欢迎访问《日用化学工业（中英文）》，今天是
日用化学工业（中英文）

日用化学工业 ›› 2017, Vol. 47 ›› Issue (6): 336-340.doi: 10.13218/j.cnki.csdc.2017.06.008

• 开发与应用 • 上一篇    下一篇

自交联丙烯酸酯乳液合成及在水性指甲油中的应用

陈习惠1, 万祥龙1, 闵凡飞1, 郝国防2   

  1. 1.安徽理工大学 材料科学与工程学院,安徽 淮南 232001;
    2.中国科学院 过程工程研究所,北京 100190
  • 收稿日期:2017-01-24 发布日期:2019-03-20
  • 通讯作者: 万祥龙,副教授,博士,电话:(0554)6668649,E-mail:xlwan@aust.edu.cn。
  • 作者简介:陈习惠(1991-),女,安徽六安人,硕士研究生,E-mail:51993956@qq.com。
  • 基金资助:
    教育部回国人员科研启动基金(第48批);安徽高校自然科学研究重点项目(KJ2015A104);安徽省博士后基金资助项目(2015B061)

Preparation and properties of self-crosslinking polyacrylic esteremulsion and its application in water-based nail polish

CHEN Xi-hui1, WAN Xiang-long1, MIN Fan-fei1, HAO Guo-fang2   

  1. 1.School of Materials Science and Engineering,Anhui University of Science and Technology,Huainan,Anhui 232001,China;
    2.Institute of Process Engineering,Chinese Academy of Sciences,Beijing 100190,China
  • Received:2017-01-24 Published:2019-03-20

PDF (PC)

336

赞

摘要： 采用预乳化乳液聚合法合成了自交联丙烯酸酯乳液,以该乳液为基料制备了水性指甲油。比较了不同指甲油涂层的亲疏水性、硬度和耐磨性等。结果表明,自交联水性指甲油感观与理化性能指标能达到QB/T 2287-2011的要求;相对于非交联水性指甲油涂层表现出较好的疏水性,接触角为64.54°;涂层硬度较高,铅笔硬度达到了HB;耐磨性有所提高,其涂层的100转磨耗量为34.58 mg,附着力好,表现出优异的综合性能。与溶剂型指甲油涂层相比,自交联水性指甲油涂层对指甲无腐蚀作用,具备作为水性指甲油安全应用的条件。

关键词: 水性指甲油, 丙烯酸酯乳液, 自交联, 亲疏水性, 腐蚀性

Abstract: Self-crosslinking polyacrylic ester emulsion was synthesized by pre-emulsification polymerization method and a kind of water-based nail polish was prepared using the emulsion as basic material.Performance indices,such as hydrophilic and hydrophobic property as well as hardness and abrasion-proof etc of the film formed by the emulsion and other nail polish commodities were tested and compared.Results show that the self-crosslinking polyacrylic ester water-based nail polish can meet all the requirements for sensory and physical-chemical indices of QB/T 2287-2011.Its film contact angle reaches to 64.54° that indicating a better hydrophobicity as comparing with other non-crosslinked nail polish films.At the same time,its hardness reaches to HB pencil level,with the abrasion loss (100 r/min) of 34.58 mg and good adhesion level.Its conventional performance is excellent.As comparing with the solvent-based nail polishes,the self-crosslinking nail polish shows no corrosive effect on the nail,and safety in application can be achieved.

Key words: water-based nail polish, polyacrylic ester emulsion, self-crosslinking, hydrophilic and hydrophobic, corrosion

中图分类号: 

  • TQ658.5+5