N,N'-对苯二亚甲基-双(十二烷基二甲基氯化铵)/AEO9复配体系表面活性研究

doi:10.13218/j.cnki.csdc.2016.07.006

Abstract

Abstract: Cationic Gemini surfactants N,N'-p-xylylene-bis-(dodecyldimethylammonium chloride) (XBDDMA) were synthesized by 1,4-bis-(chloromethyl)-benzene (XDC) and dimethyldodecylamine.The chemical structure of the purified product was confirmed by FT-IR,¹H NMR and ¹³C NMR.The XBDDMA and AEO₉ were blended with different molar ratio,as well as the critical micellar concentration (cmc),equilibrium surface tension (γ_cmc) and dynamic surface tension of the blend system were studied.The results showed that as n(XBDDMA)∶n(AEO₉) is at the range of 1∶9 - 9∶1,following the increase of content of XBDDMA,the cmc of the blend system decreases firstly and then increases,while the area occupied by the surfactant (A_min ) decreases continuously.When n(XBDDMA)∶n(AEO₉)=1∶1,the cmc of the blend system is the smallest,which is 2.27×10^-6 mol/L,and the γ_cmc is 33.06 mN/m,which is also the smallest.The addition of XBDDMA reduces the initial diffusion energy,which reduces the dynamic surface activity of AEO₉,and there is no synergism effect on the dynamic surface activity between XBDDMA and AEO₉.

Key words: quaternary ammonium salt, Gemini surfactant, blend system, synergistic effect, dynamic surface tension

CLC Number:

TQ423

LI Gang-sen,ZHAO Lin-xiu,WANG Pei-yi,SU Hao,ZHAI Jia-bin,JIANG Dong-fang. Study on surface activity of N,N'-p-xylylene-bis- (dodecyldimethylammonium chloride)/AEO₉ blend systems[J].China Surfactant Detergent & Cosmetics, 2016, 46(7): 392-396.

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Study on surface activity of N,N'-p-xylylene-bis- (dodecyldimethylammonium chloride)/AEO₉ blend systems

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Study on surface activity of N,N'-p-xylylene-bis- (dodecyldimethylammonium chloride)/AEO9 blend systems

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Study on surface activity of N,N'-p-xylylene-bis- (dodecyldimethylammonium chloride)/AEO₉ blend systems