PoPD-TiO2-GO复合光催化剂在化工染料废水吸附降解中的应用

doi:10.3969/j.issn.1001-1803.2022.10.008

Abstract

Abstract:

TiO₂-GO composite photocatalyst was prepared using graphite powder, phosphoric acid and sulfuric acid. On the basis of this catalyst, o-phenylendiamine was added to prepare the PoPD-TiO₂-GO composite photocatalyst. The simulated chemical dye wastewater containing reactive black KN-B was prepared. These two new catalysts were added to the chemical dye wastewater, and the abilities of the catalysts in adsorption and degradation were analyzed on the light reaction apparatus and thermogravimetric analyzer. The experimental results show that, excessive addition of graphene in the two catalysts will increase the specific surface area but will lead to the decrease of absorbance. Therefore, the two catalysts with 3% graphene have better effects; With the increase of adsorption time, the adsorption rate and decolorization rate of PoPD-TiO₂-GO are significantly higher than those of TiO₂-GO. The greater the amount of the two catalysts, the stronger the decolorization capacity to chemical dye wastewater; the decolorization rate of PoPD-TiO₂-GO remains above 70% after four cycles of degradation. When a variety of wastewater dyes are selected for the experiment, PoPD-TiO₂-GO can still maintain a high decolorization rate. Therefore, the degradation performance of PoPD-TiO₂-GO photocatalyst is good, which can degrade a variety of dye wastewater. In addition, the comprehensive ability of adsorption and degradation of PoPD-TiO₂-GO is higher than that of TiO₂-GO.

Key words: catalyst, chemical dye wastewater, adsorption degradation, absorbance, cyclic degradation

CLC Number:

O643.36

Zhang Qin,Shi Qiuhong. Application of PoPD-TiO₂-GO composite photocatalyst in adsorption and degradation of chemical dye wastewater[J].China Surfactant Detergent & Cosmetics, 2022, 52(10): 1088-1093.

