氟表面活性剂和氟聚合物(Ⅸ)——全氟磺酸树脂和全氟磺酸离子交换膜

doi:10.13218/j.cnki.csdc.2016.09.002

日用化学工业 ›› 2016, Vol. 46 ›› Issue (9): 494-501.doi: 10.13218/j.cnki.csdc.2016.09.002

氟表面活性剂和氟聚合物(Ⅸ)——全氟磺酸树脂和全氟磺酸离子交换膜

窦增培^1,3,白富栋²,邢航^1,3,肖进新^1,3

1.北京氟乐邦表面活性剂技术研究所,北京 100096;
2.中国石化抚顺石油化工研究院,辽宁抚顺 113001;
3.陇东学院化学化工学院陇东学院-氟乐邦表面活性剂工程技术中心,甘肃庆阳 745000

出版日期:2016-09-22 发布日期:2019-04-18
通讯作者: 肖进新,教授,博士,电话:(010)62561871,E-mail:xiaojinxin@pku.edu.cn。
作者简介:窦增培(1983-),男,北京人,博士,电话:(010)62561871,E-mail:douzengpei@pku.edu.cn。

Fluorinated surfactants and fluoropolymers (Ⅸ) Perfluorosulfonic acid resin and perfluorosulfonate ion-exchanged membrane

DOU Zeng-pei^1,3,BAI Fu-dong²,XING Hang^1,3,XIAO Jin-xin^1,3

1.Beijing FLUOBON Surfactant Institute,Beijing 100096,China;
2.Fushun Research Institute of Petroleum and Petrochemicals,SINOPEC,Fushun,Liaoning 113001,China;
3.Longdong University-FLUOBON Surfactant Engineering Technology Center,College of Chemistry & Chemical Engineering,Longdong University,Qingyang,Gansu 745000,China

Online:2016-09-22 Published:2019-04-18

摘要/Abstract

摘要： 全氟磺酸树脂(PFAR)及其前体全氟磺酰氟树脂(PFSR),以及由其为基材制备的全氟磺酸离子交换膜(PFSIEM)是重要的氟化工产品,在氯碱工业、燃料电池、化工生产和国防安全等领域有重要应用。介绍了PFSR,PFAR和PFSIEM的发展历程、产品种类、制备方式、加工方法、表征方法和产品应用,并对其研究热点及我国在该领域的发展进行了展望。

关键词: 氟聚合物, 全氟磺酸树脂, 全氟磺酰氟树脂, 全氟磺酸离子交换膜, 燃料电池

Abstract: Perfluorosulfonic acid resin (PFAR) and its precursor,perfluorinated sulfonyl fluoride resin (PFSR),as well as perfluorosulfonate ion-exchanged membrane (PFSIEM) derived from them are important fluorinated chemical products.They play key roles in the fields of chlor-alkali industry,fuel cell,chemical production as well as national defense and state security.Herein,the development course,type of products,way for the preparation and method for the processing,the characterization methods as well as applications of PFSR,PFAR and PFSIEM were described.Finally,the focused points in the research work field as well as outlook for the development in China were presented.

Key words: fluoropolymers, perfluorosulfonic acid resin, perfluorinated sulfonyl fluoride resin, perfluorosulfonate ion-exchanged membrane, fuel cell

中图分类号:

TQ423.4

窦增培,白富栋,邢航,肖进新. 氟表面活性剂和氟聚合物(Ⅸ)——全氟磺酸树脂和全氟磺酸离子交换膜[J]. 日用化学工业, 2016, 46(9): 494-501.

DOU Zeng-pei,BAI Fu-dong,XING Hang,XIAO Jin-xin. Fluorinated surfactants and fluoropolymers (Ⅸ) Perfluorosulfonic acid resin and perfluorosulfonate ion-exchanged membrane[J]. China Surfactant Detergent & Cosmetics, 2016, 46(9): 494-501.

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氟表面活性剂和氟聚合物(Ⅸ)——全氟磺酸树脂和全氟磺酸离子交换膜

Fluorinated surfactants and fluoropolymers (Ⅸ) Perfluorosulfonic acid resin and perfluorosulfonate ion-exchanged membrane

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