玉米麸质阿拉伯木聚糖对香豆酸酯的制备及性能研究

doi:10.13218/j.cnki.csdc.2018.02.005

Abstract

Abstract: By modifying water-soluble corn gluten arabinoxylan (CAX) to make CAX antioxidant.CAX was dissolved in DMA/LiCl system,took triethylamine as an acid binding agent,esterification with coumaryl chloride of this solution was realized,and arabinoxylan p-coumarate (p-CA-CAX) was obtained.The structure was analyzed by IR and NMR.Results show that p-coumaric acid (p-CA) is connected to CAX in the form of ester bond.High performance liquid chromatography (HPLC) was used to confirm the degree of substitution (DS) of p-CA.When the molar ratio of p-CA and glucoside bonds of CAX is 1∶5,1∶4,1∶3,1∶2 and 1∶1,respectively,the DS is 0.38,0.51,0.63 0.83 and 0.94,correspondingly.The molecular weights of p-CA-CAX of different DS were determined by gel permeation chromatography.The molecular weights of p-CA-CAX-0.38,p-CA-CAX-0.51 and p-CA-CAX-0.63 are 3.52×10⁵,3.85×10⁵ and 3.93×10⁵,respectively.Determination of lipid peroxides and oxygen radical absorbance capacity (ORAC) shows that p-CA-CAX has good antioxidant activity and the higher the content of p-CA,the better the antioxidant activity of p-CA-CAX.

Key words: arabinoxylan, p-coumaric acid, antioxidant activity, modification, cosmetics

CLC Number:

TQ658

LI Yan-li, LUO Zheng-zhe, HE Tong, YANG Cheng. Preparation and property of corn gluten arabinoxylan p-coumarate[J].China Surfactant Detergent & Cosmetics, 2018, 48(2): 82-87.

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Preparation and property of corn gluten arabinoxylan p-coumarate

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