双子型有机硅表面活性剂的研究进展

doi:10.13218/j.cnki.csdc.2016.05.012

摘要/Abstract

摘要： 综述了双子型有机硅表面活性剂的合成及性能特点,着重介绍了双子型有机硅表面活性剂界面性质、聚集行为及抗水解性等方面的研究现状,并对其在皮革、纺织以及农药等领域的应用前景做了展望。

Abstract: Synthesis and performance of Gemini organosilicon surfactants were reviewed.Interfacial properties,aggregation behavior and hydrolysis resistance of Gemini organosilicon surfactants were emphatically introduced.Meanwhile,outlooks about application of Gemini organosilicon surfactants in the field of leather processing,textile and pesticide manufacturing were prospected.

Key words: Gemini surfactants, organosilicon, interfacial properties, aggregation behavior, hydrolysis resistance

中图分类号:

TQ423

鲍艳,郭佳佳,李晓璐,时春华,张晓艳. 双子型有机硅表面活性剂的研究进展[J]. 日用化学工业, 2016, 46(5): 296-301.

BAO Yan,GUO Jia-jia,LI Xiao-lu,SHI Chun-hua,ZHANG Xiao-yan. Progress in field of Gemini organosilicon surfactant[J]. China Surfactant Detergent & Cosmetics, 2016, 46(5): 296-301.

