环境污染物布洛芬吸附材料的研究进展

doi:10.3969/j.issn.2097-2806.2023.12.011

摘要/Abstract

摘要：

目前，由于布洛芬引起的环境污染问题日益严重，危害人们的身体健康，如何解决工业生产和日常生活所产生的布洛芬污染成为一个迫切需要解决的科学问题。因此，国内外学者在开发新型吸附材料方面开展了一系列研究。文章概述了布洛芬的性质及污染现状等，重点总结了目前几类重要的布洛芬吸附材料。生物质炭材料具有环保、成本低、吸附能力较强、不产生二次污染等特点，使用广泛，应用价值和发展前景较好。分子印迹材料具有良好的生物相容性，也具有其他材料无法比拟的特异性分子识别能力，是一种新型的吸附功能材料，发展空间很大。介孔材料具有极高的比表面积、规则有序的孔道结构、狭窄的孔径分布等特点，是一种较好的吸附布洛芬的功能材料。另外，国内外学者利用天然聚合物、复合纳米材料、表面活性剂等其他材料，通过优化和改性设计合成了多种吸附性能优异的高分子材料。

关键词: 布洛芬, 环境污染, 生物质炭材料, 分子印迹材料, 介孔材料

Abstract:

At present, the environmental pollution caused by ibuprofen is becoming more and more serious, which is a danger to people’s health. How to solve the pollution caused by ibuprofen produced in industrial production and daily life has become an urgent scientific problem. Therefore, domestic and foreign researchers have carried out many studies on the development of new adsorbent materials. In this review, the properties and pollution status of ibuprofen were summarized, and several important types of adsorbent materials for ibuprofen were summarized. Biochar material has the characteristics of environmentally friendly, low cost, strong adsorption capacity and no secondary pollution. It has been widely used and has good application value and development prospect. Molecularly imprinted materials have good biocompatibility and incomparable molecular recognition ability. Molecularly imprinted materials are a new type of adsorptive functional materials with large development space. Mesoporous materials have the characteristics of extremely high specific surface area, regular and ordered pore structure, and narrow pore size distribution, which are good functional materials for adsorption of ibuprofen. In addition, natural polymers, composite nanomaterials, surfactants and other materials have been used to synthesize a variety of polymer materials with excellent adsorption properties through optimization and modification.

Key words: ibuprofen, environmental pollution, biochar material, molecular-imprinted material, mesoporous material

中图分类号:

TQ423

肖璐, 荣群, 白希, 莫洪波, 范维刚. 环境污染物布洛芬吸附材料的研究进展[J]. 日用化学工业（中英文）, 2023, 53(12): 1437-1442.

Lu Xiao, Qun Rong, Xi Bai, Hongbo Mo, Weigang Fan. Research progress of adsorbent materials for environmental pollutant ibuprofen[J]. China Surfactant Detergent & Cosmetics, 2023, 53(12): 1437-1442.

