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日用化学工业 ›› 2019, Vol. 49 ›› Issue (2): 92-97.doi: 10.3969/j.issn.1001-1803.2019.02.006

• 开发与应用 • 上一篇    下一篇

包覆3种紫外线吸收剂的防晒微胶囊的制备及性能研究

袁舒畅1,康园园1,余林林1,李雪婷1,鲁希华1,2()   

  1. 1.东华大学 化学化工与生物工程学院,上海 201620
    2.安徽美科迪智能微胶囊科技有限公司,安徽 铜陵 244000
  • 收稿日期:2018-06-03 修回日期:2018-12-26 出版日期:2019-02-22 发布日期:2019-03-15
  • 通讯作者: 鲁希华
  • 作者简介:袁舒畅(1996-),女,浙江宁波人,电话:15001719639,E-mail:15001719639@163.com。
  • 基金资助:
    国家自然科学基金资助项目(51473032);国家自然科学基金资助项目(51473032)

Preparation and properties of sunscreen microcapsules containing with 3 kinds of ultraviolet absorbents

Shu-chang YUAN1,Yuan-yuan KANG1,Lin-lin YU1,Xue-ting LI1,Xi-hua LU1,2()   

  1. 1.College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai 201620, China
    2.Anhui Microdelivery Smart Microcapsule Sci. & Tech. Co. Ltd., Tongling, Anhui 244000, China;
  • Received:2018-06-03 Revised:2018-12-26 Online:2019-02-22 Published:2019-03-15
  • Contact: Xi-hua LU

摘要:

采用界面自由基聚合法制备了以聚二甲基丙烯酸乙二醇酯 (PEGDMA) 为壁材,紫外线吸收剂胡莫柳酯 (HMS) 、阿伏苯宗 (AVB) 和奥克立林 (OCT) 的混合物为芯材的微胶囊。利用光学显微镜 (OM) 探究了不同芯材比和不同壁材含量对微胶囊形貌的影响。用傅里叶红外光谱 (FT-IR) 、纳米粒度与电位分析仪(Nano-zs) 和扫描电镜 (SEM) 分别对微胶囊的化学结构、粒径分布和形貌进行了表征。利用热重分析仪 (TGA) 分析了微胶囊的热稳定性并测定了包埋率。通过紫外线透过率分析仪测试其SPF值。结果表明,芯材中3种紫外线吸收剂 m (AVB) ∶m (OCT) ∶m (HMS) =1∶2∶3,壁材质量分数为6%时,制备的微胶囊为饱满的球形,测得该体系中芯材的包埋率为73.55%。与未包覆的HMS、AVB和OCT混合物SPF值相比,防晒微胶囊SPF值显著提高。

关键词: 防晒, 微胶囊, 胡莫柳酯, 阿伏苯宗, 奥克立林, 包覆

Abstract:

The sunscreen microcapsules were prepared by interfacial free-radical polymerization, with poly (ethylene glycol) dimethacrylate (PEGDMA) as shell material and the mixture of homosalate (HMS), avobenzone (AVB) and octocrilene (OCT) as core material. The morphologies of PEGDMA microcapsules prepared at different core composition and with different amounts of shell were explored by optical microscope (OM). The chemical structure, particle size distribution and the morphology of microcapsules were characterized by FT-IR, particle size & zeta potential analyzer (Nano-zs) and scanning electron microscope (SEM), respectively. The thermal stability of microcapsules and encapsulation efficiency were obtained by thermogravimetric analysis (TGA). The values of sun protection factor (SPF) of microcapsules were measured on a UV transmittance analyzer. The results show that when m(AVB) ∶m(OCT) ∶m(HMS)=1∶2∶3 in the core, and the mass concentration of PEGDMA (the material for building shell) is 6%, the microcapsules thus prepared will have a spherical morphology, indicative of an encapsulation efficiency of 73.55%. Moreover, the sunscreen microcapsules lead to obviously higher SPF values compared with the naked mixture of HMS, AVB and OCT in sunscreen creams.

Key words: sunscreen, microcapsule, homosalate, avobenzone, octocrilene, coating

中图分类号: 

  • TQ658.2 +4