对称型双子表面活性剂的合成研究进展

doi:10.13218/j.cnki.csdc.2014.02.022

摘要/Abstract

摘要： 简要介绍了对称型双子表面活性剂的合成原理,包括极性头基加入法、疏水链加入法和联接链加入法;详细综述了各种对称型双子表面活性剂按照不同原理的合成路线,包括阳离子型双子表面活性剂、阴离子型双子表面活性剂、非离子型双子表面活性剂、两性离子型双子表面活性剂、具有特殊结构和功能的双子表面活性剂及多聚体等;简单总结了各种合成路线的优缺点,并对对称型双子表面活性剂的发展趋势和应用前景进行了展望。

关键词: 对称型双子表面活性剂, 合成方法, 特殊功能, 研究进展

Abstract: Principles for synthesis of symmetric gemini surfactants,including polar head group addition method,hydrophobic chain addition method and coupling chain addition method were briefed.Synthesis routes for various types of symmetric gemini surfactants including cationic gemini surfactants,anionic gemini surfactants,nonionic gemini surfactants,zwitterionic gemini surfactants,as well as gemini surfactants with special structures and functions and their polymers prepared in accordance with different principles were described in detail.A brief summary of the advantages and disadvantages of various synthesis routes was listed and development trends and application of symmetric gemini surfactants were prospected.

Key words: symmetric gemini surfactant, synthetic method, special features, research progress

中图分类号:

TQ423

侯宝峰, 王业飞, 刘宏刚, 王桂杰. 对称型双子表面活性剂的合成研究进展[J]. 日用化学工业, 2014, 44(2): 94-99.

HOU Bao-feng, WANG Ye-fei, LIU Hong-gang, WANG Gui-jie. Progress in research work with respect to synthesis of symmetric gemini surfactants[J]. China Surfactant Detergent & Cosmetics, 2014, 44(2): 94-99.

参考文献

[1] 唐善法,刘忠运,胡小冬.双子表面活性剂研究与应用[M].北京:化学工业出版社,2011:22.
[2] ROSEN M J,KUNJAPPU J T.Surfactants and interfacial phenomena[M].New York:John Wiley & Sons,Inc,2004:415.
[3] MENGER F M,KEIPER J S.Gemini surfactants[J].Angew Chem Int Ed,2000,39:1907-1920.
[4] ZANA R,XIA J.Gemini surfactants:Synthesis,interfacial and solution-phase behavior,and applications[M].New York:CRC Press,2003:10.
[5] 姚志钢,李干佐,董凤兰,等.Gemini表面活性剂合成进展[J].化学进展,2004,16(3):349-364.
[6] 胡廷峰,郭祥峰,贾丽华.阳离子双子表面活性剂的应用研究进展[J].精细与专用化学品,2006,14(11):1-4.
[7] 唐善法,王力,郝明耀,等.双子表面活性剂(C_12-2-12·2Br^-1)表面活性与驱油效率研究[J].钻采工艺,2007,30(4):127-129.
[8] 陈功,黄鹏程,马云容,等.一种双子表面活性剂的合成[J].精细化工,2001,18(8):440-442.
[9] QIU LINGGUANG,XIE ANJIAN,SHEN YUHUA.Synthesis and surface activity of novel triazole-based cationic gemini surfactants[J].Chinese Chemical Letters,2003,14(6):653-656.
[10] 刘忠运,陆锋锋.新型双子表面活性剂在三次采油中的应用研究[J].化工科技,2009,17(6):82-85.
[11] LIU X P,FENG J,ZHANG L,et al.Synthesis and properties of a novel class of anionic gemini surfactants with polyoxyethylene spacers[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2010,362(1):39-46.
[12] 谢亚杰.磺酸系双子表面活性剂的合成与分离[J].浙江大学学报:理学版,2004,31(3):306-308.
[13] 黄智,李成海,梁宇宁,等.N,N′-双月桂酰基乙二胺二乙酸钠合成方法的改进[J].精细化工,2002,19(1):1-3.
[14] YOSHIMURA T,ISHIHARA K,ESUMI K.Sugar-based gemini surfactants with peptide bonds synthesis,adsorption,micellization,and biodegradability[J].Langmuir,2005,21(23):10409-10415.
[15] SAKAI K,UMEZAWA S,TAMURA M,et al.Adsorption and micellization behavior of novel gluconamide-type gemini surfactants[J].Journal of Colloid and Interface Science,2008,318(2):440-448.
[16] FIELDEN M L,PERRIN C,KREMER A,et al.Sugar-based tertiary amino gemini surfactants with a vesicle-to-micelle transition in the endosomal pH range mediate efficient transfection in vitro[J].Eur J Biochem,2001,268(5):1269-1279.
[17] 杨青,曹丹红,方波,等.一种新型双联两性表面活性剂的合成与性能[J].高校化学工程学报,2009,23(1):110-115.
[18] 郑延成.两性孪联表面活性剂的合成及其协同效应[J].石油化工高等学校学报,2006,19(4):11-14,18.
[19] 齐丽云,种名伟,方云,等.α-癸基甜菜碱两性表面活性刑复配行为研究[J].日用化学工业,2009,39(1):1-4.
[20] 唐善法,刘忠运,胡小冬.双子表面活性剂研究与应用[M].北京:化学工业出版社,2011:45-46.
[21] ODA R,HUC I,DANINO D,et al.Aggregation properties and mixing behavior of hydrocarbon fluorocarbon and hybrid hydrocarbon-fluorocarbon cationic dimeric surfactants[J].Langmuir,2000,16(25):9759-9769.
[22] OHNO A,KUSHIYAMA A,KONDO Y,et al.Synthesis and properties of gemini-type hydrocarbon-fluorocarbon hybrid surfactants[J].Journal of Fluorine Chemistry,2008,129(7):577-582.
[23] HU Y M.Synthesis and properties of a series of novel cationic fluoro surfactants[J].Advanced Materials Research,2012,512:2329-2332.
[24] 王军,栾立辉,杨许召,等.季铵盐双子表面活性剂的合成和表面活性[J].精细化工,2009,26(1):14-17.
[25] LASCHEWSKY A,WATTEBLED L,AROTCARENA M.Synthesis and properties of cationic oligomeric surfactants[J].Langmuir,2005,21:7170-7179.
[26] QIU L G,XIE A J,SHEN Y H.A novel triazole-based cationic gemini surfactant:synthesis and effect on corrosion inhibition of carbon steel in hydrochloric acid[J].Materials Chemistry and Physics,2005,91(2):269-273.
[27] SHUKLA D,TYAGI V K.Cationic gemini surfactants:a review[J].Journal of Oleo Science,2006,55(8):381-390.
[28] ZHU S,CHENG F,WANG J,et al.Anionic gemini surfactants:synthesis and aggregation properties in aqueous solutions[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2006,281(1):35-39.
[29] ZHOU T,YANG H,XU X,et al.Synthesis,surface and aggregation properties of nonionic poly (ethylene oxide) gemini surfactants[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2008,317(1):339-343.