参考文献

[1] 韩富.新型有机硅表面活性剂的合成及性能研究[D].武汉:武汉大学,2004.
[2] HAN FU,WANG PENGLI,SONG JIA,et al.A surface rheological study of a glucosamidebased trisiloxane Gemini surfactant at the air/water interface [J].Journal of Dispersion Science and Technology,2012,33:1708-1714.
[3] HUANG ZHIQIANG,ZHONG HONG,WANG SHUAI,et al.Gemini trisiloxane surfactant:synthesis and flotation of aluminosilicateminerals [J].Minerals Engineering,2014,56:145-154.
[4] 王军.特种表面活性剂[M].北京:中国纺织出版社,2007:106-113.
[5] 王培义.表面活性剂:合成、性能、应用[M].北京:化学工业出版社,2012:99-101.
[6] 杨继生.表面活性剂原理与应用[M].南京:东南大学出版社,2012:126-127.
[7] WAGNER R,STREY R.Phase behavior of binary water trimethylsilane surfactant systems:origin of the dilute lamellar phase [J].Langmuir,1999,15:902-905.
[8] XING ZHONG,GUO JIANWEI,FENG LIJUAN,et al.Cationic Gemini surfactants based on adamantane:synthesis,surface activity and aggregation properties [J].Colloids and Surfaces A:Physicochem Eng Aspects,2014,441:572-580.
[9] 赵祖培.农药助剂用有机硅表面活性剂(上)[J].农药译丛,1994,16(6):34-42.
[10] KNOCHE M,TAMURA H,BUKOVAC M J.Performance and stability of the organosilicon Surfactant L-77:Effect of pH,concentration,and temperature [J].Journal of Agricultural and Food Chemistry,1991,39(1):202-206.
[11] ZHANG YUE,HAN FU.The spreading behaviour and spreading mechanism of new glucosamide-based trisiloxane on polystyrene surfaces[J].Journal of Colloid and Interface Science,2009,337:211-217.
[12] XING FENGLAN,GAO YUEYUE,XU QUN.The Effects of the organic groups attached at the silicone atoms of the organosilane-based Gemini nonionic surfactants on their surface activities [J].Journal of Surfactants and Detergents,2014,17:739-745.
[13] SHI CUILEI,YANG XIAODENG,SHI LEI.Synthesis of a novel class of organosilicon quaternary ammonium Gemini surfactants [J].Journal of Dispersion Science and Technology,2013,34:528-531.
[14] 罗儒显,何姗姗.季铵盐型有机硅双子表面活性剂的合成与界面性能[J].精细化工,2013,30(3):268-272.
[15] 梁维平,赵晓辉,安东,等.四硅氧烷Gemini咪唑表面活性剂的合成及表面性能[J].高等学校化学学报,2015,36(10):2009-2015.
[16] ROSEN M J,WU Y.Superspreading of trisiloxane surfactant mixtures on hydrophobic surfaces.1.Interfacial adsorption of aqueous trisiloxane surfactant-N-alkyl pyrrolidinone mixtureson polyethylene [J].Langmuir,2001,17:7296-7305.
[17] HAN FU,ZHANG GAOYONG.New family of Gemini surfactants with glucosamide-based trisiloxane [J].Colloids and Surfaces A:Physicochem Eng Aspects,2004,237,79-85.
[18] WANG GUOYONG,ZHANG DIANLONG,DU ZHIPING,et al.Spontaneous vesicle formation from trisiloxane-tailed Gemini surfactant [J].Journal of Molecular Liquids,2014,20:1247-1250.
[19] KUNITAKE T.In modern trends of colloid science in chemistry and biology [M].Swizerland:Makromol Chem Suppl,1985:14-81.
[20] KALER E W,KAMALAKARA M A,RODIGUEZ B E,et al.Sponta-neous vesicle formation in aqueous mixtures of single-tailed surfactants [J].Science,1989,245:4924-4926.
[21] LIN LI-HUEI,WANG CHEE-CHAN,CHEN KENG-MING,et al.Synthesis and physicochemical properties of silicon-based Gemini surfactants [J].Colloids and Surfaces A:Physicochem Eng Aspects,2013,436:881-889.
[22] PENG ZHONGLI,WU QING,CAI TAO,et al.Syntheses and properties of hydrolysis resistant twin-tail trisiloxane surfactants [J].Colloids and Surfaces A:Physicochem Eng Aspects,2009,342:127-131.
[23] LIU HSIN-JIANT,LIN LI-HUEI,CHEN KENG-MING,et al.Preparation and properties of water-soluble polyester surfactants.Ⅲ.Preparation and wetting properties of polyethylene glycol-polydimethylsiloxane polyester surfactants [J].Journal of Appled Polymer Science,2003,88:1236-1241.
[24] 彭忠利.耐水解的双尾六硅氧烷表面活性剂:CN101318116A [P].2008-12-10.
[25] 陈耀彬,罗儒显,姜少华,等.双子型聚氧乙烯醚三硅氧烷表面活性剂的合成与性能[J].精细化工,2014,31(9):1070-1071.
[26] 黄良仙,张乐,李婷,等.季铵盐型有机硅双子表面活性剂的制备及其界面性能[J].印染助剂,2015,32(9):13-16.
[27] CHURAEV N V,ESIPOVA N E,HILL R M,et al.The superspreading effect of trisiloxane surfactant solutions [J].Langmuir,2001,17:1338-1348.
[28] SALAH M T,ABDEL-AAL A A,SAMY S,et al.Surface,thermodynamic and biological activities of some synthesized Gemini quaternary ammonium salts based on polyethylene glycol [J].Journal of Industrial and Engineering Chemistry,2015,30:112-119.
[29] HAO CHUANMING,CUI YUEZHI,YANG PENGFEI,et al.Effect of siloxane spacer length on organosilicon bi-quaternary ammonium amphiphiles [J].Colloids and Surfaces B:Biointerfaces,2015,6944:1-5.
[30] 马建中.皮革化学品的合成原理与应用技术[M].北京:中国轻工业出版社,2007:67-69.
[31] 王学川,丁建华,袁绪政.有机硅类表面活性剂的研究动态及其在皮革工业中的应用前景[J].日用化学品科学,2007,30(9):22-26.
[32] 韩富,张高勇,王军.有机硅消泡剂[J].日用化学工业,2001,31(4):39-41.
[33] 王高雄,李临生.有机硅皮革手感剂的合成与应用[J].中国皮革,2007,36(3):48.
[34] 王瑾,陈均志,邵超群.有机硅材料在日化及纺织领业中的应用[J].日用化学品科学,2008,31(10):18-21.
[35] LIN LI-HUEI,CHEN KENG-MING.Surface activity and water repellency properties of cleavable-modified silicone surfactants [J].Colloids and Surfaces A:Physicochem Eng Aspects,2006,275:99-106.
[36] 屠豫钦,袁会珠,齐淑华,等.我国农药的有效利用率与农药的负面影响问题[J].世界农药,2003,25(6):1-4.
[37] 于丽,王春光,张培龙,等.农用抗水解有机硅表面活性剂合成研究进展[J].农药,2012,51(9):634-637.
[38] ZHANG YUE,ZHANG GAOYONG,HAN FU.The spreading and superspeading behavior of new glucosamide-based trisiloxane surfactants on hydrophobic foliage [J].Colloids and Surfaces A:Physicochem Eng Aspects,2006,276:100-106.
[39] 庄占兴,路福绥,刘月,等.表面活性剂在农药中的应用研究进展[J].农药,2008,47(7):469-475.
[40] 沈晋良,周明国,胡美英,等.农药加工与管理[M].北京:中国农业出版社,2001.
[41] WANG WENTAO,HAN YUCHUN,TIAN MAOZHANG,et al.Cationic Gemini surfactant-assisted synthesis of hollow Au nanostructures by stepwise reductions [J].ACS Applied Materials & Interfaces,2013,5:5709-5716.
[42] CHEN Q R,SAKAMOTO Y,TERASAKI O,et al.Synthesis of silica mesoporous crystalswith controlled structure and morphology using Gemini surfactant [J].Micropor Mesopor Mat,2007,105:24-33.