季铵盐表面活性剂有机蒙脱土的制备及其苯酚吸附行为研究

doi:10.13218/j.cnki.csdc.2016.02.001

日用化学工业 ›› 2016, Vol. 46 ›› Issue (2): 61-65.doi: 10.13218/j.cnki.csdc.2016.02.001

• 基础研究 • 下一篇

季铵盐表面活性剂有机蒙脱土的制备及其苯酚吸附行为研究

高艳丽,孙晨雅,齐丽云,方云

江南大学化学与材料工程学院食品胶体与生物技术教育部重点实验室,江苏无锡 214122

出版日期:2016-02-22 发布日期:2016-02-22
通讯作者: 齐丽云,副教授,硕士生导师,电话:13382888602,E-mail:qilyun@126.com。
作者简介:高艳丽(1988-),女,山西朔州人,硕士研究生,电话:18352512757,E-mail:gaoyanli425@163.com。
基金资助:
国家自然科学基金资助项目(21141004)

Preparation of organo-montmorillonite modified with quaternary ammonium surfactant and its adsorption behavior for phenol

GAO Yan-li,SUN Chen-ya,QI Li-yun,FANG Yun

MOE Key Laboratory of Food Colloids and Biotechnology,School of Chemical and Material Engineering, Jiangnan University,Wuxi,Jiangsu 214122,China

Online:2016-02-22 Published:2016-02-22

摘要/Abstract

摘要： 选用阳离子表面活性剂双十六烷基二甲基溴化铵(DHDMA)和Gemini型表面活性剂1,2-亚乙基-双(十六烷基二甲基溴化铵)(16-2-16)分别制备2种有机蒙脱土产品DHDMA-MMT和16-2-16-MMT。采用FT-IR,XRD和TGA进行产品结构表征;并对比研究了2种产品吸附水中苯酚的性能。实验结果表明,当表面活性剂负载量相当时,2种产品有机碳含量相近,而16-2-16-MMT对苯酚的吸附量和有机碳归一化吸附系数均显著大于DHDMA-MMT。2种产品的分子中均含有2条十六烷基碳链,16-2-16分子仅比DHDMA分子多1个季铵盐头基,表明季铵盐头基在有机蒙脱土吸附苯酚过程中具有重要的作用。

关键词: 双十六烷基二甲基溴化铵, 1,2-亚乙基-双(十六烷基二甲基溴化铵), 有机蒙脱土, 吸附层结构, 吸附性能

Abstract: Cationic surfactant dihexadecyldimethylammonium bromide (DHDMA) and Gemini surfactant 1,2-ethylene bis(cetyldimethyl ammonium bromide) (16-2-16) were used separately to prepare two kinds of organo-montmorillonite DHDMA-MMT and 16-2-16-MMT.The products were characterized by FT-IR,X-ray diffraction (XRD) and thermal gravimetric analysis (TGA).Phenol adsorption behavior of the two kinds of product was investigated and compared.Experiment results demonstrated that the organic carbon content of the two kinds of product is close to each other at the same surfactant loadings while the adsorption amount of phenol and normalized organic carbon content adsorption coefficient of 16-2-16-MMT is remarkably higher than that of DHDMA-MMT.In view of that same carbon chains are containing in the molecule structure of the two kinds of product,and the structure difference of the two surfactants is only that 16-2-16 owns an extra quaternary ammonium headgroup as comparing with DHDMA,it is reasonable to conclude that the quaternary ammonium headgroup plays an important role in the process of adsorbing phenol from aqueous solution by the organo-montmorillonite.

Key words: dihexadecyldimethylammonium bromide, 1,2-ethylene bis(cetyldimethyl ammonium bromide), organo-montmorillonite, structure of adsorption layer, adsorption performance

中图分类号:

TQ423.12

高艳丽,孙晨雅,齐丽云,方云. 季铵盐表面活性剂有机蒙脱土的制备及其苯酚吸附行为研究[J]. 日用化学工业, 2016, 46(2): 61-65.

GAO Yan-li,SUN Chen-ya,QI Li-yun,FANG Yun. Preparation of organo-montmorillonite modified with quaternary ammonium surfactant and its adsorption behavior for phenol[J]. China Surfactant Detergent & Cosmetics, 2016, 46(2): 61-65.

