-Eng,1985,27(4):653-697.
[8] 张文金,刘海婷,张炯.醇一步法制叔胺生产工艺控制[J].日用化学工业,2009,39(1):71-74.
[9] 岡部和彦.制备高碳脂肪叔胺催化剂的最新动向[J].李焕珍,译.日用化学工业译丛,1989(1):9-13.
[10] 李秋小,邢英站,魏海威,等.二甲胺歧化对脂肪醇催化胺化反应的影响[J].日用化学工业,2002,32(5):11-13.
[11] 魏代军,刘振泊.伯胺甲醇一步法合成脂肪烷基二甲基叔胺的研究[J].中国洗涤用品工业,2008(1):76-78.
[12] 李运玲.催化胺化制三烷基叔胺的研究[D].太原:山西大学,2012.
[13] 梁勤学.脂肪醇常压胺化法制单烷基叔胺工艺开发[D].成都:四川大学,2003.
[14] KIMURA H,MATSUTAMI S,NOMURA S.Basic function of Cu/Ni-based catalyst in a colloidal stste for one-pot amination of alcohols to N,N-dimethyl tertiary amines [J].Catal Lett,2005,99:119-131.
[15] KENNEALLY C J,SCHEIBEL J J.Process for making long-chain internal fatty tertiary amines:EP1812375 [P].2007-08-01.