含羟基-磺酸基不对称表面活性剂的合成及表面活性

doi:10.13218/j.cnki.csdc.2014.03.028

Abstract

Abstract: Three dissymmetric surfactants containing a sulfonic and a hydroxyl group with different length of carbon chain (XSOHC₆,XSOHC₈ and XSOHEC₈) were synthesized with cyanuric chloride,three different kinds of fatty amine,taurine and ethanolamine as starting materials.Structure of the targeted products was characterized by ¹HNMR,ESI-MS and elemental analysis.Surface activity of the surfactants was measured by Wilhelmy plate method.The critical aggregation number of micelle (N_m) was determined by steady-state fluorescence probe method.The cmc of XSOHC₆,XSOHC₈ and XSOHEC₈ is 8.1×10^-4,2.1×10^-6 and 8.5×10^-5 mol·L^-1,γ_cmc of them is 33.0,27.6 and 28.2 mN·m^-1,and N_m of them is 18,11 and 18 respectively.The results of the study showed that such dissymmetric surfactants have rather good surface activity.

Key words: dissymmetric anionic surfactant, surface activity, aggregation number of micelle

CLC Number:

TQ423.11

HOU Lu, HU Zhi-yong, JIANG Xin-xin, JIAN Feng-tian. Synthesis and surface activity of dissymmetric surfactants containing a sulfonic and a hydroxyl group[J].China Surfactant Detergent & Cosmetics, 2014, 44(3): 121-125.

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Synthesis and surface activity of dissymmetric surfactants containing a sulfonic and a hydroxyl group

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