参考文献

[1] BOYD S A,LEE J F,MORLAND M M.Attenuating organic contaminant mobility by soil modification [J].Nature,1988,333:345-347.
[2] CHUN Y,SHENG G Y,BOYD S A.Sorptive characteristics of tetralkylammonium-exchanged smectite clays [J].Clays and Clay Minerals,2003,51(4):415-420.
[3] XI YUNFEI,FROST R L,HE HONGPING,et al.Modification of Wyoming montmorillonite surfaces using a cationic surfactant [J].Langmuir,2005,21:8675-8680.
[4] JOHNSTON C T,KHAN B,BARTH E F,et al.Nature of the interlayer environment in an organoclay optimized for the sequestration of dibenzo-p-dioxin [J].Environmental Science and Technology,2012,46(17):9584-9591.
[5] SHEN YUNHWEI.Phenol sorption by organoclays having different charge characteristics [J].Colloids and Surfaces A:Physicochem Eng Aspects,2004,232:143-149.
[6] BREEN C,WATSON R,MADEJOVA J,et al.Acid-activated organoclays:preparation,characterization and catalytic activity of acid-treated tetraalkylammonium-exchanged smectites [J].Langmuir,1997,13(24):6473-6479.
[7] BARTELT-HUNT S L,BURNS S E,SMITH J A.Nonionic organic solute sorption onto two organo bentonites as a function of organic-carbon content [J].Journal of Colloid Interface Science,2003,266(2):251-258.
[8] LI F,ROSEN M J.Adsorption of Gemini and conventional cationic surfactants onto montmorillonite and the removal of some pollutants by the clay [J].Journal of Colloid and Interface Science,2000,224(2):265-271.
[9] ROSEN M,LI F.The adsorption of Gemini and conventional surfactants onto some soil solids and the removal of 2-naphthol by the soil surfaces [J].Journal of Colloid and Interface Science,2001,234(2):418-424.
[10] KAN T T,JIANG XIAOHUI,ZHOU LIMEI,et al.Removal of methyl orange from aqueous solutions using a bentonite modified with a new Gemini surfactant [J].Applied Clay Science,2011,54(2):184-187.
[11] LIU BO,WANG XIAOYING,YANG BIN,et al.Rapid modification of montmorillonite with novel cationic Gemini surfactants and its adsorption for methyl orange [J].Materials Chemistry and Physics,2011,130:1220-1226.
[12] YANG SENFENG,GAO MANGLAI,LUO ZHONGXIN.Adsorption of 2-naphthol on the organo-montmorillonites modified by Gemini surfactants with different spacers [J].Chemical Engineering Journal,2014,256:39-50.
[13] LIU YUENING,GAO MANGLAI,GU ZHENG,et al.Comparison between the removal of phenol and catechol by modified montmoril-lonite with two novel hydroxyl-containing Gemini surfactants [J].Journal of Hazardous Materials,2014,256:71-80.
[14] 孙晨雅,高艳丽,方云,等.季铵盐与双子季铵盐表面活性剂有机蒙脱土的制备及性能研究[J].日用化学工业,2015,45(2):61-65.
[15] HIRAMATSU K,KAMEYAMA K,ISHIGURO R,et al.Properties of dilute aqueous solutions of double-chain surfactants,alkyldodecyl-dimethylammonium bromides with a change in the length of the alkyl chains [J].Bulletin of the Chemical Society of Japan,2003,76:1903-1910.
[16] KUNIO E,KAZUHIRO T,YOSHIFUMI K.Aqueous properties of multichain quaternary cationic surfactants [J].Langmuir,1996,12:4039-4041.
[17] LAGALY G.Characterization of clays by organic compounds [J].Clay Minerals,1981,16(1):1-21.
[18] RAWAIFIH Z,NSOUR N.Characteristics of phenol and chlorinated phenols sorption onto surfactant-modified bentonite [J].Journal of Colloid and Interface Science,2006,298(1):39-49.
[19] 徐立恒.有机膨润土的结构调控和吸附性能研究[D].杭州:浙江大学,2009.

季铵盐表面活性剂有机蒙脱土的制备及其苯酚吸附行为研究

Preparation of organo-montmorillonite modified with quaternary ammonium surfactant and its adsorption behavior for phenol

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