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China Surfactant Detergent & Cosmetics ›› 2019, Vol. 49 ›› Issue (6): 358-362.doi: 10.3969/j.issn.1001-1803.2019.06.002

• Lecture of science and technology • Previous Articles     Next Articles

Self-assembly of surfactants controlled by weak interactions(VI)Applications in catalysis

SUN Pan-pan,ZHENG Li-qiang,SUN Ji-chao()   

  1. Key Laboratory of Colloid and Interface Chemistry, Shandong University, Jinan, Shandong 250100, China
  • Received:2019-05-27 Online:2019-06-22 Published:2019-06-24
  • Contact: Ji-chao SUN E-mail:jichaosun@sdu.edu.cn

Abstract:

When the surfactant solution reaches a certain concentration, a variety of ordered molecular aggregates with different structures and shapes can be formed. In this paper, the role of ordered molecular aggregates as a simple, economical and green reaction medium in the chemical reaction has been described. We focus on how aggregates such as micelles, reverse micelles, vesicles and microemulsions participate in the reactions involving carbon-carbon/carbon-heteroatom bond formation, Keep elimination reaction and aldol reaction. The effects of the photochromism surfactant on the selectivity and cycling of the catalyst in the coupling reaction are also discussed.

Key words: surfactant, weak interaction, ordered molecular aggregates, catalysis

CLC Number: 

  • TQ423