甜菜碱型表面活性剂纳米乳液的构建及性能评价

doi:10.3969/j.issn.2097-2806.2026.02.008

Abstract

Abstract:

To solve the problems of high injection pressure and low injection efficiency during the process of water flooding, three nanoemulsion systems（S-S12, S-S16, and S-C16）for pressure reduction and injection stimulation were developed. Their stability, particle size morphology, interfacial tension, wetting ability, stripping ability, and performance of reducing pressure and increasing injection were evaluated. Laboratory evaluation results showed that all the three nanoemulsion systems had good stability, nano-sized droplets（all less than 350 nm）, and low oil-water interfacial tension. Among them, the interfacial tension between 0.1% S-S16 nanoemulsion and crude oil reached an ultra-low level, which changed the wettability of the core surface from lipophilic to weakly hydrophilic. It was also the best one for stripping crude oil, leading to a 48% reduction in carbon content. In addition, the injection of S-S16 nanoemulsion system after water flooding in natural cores could lead to a 78.70% reduction in the replacement pressure, which achieved efficient performance in pressure reduction and injection stimulation.

Key words: nanoemulsion, betaine, interfacial tension, pressure reduction and injection stimulation

CLC Number:

TQ423

Chunsheng Zhang, Changlong Liu, Bin Chen, Yanyue Li, Fantao Meng, Peng Zhao. Preparation and performance evaluation of the nanoemulsions stabilized with betaine surfactants[J].China Surfactant Detergent & Cosmetics, 2026, 56(2): 201-207.

Figures/Tables 12

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References 21

[1]	宋文, 许飞. 低渗透油藏注水井表面活性剂降压增注体系研究[J]. 化学与生物工程, 2021, 38(4): 48-51.
[2]	张小东, 吴磊磊, 周升沦. 低渗油藏注水井欠注原因分析及增注措施[J]. 清洗世界, 2019, 35(4): 43-44.
[3]	吕文斌, 王博, 曹耀平, 等. 低渗透油藏注水井纳米微乳液降压增注体系研究[J]. 当代化工, 2022, 51(2): 370-373.
[4]	姚约东, 葛家理, 魏俊之. 低渗透油层渗流规律的研究[J]. 石油勘探与开发, 2001, 28(4): 73-75.
[5]	李璐, 孔瑞江, 李婵, 等. 低孔低渗油藏纳米乳液降压增注研究[J]. 当代化工, 2022, 51(11): 2541-2544.
[6]	徐娜, 刘卫东. 季铵盐型孪连表面活性剂G-52的降压增注效果[J]. 油田化学, 2007, 24(2): 138-142.
[7]	熊建华, 李庆彤, 陶剑清, 等. 注水井纳米降压增注工艺的应用与认识[J]. 石油钻采工艺, 2010, 7(4): 78-80.
[8]	董小刚, 黄哲, 聂安琪, 等. 纳米乳液降压增注技术研究与试验[J]. 精细石油化工, 2022, 39(1): 53-57.
[9]	王正权, 解统平, 张怀杰, 等. 适合特低渗透油藏注水井降压增注的纳米乳液体系研究[J]. 能源化工, 2021, 42(5): 45-48.
[10]	周勤. 低渗透油藏纳米乳液降压增注研究[J]. 油气藏评价与开发, 2016, 6(6): 61-66.
[11]	吴宇航, 龚辉, 夏康杰, 等. 一种纳米硅型微乳液对低渗透油藏降压增注适应性研究[J]. 钻采工艺, 2020, 43(2): 111-114. doi: 10.3969/J. ISSN.1006-768X.2020.02.30
[12]	王伟琳, 李应成, 徐岩光, 等. 原位微乳液表活剂体系研制及在降压增注中的应用[J]. 大庆石油地质与开发, 2021, 40(2): 116-122.
[13]	Kaushik A, Joshi D, Saw R K, et al. Formation and characterization of nanoparticle assisted surfactant stabilized oil-in-water nanoemulsions for application in enhanced oil recovery[J]. Fuel, 2024, 359: 130500. doi: 10.1016/j.fuel.2023.130500
[14]	Wu Y, Zou C, Hu A, et al. Alternative method of injection of nanoemulsion for intensifying coalbed methane recovery[J]. Langmuir, 2025, 41: 8574-8581. doi: 10.1021/acs.langmuir.4c04900
[15]	Zan Y, Wu Y, Ran D, et al. Nano-emulsion stabilized by multiple surfactants: An effective alternative for enhancing coal seam water injection effect[J]. Journal of Molecular Liquids, 2024, 398: 124150. doi: 10.1016/j.molliq.2024.124150
[16]	Qi J, Ge Y, Li Q P, et al. Sustainable and cleaner approach for paraffin wax treatment via CO₂-induced polarity transformation of switchable solvents[J]. Journal of Cleaner Production, 2023, 396: 136500. doi: 10.1016/j.jclepro.2023.136500
[17]	袁俊秀, 王康. 纳米乳液驱油体系性能评价及驱油机理分析[J]. 能源化工, 2016, 37(3): 47-49.
[18]	Liu D, Xu J, Zhao H, et al. Nanoemulsions stabilized by anionic and non-ionic surfactants for enhanced oil recovery in ultra-low permeability reservoirs: Performance evaluation and mechanism study[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2022, 637: 128235. doi: 10.1016/j.colsurfa.2021.128235
[19]	赵学之, 廖广志, 刘卫东, 等. 表面活性剂驱油机理研究新进展:胶束增溶和原位乳化[J]. 中国科学:化学, 2023, 53(7): 1088-1103.
[20]	李相方, 冯东, 张涛, 等. 毛细管力在非常规油气藏开发中的作用及应用[J]. 石油学报, 2020, 41: 1719-1733. doi: 10.7623/syxb202012024
[21]	郭宏亮, 张立萍, 安继彬, 等. 界面张力及乳化效果对提高采收率的贡献[J]. 石油化工, 2019, 48(4): 381-385.

微乳液类型	m(表面活性剂)/g	助表面活性剂	m(水)/g	m(白油5#)/g	m(正己烷)/g
S-S12	2.5	3.75 g ZJ-1醇	2.5	1.25	-
S-S16	3.2	4.80 g ZJ-1醇	1	2	-
S-C16	1.8	2.70 g ZJ-2醇	2	-	1

类型	w/%	界面张力/（mN/m）	水相粘附功/（J/m²）
S-S16	0.1	0.006	0.10
S-S12	0.1	0.003	0.08
S-C16	0.1	0.030	0.07

岩心编号	大小/cm	孔隙度/%	渗透率/mD	降压率/%
HL-1	30.1×4.48×4.44	24.83	1 544	54.82
HL-2	30.1×4.48×4.48	25.36	1 544	72.73
HL-3	30.1×4.46×4.48	26.25	1 544	78.70

Preparation and performance evaluation of the nanoemulsions stabilized with betaine surfactants

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