二氧化钛@氢氧化铝-海藻酸钠复合纳米颗粒的制备及其在防晒霜中的应用

doi:10.3969/j.issn.2097-2806.2025.12.010

Abstract

Abstract:

Titanium dioxide@aluminum hydroxide-sodium alginate composite nanoparticles （Ti@Al-SA NPs） were prepared through the electrostatic adsorption between titanium dioxide@aluminum hydroxide and sodium alginate （SA）. Subsequently, these composite nanoparticles were dispersed into a slurry, and the slurry was further formulated into a sunscreen lotion. The mechanism of SA adsorption on the surface of Ti@Al NPs was studied using Zeta potential measurement. Thermogravimetric analysis （TGA） was used to determine the adsorption amount. Polarizing microscopy was employed to observe the emulsion morphology. Rheological properties were investigated using a rheometer, and the sun protection factor （SPF） of the emulsion was tested using an SPF meter. Additionally, thermal shock tests were conducted to evaluate the stability of emulsions. The results indicated that the adsorption interaction between SA and Ti@Al NPs was the strongest at pH of 5. The adsorption amount of SA in the Ti@Al-SA0.2 NPs thus prepared was 14.2%. The corresponding aqueous slurry was prepared with Ti@Al-SA0.2 NPs in a solid content of 25.0%, achieving a viscosity of 954.8 mPa·s. The SPF of the prepared emulsion reached a maximum of 22.5. After five heating-cooling cycles, the emulsion did not break and its viscosity maintained at more than 80% of the original viscosity, with the SPF remaining above 95% of the original value.

Key words: titanium dioxide, sodium alginate, electrostatic adsorption, nanocomposite, sunscreen cosmetics

CLC Number:

TQ658

Huamin Liu, Yue Cai, Junjie Nian, Fengqin Wu, Chao Yao, Haoguan Gui. Preparation of titanium dioxide@aluminum hydroxide-sodium alginate composite nanoparticles and their application in sunscreen lotions[J].China Surfactant Detergent & Cosmetics, 2025, 55(12): 1575-1581.

Figures/Tables 10

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组分	原料	用量/%	功能
A相	鲸蜡硬脂醇	1.1	乳化剂
	甘油硬脂酸酯	1.5	乳化剂
	鲸蜡醇磷酸酯钾	2.5	增稠剂
	丁基辛醇水杨酸酯	2.0	乳化剂
	新戊二醇二庚酸酯	6.0	润肤剂
	聚二甲基硅氧烷	2.0	润肤剂
	异十二烷	8.0	润肤剂
	碳酸二乙基己酯	10.0	润肤剂
	红没药醇	0.5	保湿剂
	维生素E	0.4	保湿剂
B相	去离子水	40.5	溶剂
	丁二醇	10.0	保湿剂
	Ti@Al-SA	12.5	防晒剂
	聚丙烯酸酯交联聚合物-6	0.6	增稠剂
	甘草酸二钾	0.8	保湿剂
	1, 2-己二醇	1.0	保湿剂
C相	苯氧乙醇	0.6	防腐剂

Preparation of titanium dioxide@aluminum hydroxide-sodium alginate composite nanoparticles and their application in sunscreen lotions

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