烷基糖苷磺基琥珀酸酯盐与烷基糖苷的复配性能和相行为

doi:10.3969/j.issn.1001-1803.2020.01.004

Abstract

Abstract:

The mixtures of alkyl polyglycoside （APG） and alkyl polyglycoside sulfosuccinate （APG-SS） with different mixing ratios were studied by measuring their surface activity and foaming properties. The phase behavior of the ternary system of APG/APG-SS/H₂O was also studied. The results show that the best synergism is found in surface activity （γ_cmc=27.90 mN/m, cmc=0.044 mmol/L, Γ_max=10.86 μmol/m ², A_min=0.15 nm ²） when n_APG-SS∶n_APG=2∶8. The mixed system has higher foaming ability in distilled water and hard water than single surfactant when n_APG-SS∶n_APG=2∶8 and 4∶6, so it has synergism. At the same time, the foam stability of the mixed system is better than APG, which can improve the hard water resistance of APG. The phase diagrams of the APG-SS/APG/H₂O ternary systems were characterized by micellar phase, a region where lamellar liquid crystal and micellar phases coexisted and a region of “aqueous two-phase”.

Key words: alkyl polyglycoside, alkyl polyglycoside sulfosuccinate, compounding, surface activity, foaming ability, phase behavior

CLC Number:

TQ423

ZHOU Yuan,YANG Xiu-quan,ZHANG Jun. Performance and phase behavior of the mixture of alkyl polyglycoside sulfosuccinate and alkyl polyglycoside[J].China Surfactant Detergent & Cosmetics, 2020, 50(1): 20-25.

Figures/Tables 10

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References 20

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n_APG-SS∶n_APG	cmc/ （mmol·L^-1）	γ_cmc/ （mN·m^-1）	Γ_max/ （μmol·m^-2）	A_min/nm²	pc₂₀
10∶0	0.125	30.94	1.72	0.97	5.00
8∶2	0.075	29.40	5.20	0.32	5.20
6∶4	0.058	29.21	5.62	0.30	5.23
4∶6	0.048	28.02	8.03	0.21	5.35
2∶8	0.044	27.90	10.86	0.15	5.36
0∶10	0.049	28.33	9.88	0.17	5.36

样品	w/%
样品	APG-SS	APG	H₂O
1	0.136 2	0.222 1	0.641 7
2	0.344 5	0.096 8	0.558 7
3	0.213 5	0.248 9	0.537 6
4	0.023 1	0.438 2	0.538 8

Performance and phase behavior of the mixture of alkyl polyglycoside sulfosuccinate and alkyl polyglycoside

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