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日用化学工业 ›› 2017, Vol. 47 ›› Issue (9): 481-486.doi: 10.13218/j.cnki.csdc.2017.09.001

• 基础研究 •    下一篇

醇醚糖苷厌氧生物降解性能及降解机理研究

张广良, 董庆斌, 赵永红, 冯瑜   

  1. 中国日用化学工业研究院,山西 太原 030001
  • 收稿日期:2017-05-24 发布日期:2019-03-20
  • 作者简介:张广良(1981-),男,山西人,高级工程师,硕士,电话:(0351)4173578,E-mail:zgliang3420@163.com。
  • 基金资助:
    山西省青年基金资助项目(2015021050)

Study on performance and mechanism of anaerobic biodegradation of alkylethoxyglucosides

ZHANG Guang-liang, DONG Qing-bin, ZHAO Yong-hong, FENG Yu   

  1. China Research Institute of Daily Chemical Industry,Taiyuan,Shanxi 030001,China
  • Received:2017-05-24 Published:2019-03-20

摘要: 参考GB/T 27857-2011有机物厌氧降解试验方法,在实验室条件下模拟厌氧环境,采用蒽酮法和TOC法分别研究了醇醚糖苷(AEG)的初级和最终生物降解性能。结果表明,即使AEG的起始质量浓度达到100 mg/L,其初级厌氧生物降解率仍然能够达到90%以上;当起始质量浓度为40 mg/L时,其最终厌氧生物降解率为88.5%。最后采用气-质联用仪对AEG的厌氧生物降解机理进行探讨发现:AEG首先经历糖苷醚键断裂,生成葡萄糖和AEO;之后AEO从末端EO链开始降解形成醇,最后转化为CO2、CH4和水等。

关键词: 醇醚糖苷, 生物降解, 厌氧, 降解机理

Abstract: With “Test method for anaerobic biodegradability of organic materials” (GB/T 27857-2011) as reference,and under simulated anaerobic laboratory conditions,the primary and ultimate anaerobic biodegradability performance of alkylethoxyglucosides (AEG) were measured separately by anthrone colorimetric method and TOC method respectively.Results show that even if the initial mass concentration of AEG reaches 100 mg/L,the primary degradation extent can achieve more than 90%,and when the initial mass concentration is 40 mg/L,the ultimate anaerobic degradation extent can achieve 88.5%.The biodegradation mechanism of AEG is studied with the application of GC-MS,and the result shows that the first step is the cleavage of the ether-glucoside bond with the formation of glucose and AEO,and the next step is the degradation of AEO molecule from the terminal EO,with the releasing of alcohol molecule.Finally they convert to carbon dioxide,methane and water.

Key words: alkylethoxyglucosides, biodegradation, anaerobic, biodegradation mechanism

中图分类号: 

  • TQ423.2