高悬浮能力清洁剂的制备与性能研究

doi:10.3969/j.issn.1001-1803.2022.03.004

日用化学工业 ›› 2022, Vol. 52 ›› Issue (3): 253-257.doi: 10.3969/j.issn.1001-1803.2022.03.004

高悬浮能力清洁剂的制备与性能研究

张云¹,李琛^2,^*(),于思涵¹,刘冬¹

1.苏州绿叶日用品有限公司,江苏苏州 215000
2.玉溪师范学院化学生物与环境学院,云南玉溪 653100

收稿日期:2021-06-01 修回日期:2022-01-06 出版日期:2022-03-22 发布日期:2022-03-21
通讯作者: 李琛
基金资助:
国家自然科学基金地区科学基金项目(21765023);云南省科技厅科技计划项目(2018FD091)

Study on preparation and performances of high suspension ability detergent

Zhang Yun¹,Li Chen^2,^*(),Yu Sihan¹,Liu Dong¹

1. Suzhou Green Leaf Daily Necessities Co., Ltd., Suzhou, Jiangsu 215000, China
2. School of Chemistry, Biology and Environment, Yuxi Normal University, Yuxi, Yunnan 653100, China

Received:2021-06-01 Revised:2022-01-06 Online:2022-03-22 Published:2022-03-21
Contact: Chen Li

摘要/Abstract

摘要：

为了制备出具有高悬浮能力、低黏度、高透明度和低成膜性的清洁剂,采用丙烯酸乙酯和甲基丙烯酸两种单体来制备聚合物作为清洁剂（实验组A）中的悬浮剂,考察了不同单体比例对悬浮剂悬浮能力的影响。与两种常用的丙烯酸类悬浮剂即Carbopol® Aqua SF-1 Polymer（对照组B）和Carbopol® Aqua SF-2CN Polymer（对照组C）进行对比实验,比较3种悬浮剂在体系中的黏度和浊度、悬浮能力、成膜性和剪切变稀能力的区别。结果表明：在相同实验条件下,实验组A的黏度最小,涂抹时的延展性最好;当悬浮剂质量分数≥1.8%时,3种悬浮剂都具有较好的透明度和悬浮能力;实验组A的成膜性最差,不容易堵塞泵头;实验组A的喷雾挤压力度和喷雾均匀度这两个性能均优于对照组B和对照组C。总体来看,实验组A的性能最优。

关键词: 悬浮剂, 清洁剂, 黏度, 浊度, 成膜性

Abstract:

In order to prepare detergents with high suspension ability, low viscosity, high transparency and low film-forming ability, two monomers of ethyl acrylate and methacrylic acid were used to prepare the polymer as the suspending agent in detergent （experimental group A）. The influence of different monomer ratios on the suspension ability of the suspension agent was investigated. The viscosity and turbidity, suspension ability, film-forming ability and shear thinning ability in detergent of the experimental group A was compared with two commonly used acrylic suspension agents, namely Carbopol® Aqua SF-1 Polymer （control group B） and Carbopol® Aqua SF-2CN Polymer （control group C）. The results show that the ductility in application of the experimental group A is the best due to the smallest viscosity in the same experimental conditions. When the mass fraction of the suspending agent is ≥1.8%, all three suspending agents have good transparency and suspending ability. The film forming ability of the experimental group A is the worst, therefore it is not easy to block the pump head. The spray extrusion strength and spray uniformity of the experimental group A are better than those of the control group B and the control group C. Overall, the performances of the experimental group A are the best.

Key words: suspending agent, detergent, viscosity, turbidity, film-forming ability

中图分类号:

TQ423

张云,李琛,于思涵,刘冬. 高悬浮能力清洁剂的制备与性能研究[J]. 日用化学工业, 2022, 52(3): 253-257.

Zhang Yun,Li Chen,Yu Sihan,Liu Dong. Study on preparation and performances of high suspension ability detergent[J]. China Surfactant Detergent & Cosmetics, 2022, 52(3): 253-257.

图/表 6

图1

表1

表2

图2

图3

表3

悬浮剂种类	质量分数/%	体系黏度/（mPa·s）			体系浊度/NTU
悬浮剂种类	质量分数/%	pH=4.0	pH=7.0	pH=10.0	pH=4.0	pH=7.0	pH=10.0
实验组A	0.6	16.5	6.3	8.4	380	294	295
	0.9	99.3	29.4	28.8	321	218	210
	1.2	145	112.8	100.2	296	154	143
	1.8	1 452	372	367	147	79.6	77.4
	3.0	3 323	1 386	1 218	81	56.3	50.2
对照组B（Carbopol® Aqua SF-1 Polymer）	0.6	32.7	10.2	9.3	563	40.8	152
	0.9	197.1	67.8	50.4	313	23	100
	1.2	646.4	260.9	183	203	10.9	60.4
	1.8	2 220	1 176	721	145	5.56	26.8
	3.0	7 332	5 153	3 263	183	5.14	14
对照组C（Carbopol® Aqua SF-2 Polymer）	0.6	23.2	9.2	8.1	432	92	192
	0.9	145.2	47.2	45.9	322	46	82
	1.2	292.1	172.4	161	265	38	71
	1.8	1 720	721	670	148	12	32
	3.0	5 210	2 432	2 152	142	9.2	12

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高悬浮能力清洁剂的制备与性能研究

Study on preparation and performances of high suspension ability detergent

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悬浮剂种类	喷雾测试
悬浮剂种类	喷雾挤压力度	喷雾均匀度
实验组A	5	5
对照组B	4	3
对照组C	4	4