Figures/Tables 7

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References 20

[1]	Li Z L, Zhao B X, Liu L X, et al. Preparation of Fe/Co/Al-Mt catalysts by ultrasound-assisted ion exchange method and its property investigation[J]. Environmental Chemistry, 2020, 39 (10): 2929-2936.
[2]	Qian C Y, Li Z S, Wu G, et al. Experiment on recycling of waste warm paste component used for treatment of MB in wastewater[J]. New Chemical Materials, 2020, 48 (11): 256-259.
[3]	Zhu Q R, He S Y, Zhao X L, et al. Photocatalytic degradation of methyl orange by AgCl/ZnO/GO[J]. Research of Environmental Sciences, 2020, 33 (4): 969-977.
[4]	Jiao Z J, Chen L G, Liu Y Q, et al. Preparation of CuCe oxide catalyst for CWPO degradation of bisphenol A[J]. CIESC Jorunal, 2020, 71 (4): 1646-1656.
[5]	Zhu W T, Yu X C, Tian S Y, et al. Photocatalytic degradation of tetracycline hydrochloride in mariculture wastewater by CuO/ZnO composite photocatalyst[J]. Environmental Pollution and Control, 2020, 42 (3): 305-309, 316.
[6]	Wang L X, Wang Z H. Preparation of cellulose-TiO₂ composite catalyst and its application in degradation of methyl orange[J]. Textile Auxiliaries, 2020, 37 (11): 33-36.
[7]	Liang K, Zhou J, Wu L, et al. Application of molecular simulation technique on new catalyst design[J]. New Chemical Materials, 2020, 48 (2): 41-45, 49.
[8]	Wang W, Liu J C, Huo W C, et al. Adsorption-photocatalytic degradation of oilfield wastewater by c-doped diatomite@TiO₂ catalyst[J]. Materials Review, 2020, 34 (23): 23027-23032.
[9]	Bai S L, Xue Y J, Huang W H, et al. Preparation of CdS/ZIF-8 photocatalyst and its application in the degradation of dyeing wastewater[J]. Journal of Henan Normal University(Natural Science Edition), 2022, 50 (2): 121-128.
[10]	Zhao L M, Jin R F, Ma F Y, et al. The Prepartion of Er³⁺: V_0.01 Y_2.99 Al₅ N_0.01 F_0.01 O_11.98/BiPO₄/Pt photocatalyst and its application in the photocatalytic degradation of methylene blue in wastewater[J]. Journal of Molecular Catalysis (China), 2020, 34 (3): 201-209.
[11]	Yang H G, Ran X C, Tan J W, et al. Preparation of noble metal supported commercial TiO₂ photocatalyst and its degradation performance for dye-containing wastewater[J]. New Chemical Materials, 2020, 48 (10): 135-138.
[12]	Fan W Y, Liu J, Gu J H, et al. Study on catalytic degradation of dyeing wastewater by ozone with SiO₂@CuO-ZnO bishell-catalyst[J]. Journal of Safety and Environment, 2021, 21 (2): 780-786.
[13]	Qiu S X, Han X, Zhang M, et al. Research progress and development trends in heterogeneous Fenton-like catalysts for degradation of antibiotics in wastewater[J]. Chinese Journal of Engineering, 2021, 43 (4): 460-474.
[14]	Guo J, Yu C H, Zhao C, et al. Influence of nano-silica-silver composite particle on TiO₂ visible light photocatalytic activity[J]. New Chemical Materials, 2020, 48 (11): 203-208.
[15]	Huangfu H J, Ren R, Li C N, et al. Metal polyphthalocyanine enhanced catalytic activity of oxide graphene for degradation of dyes in wastewater[J]. Applied Chemical Industry, 2020, 49 (12): 3111-3114.
[16]	Li Zhongqin, Chen Xiaowei, Wang Yan, et al. CeTiO₄/g-C₃N₄ preparation of 4 composite and its efficient photocatalytic dye degradation performance[J]. Journal of Inorganic Chemistry, 2022, 38 (1): 53-62.
[17]	Zhao Qi, Liu Ruiruirui, Zhang Zhijun, et al. 3D flower Bi₂WO₆BioBr heterojunction and its degradability to various dyes[J]. Chinese Journal of Inorganic Chemistry, 2022, 38 (2): 321-332.
[18]	Hao M T, Wang J L, Wang L L. Preparation of Fe-TiO₂-SiO₂/QCS composite membrane catalyst and its photodegradation performance of methyl orange[J]. New Chemical Materials, 2020, 48 (12): 204-208.
[19]	Li Chen, Lin Qiang, Wu Di, et al. Preparation of Y³⁺/TiO₂ photocatalyst by ball milling and treatment of mariculture wastewater[J]. Journal of Inorganic Chemistry, 2019, 35 (3): 376-384.
[20]	Zhang Z W, Lei C S, Wang S, et al. Preparation of multi-component composite nano-photocatalyst and degradation of dye wastewater under visible light[J]. Textile Auxiliaries, 2021, 38 (4): 15-19.

催化剂类型	w（石墨烯）/%	孔径分布/（cm³/g）	比表面积/（m²/g）	吸光度/%
TiO₂-GO光催化剂	0	0.086	34.7	87.4
	1	0.078	36.7	84.3
	2	0.079	38.2	74.6
	3	0.082	43.6	68.9
	5	0.083	53.8	54.2
	10	0.085	64.9	51.3
PoPD-TiO₂-GO光催化剂	0	0.078	38.4	96.4
	1	0.087	42.7	91.4
	2	0.089	53.8	85.8
	3	0.079	58.5	79.5
	5	0.076	68.5	63.2
	10	0.083	76.8	59.9

染料名称	相对分子质量	30 min脱色率/%	60 min脱色率/%
活性蓝B	851	81.6	85.8
活性艳红KE-3B	1 470	82.6	86.9
活性红MS	999	82.4	85.7
酸性黑324	851	83.8	87.7
直接枣红GB	712	84.1	93.4
直接黄棕D3G	656	83.5	91.5
直接灰D	618	84.2	89.6
媒介黑PV	383	81.5	91.5

Application of PoPD-TiO₂-GO composite photocatalyst in adsorption and degradation of chemical dye wastewater

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Application of PoPD-TiO2-GO composite photocatalyst in adsorption and degradation of chemical dye wastewater

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Application of PoPD-TiO₂-GO composite photocatalyst in adsorption and degradation of chemical dye wastewater