烷基化壳聚糖硫酸盐的制备及性能研究

doi:10.3969/j.issn.1001-1803.2020.11.003

Abstract

Abstract:

Two kinds of chitosan surfactants, dodecyl chitosan sulfate （D₁₀CTS） and decyl chitosan sulfate （D₁₂CTS） were synthesized by Schiff base reaction, reduction, sulfation and neutralization reaction. Their structures were identified by infrared spectroscopy （FT-IR）, H NMR spectroscopy（¹H NMR）, elemental analysis （EA）, and thermogravimetric analysis （TGA）. The results show that the degrees of alkylation are 0.77 and 0.52, and the degrees of sulfation are 1.35 and 1.79, respectively. Favourable surface activity and spreadability of D₁₀CTS and D₁₂CTS were evidenced by surface tension and contact angle measurements. The critical micelle concentrations （cmc） are 0.69 and 0.49 g/L, and the minimum surface tension γ_cmc are 39.50 and 35.75 mN/m, respectively. The target products possess certain foaming properties and emulsification performance. The surfactants are low-foaming and are expected to play a potential application in the field of cosmetics.

Key words: chitosan surfactant, degree of alkylation, degree of sulfation, low-foaming surfactant

CLC Number:

TQ423

JIA Zhen-yong,LI Ping,YANG Xiao-yi,GUO Chao-hua,LI Jian-bo. Preparation and properties of alkylated chitosan sulfate[J].China Surfactant Detergent & Cosmetics, 2020, 50(11): 749-755.

Figures/Tables 10

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References 16

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样品	w（C）/%	w（N）/%	w（H）/%	w（S）/%	DS_alkyl/%	DS_sulfo/%	DA/%
CTS	41.51	7.61	6.36	—	—	—	71.0
D₁₀CTS	33.86	2.80	8.29	8.66	77.38	135.31	71.0
D₁₂CTS	30.83	2.85	6.97	11.65	52.08	178.84	71.0

样品	阶段	T₀	T_e	w_f/%	R/%
CTS	Ⅰ	50	248	8	92
	Ⅱ	248	336	39	53
	Ⅲ	336	657	53	0
	Ⅳ	657	800	0	0
D₁₀CTS	Ⅰ	50	202	8	92
	Ⅱ	202	318	38	54
	Ⅲ	318	599	18	36
	Ⅳ	599	761	21	15
	Ⅴ	761	800	0	15
D₁₂CTS	Ⅰ	50	238	11	89
	Ⅱ	238	322	29	60
	Ⅲ	322	574	17	43
	Ⅳ	574	772	23	20
	Ⅴ	772	800	1	19

Preparation and properties of alkylated chitosan sulfate

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