餐厨废弃油脂磺酸盐二元复合驱油效果评价

doi:10.3969/j.issn.1001-1803.2021.10.002

Abstract

Abstract:

The salt of sulfonated kitchen waste oil （KWOS） was synthesized by sulfonation reaction. The interfacial performance between the KWOS solution and the crude oil was evaluated by measurement of interfacial tension, thermal stability, calcium and magnesium ion resistance and adsorption loss. The binary composite systems of polyacrylamide and KWOS were prepared to carry out oil displacement experiments at different permeabilities of core and various mass fraction of KWOS. The influences of core permeability and mass fraction of KWOS on the oil displacement were investigated. The results show that the interfacial tension between oil and water is gradually decreased with the increase of mass fraction of KWOS. When the mass fraction of KWOS reaches 0.175%, the interfacial tension between oil and water can be reduced to the order of magnitude of 10^-3 mN/m. The interfacial tension between KWOS solution and crude oil is increased with the increase in thermal stability time, the total mass concentration of calcium and magnesium ions and the adsorption loss, but it can be still maintained in the order of 10^-3 mN/m, indicative of a favorable adaptability to oil reservoir. With the decrease of core permeability and the increase of mass fraction of KWOS, the enhanced oil recovery of binary composite system first increases and then decreases. When the core permeability is 0.421 μm ² and the mass fraction of KWOS is 0.3%, the binary composite system shows the highest enhanced oil recovery, illustrating that there are the best conditions for the binary composite system of polyacrylamide and KWOS in enhanced oil recovery.

Key words: kitchen waste oil, sulfonate, interfacial tension, binary composite flooding system, enhanced oil recovery

CLC Number:

TQ423

Wang Qihao,Guo Haiyan,Wang Yuyi,Huang Xiaohe,Zhang Ya,Long Yunqian. Evaluation of enhanced oil recovery of the binary composite flooding system based on the sulfonate of kitchen waste oil and polyacrylamide[J].China Surfactant Detergent & Cosmetics, 2021, 51(10): 932-938.

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References 19

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编号	长度/cm	直径/cm	渗透率/μm²	孔隙度/%
1	2.53	5.57	0.126	15.39
2	2.51	5.39	0.421	18.54
3	2.54	5.26	0.760	20.26
4	2.52	5.28	1.109	23.19
5	2.54	5.54	1.523	25.48
6	2.53	5.48	0.554	20.35
7	2.52	5.38	0.562	21.37
8	2.51	5.52	0.548	22.84
9	2.50	5.27	0.571	23.01
10	2.55	5.43	0.565	24.51

表面活性剂溶液	σ×10³/（mN·m^-1）
表面活性剂溶液	吸附前	吸附后
KWOS溶液	0.92	6.53
PS溶液	6.64	35.91
KWOS和PS混合溶液	3.22	8.96

Evaluation of enhanced oil recovery of the binary composite flooding system based on the sulfonate of kitchen waste oil and polyacrylamide

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