金属酞菁类化合物的制备及应用研究进展

doi:10.3969/j.issn.2097-2806.2025.02.013

摘要/Abstract

摘要：

金属酞菁类催化剂具有稳定性好、大平面的共轭结构、配位灵活等优点，但在实际应用中与大多数溶剂的溶解性差的缺点影响了其应用范围。介绍了近年来单核以及多核金属酞菁类化合物的研究进展，包括单核/多核金属酞菁类化合物的固相法以及液相法的制备以及在脱硫醇、降解污染物、电催化等方面的相关应用研究，并对单/双核金属酞菁类化合物的发展及应用的前景进行了展望，提出对于金属酞菁类化合物存在的生产应用中的问题，以及后续研究应着重于材料的结构设计以及回收利用。

关键词: 金属酞菁, 制备, 溶解性, 催化剂

Abstract:

Metal phthalocyanine catalysts have the advantages of good stability, large planar conjugated structures, and flexible coordination. However, their poor solubility compared to most solvents in practical applications affects their application range. The research progress in single core and multi-core metal phthalocyanine compounds in recent years are reviewed, including the preparation of single core/multi-core metal phthalocyanine compounds by solid-phase and liquid-phase methods, as well as the related application research in thiol removal, pollutant degradation, electrocatalysis, etc. It also looks forward to the development and application prospects of single/binuclear metal phthalocyanine compounds, and poses questions about the practical applications in the production of metal phthalocyanine compounds. Subsequent research should focus on the structural design and recycling of materials.

Key words: metal phthalocynine, preparation, solubility, catalyst

中图分类号:

TQ426

陈苏翰,杨效益,李建波,任晓丹,张和平. 金属酞菁类化合物的制备及应用研究进展[J]. 日用化学工业（中英文）, 2025, 55(2): 235-243.

Suhan Chen,Xiaoyi Yang,Jianbo Li,Xiaodan Ren,Heping Zhang. Research progress on preparation and application of metal phthalocyanine[J]. China Surfactant Detergent & Cosmetics, 2025, 55(2): 235-243.

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表1

金属酞菁材料汇总"

	制备	应用	特点	引用文献
氯代酞菁钴	苯酐为原料在DMF溶剂中微波加热合成	汽油的脱硫醇	通过控制氯离子的取代量调控催化性能	[21]
四羟基酞菁铝/碳纳米管复合材料	苯酐为原料，硝基苯为溶剂液相合成	燃油中乙硫醇的脱除	负载在碳纳米管上可增强催化活性	[22]
N-苄基化酞菁钴四磺酰胺	苯酐为原料，硝基苯为溶剂液相合成	氧化脱硫催化剂	通过苄基化加强了材料的油溶性	[23]
双核金属酞菁（Fe、Co、Zn）碳纳米管复合材料	邻苯二甲腈为原料，溶剂为DMAE液相合成	脱除模型燃油中的二苯并噻吩	具有良好的分散性和光催化活性	[24]
聚合金属酞菁（Mn、Fe、Co、Ni、Cu、Zn）	苯酐为原料，煤油为溶剂液相合成	脱除噻吩	材料催化活性随着酞菁环共轭体系增加而提高	[25]
μ-硝基二铁四叔丁基酞菁铁	邻苯二甲腈为原料，正戊醇为溶剂液相合成	降解氯代苯酚以及含氟芳香族化合物等卤代污染物	能与双氧水生成使全氟芳烃脱氟的高价二铁氧	[26]
酞菁锌与4,6-二氨基间苯二酚二盐酸盐的共轭微孔聚合物	偏苯三酸酐为原料，固相合成	催化降解罗丹明B等的有机染料污染物	不易聚集、光催化活性高、易回收	[8]
四羧基酞菁锌复合在金纳米金属硅胶	邻苯二甲腈为原料，正戊醇为溶剂液相合成	光催化降解橙黄G和甲基橙等有机污染物	催化完可通过简单的过滤分离	[27]
羧基取代多核金属酞菁钴	偏苯三酸酐为原料，固相法合成	对溶液中硫化钠、硫代硫酸钠、苯酚的催化氧化	可在有光及无光条件下催化氧化硫化钠	[28]
键合型六羧基双核金属酞菁	苯三酸酐为原料固相法制备	处理废水中的甲基橙	带有高度有序的孔道结构	[29]
八甲氧基酞菁镍与碳纳米管复合材料	邻苯二甲腈为原料，亚砜为溶剂液相合成	催化CO₂转化为CO	负载后的酞菁镍稳定性更高	[30]
酞菁铜负载在炭黑上	邻苯二甲酸酐为原料，固相法合成	将CO₂高选择性电化学还原为C₂H₄	通过调控催化剂结晶度可控制反应的选择性	[31]
八烷氧基酞菁钴负载在石墨烯	4, 5-二氯邻苯二甲腈为原料，DMAE为溶剂液相法合成	催化CO₂转化为CO	烷氧基的取代可以抑制酞菁钴的聚集	[31]

表1

参考文献 32

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