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China Surfactant Detergent & Cosmetics ›› 2025, Vol. 55 ›› Issue (6): 747-755.doi: 10.3969/j.issn.2097-2806.2025.06.009

• Development and application • Previous Articles     Next Articles

Preparation and properties of O1/W/O2 double emulsion loaded with menthol

Yueling Xu1,Xinfeng Dong2,Xianyan Zhu1,Ge Yang1,Ruishuang Xu1,Wei Tang1,Li Yu2,*()   

  1. 1. Nantong Cigarette Filter Co., Ltd., Nantong, Jiangsu 226014, China
    2. Key Laboratory of Colloid and Interface Chemistry, Ministry of Education, Shandong University, Jinan, Shandong 250100, China
  • Received:2024-09-20 Revised:2025-05-29 Online:2025-06-22 Published:2025-07-01
  • Contact: E-mail: ylmlt@sdu.edu.cn.

Abstract:

The O1/W/O2 double emulsion loaded with menthol was prepared by two-step emulsification method, with caprylic capric triglyceride solution of menthol as the inner oil phase (O1), glyceryl triacetate as the outer oil phase (O2), Tween 80 and Span 80 as the water-soluble and the oil-soluble emulsifiers, respectively. The effects of emulsifier contents and oil-water mass ratios on the stability of O1/W/O2 double emulsion loaded with menthol were investigated, and the optimum preparation conditions were determined. Moreover, the emulsion type and microstructure of O1/W/O2 double emulsion were studied, and its loading, holding and heat-releasing properties for menthol were explored. The results show that the stability of the O1/W emulsion (primary emulsion) is the best when the mass ratio of O1 phase to water phase (mass percentage of Tween 80 is 5%) is 6∶4, and the O1/W/O2 emulsion loaded with menthol displays the best stability when the mass ratio of primary emulsion to O2 phase (mass percentage of Span 80 is 5%) is 5∶5. And after centrifugation at 12 000 r/min for 3 min or at room temperature for 60 days, it can still exist stably and without stratification. When menthol is loaded with this emulsion, its maximum load rate can reach 22.7%, and the controlled release of menthol can be achieved in the temperature range of 40-90 ℃. In this study, the payload and controlled release of menthol (the main component of peppermint essence) are realized by using double emulsion as the carrier, which lays a theoretical foundation and provides a technical support for the applications of essences in the relevant fields, such as food and home fragrance industries.

Key words: menthol, double emulsion, loading property, stability, controlled release

CLC Number: 

  • TQ658