图/表 5

参考文献 27

[1]	Naima Azri, Ammar Fadel, Abdelkader Ouakouak, et al. Development of a novel and efficient biochar produced from pepper stem for effective ibuprofen removal[J]. Bioresource Technology, 2022, 347: 1245-1257.
[2]	Lagha A, Adhoum N, Monser L. A molecularly imprinted polymer for the selective solid-phase extraction of ibuprofen from urine samples[J]. The Open Chemical and Biomedical Methods Jourmal, 2011, 4: 7-13.
[3]	Huang Hong, Cheng Shi, Qian Yuting, et al. Research progress of IBP removal process[J]. Shandong Chemical Industry, 2022, 51 (14) : 79-81, 84.
[4]	Zhao Yunping. Adsorption characteristics of IBP on iron oxide modified biochar[D]. Beijing: China University of Geosciences (Beijing), 2018.
[5]	Sun Tao, Zhu Xinping, Li Dianpeng, et al. Comparative analysis of physicochemical properties of biochar from different raw materials[J]. Journal of Agricultural Resources and Environment, 2017, 34 (6) : 543-549.
[6]	Liu Hongqiang. Study on preparation of wetland plant biochar and its adsorption of IBP in water[D]. Jinan: Shandong Normal University, 2020.
[7]	He Qiuwen, Lin Zizeng, Huang Xin, et al. Study on preparation of cattails activated carbon and its adsorptive property for IBP[J]. Forest Engineering, 2019, 35 (5) : 82-90.
[8]	He Qiuwen, Lin Zizeng, Huang Xin, et al. Comparison of adsorption properties of cattail activated carbon prepared at two different temperatures for IBP[J]. Water Purification Technology, 2020, 39 (3) : 106-114.
[9]	Omorogie M O, Babalola J O, Ismaeel M O, et al. Activated carbon from Nauclea diderrichii agricultural waste: a promising adsorbent for ibuprofen, methylene blue and CO₂[J]. Advanced Powder Technology, 2021, 32 (3) : 866-874. doi: 10.1016/j.apt.2021.01.031
[10]	Cao Shijun. Preparation of arbor biomass composites and their adsorption properties for IBP[D]. Lanzhou: Northwest University for Nationalities, 2022.
[11]	Olugbenga S B, Mustapha A M, Blessing A E, et al. Ibuprofen removal using coconut husk activated biomass[J]. Chemical Data Collections, 2020, 29: 1-10.
[12]	Gu Juan. Preparation of hydrothermal carbon and adsorption of hexavalent chromium and IBP from kitchen waste[D]. Chongqing: Chongqing University, 2020.
[13]	Wu Xiuling. Preparation of biomimetic molecularly imprinted nanocomposite membranes and their selective separation behavior and mechanism[D]. Guangzhou: Guangdong Pharmaceutical University, 2018.
[14]	Zhang Li, Wang Xin, Fan Weigang, et al. Preparation of molecularly imprinted polymer on surface of IBP by sol-gel method and its properties[J]. China Surfactant Detergent & Cosmetics, 2022, 52 (5) : 493-498.
[15]	Vallet-Regi M, Rámila A, Real R P, et al. A new property of MCM-41: drug delivery system[J]. Chem Mater, 2001, 13: 308-311.
[16]	Sun Lina, Zhang Xiaotong, Chen Le, et al. Study on the adsorption and controlled release of functionalized SBA-15-NH₂ on drug IBP[J]. Journal of Petrochemical Universities, 2010, 23 (3) : 1-5.
[17]	Wang Haixia, Liu Huanrong, Yang Hengquan. Adsorption and pH controlled release of polyamine functionalized mesoporous silica for IBP[J]. Journal of Shanxi University (Natural Science Edition), 2013, 36 (2) : 239-244.
[18]	Chen Lei, Zhang Fan, Shao Xinchao, et al. Adsorption and controlled release of IBP by modified mesoporous molecular sieves[J]. Chemical Industry & Engineering, 2011, 28 (4) : 11-15.
[19]	Yang Lejia, Ma Dan, Zhao Fei, et al. Adsorption properties of β-cyclodextrin polymer microspheres for IBP[J]. Chinese Journal of Spectroscopy, 2012, 29 (4) : 2429-2432.
[20]	Kong M, Chen X G, Xing K, et al. Antimicrobial properties of chitosan and mode of action: a state of the art review[J]. International Journal of Food Microbiology, 2010, 144 (1) : 51-63. doi: 10.1016/j.ijfoodmicro.2010.09.012 pmid: 20951455
[21]	Gao Qi. Preparation and adsorption of magnetic chitosan composite microspheres for IBP[D]. Shanghai: East China Normal University, 2019.
[22]	Imran A, Zeid A A, Abdulrahman A. Synthesis of composite iron nano adsorbent and removal of ibuprofen drug residue from water[J]. Journal of Molecular Liquids, 2016, 219: 858-864. doi: 10.1016/j.molliq.2016.04.031
[23]	Asiyeh K, Hossein G, Shahrzad J, et al. Efficient removal of ibuprofen via novel core-shell magnetic bio-surfactant rhamnolipid-layered double hydroxide nanocomposite[J]. Journal of Environmental Chemical Engineering, 2021, 9 (5) : 106-115.
[24]	Lewis K N, Minseok K, Yeonji Y, et al. Efficient adsorption of naproxen and ibuprofen by gelatin/zirconium-based metal-organic framework/sepiolite aerogels via synergistic mechanisms[J]. Journal Pre-proofs, 2022, 7: 452-463.
[25]	Md M H M, Dong K Y, Sung H J. Adsorptive removal of carbamazepine and ibuprofen from aqueous solution using a defective Zr-based metal-organic framework[J]. Journal of Environmental Chemical Engineering, 2022, 10: 297-310.
[26]	Georgia´ L, Ana P C, Ana S M, et al. Individual and competitive adsorption of ibuprofen and caffeine from primary sewage effluent by yeast-based activated carbon and magnetic carbon nanocomposite[J]. Sustainable Chemistry and Pharmacy, 2022, 28: 1-13.
[27]	Priya B, Pinaki D, Aisha Z, et al. Application of graphene oxide nanoplatelets for adsorption of ibuprofen from aqueous solutions: Evaluation of process kinetics and thermodynamics[J]. Process Safety and Environmental Protection, 2016, 101: 1-31. doi: 10.1016/j.psep.2016.05.011

样品名称	IBP负载量/%
MCM-41	20.3
MCM-41-NH₂	30.2
SBA-15	18.5
SBA-15-NH₂	27.8