磁性表面活性剂的研究进展

doi:10.3969/j.issn.1001-1803.2021.06.012

Abstract

Abstract:

Magnetic surfactants are a kind of surfactants with both surface activity and magnetic response. The properties of the surfactants can be simply controlled by the “on” and “off” of external magnetic fields. The structure, synthesis, properties and application of magnetic surfactants are reviewed. The counterions with magnetic response and surface active ions can be combined by electrostatic attraction or complexation. Magnetic surfactants have better surface properties than nonmagnetic parent surfactants, such as lower surface tension and smaller cmc. The surface tension of aqueous solutions of magnetic surfactants can be further reduced by external magnetic field. The magnetic moment of a magnetic surfactant is mainly determined by metal ions, and the magnetic moment of alkyl trimethyl ammonium magnetic surfactant is greater than that of alkyl imidazole magnetic surfactant. Magnetic surfactants exhibit unique properties in drug delivery, microemulsion, nanomaterials and sterilization, which indicates that this kind of surfactants have good development prospect.

Key words: magnetic surfactant, surface activity, synthesis, application

CLC Number:

TQ423

WANG Jun,ZHANG Chen-long,YANG Xu-zhao,BAI Ya-rong. Research progress of magnetic surfactants[J].China Surfactant Detergent & Cosmetics, 2021, 51(6): 546-553.

Figures/Tables 4

Fig. 1

Tab. 1

Tab. 2

Tab. 3

References 33

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表面活性剂	cmc/（mmol·L^-1）	γ_cmc/（mN·m^-1）	文献
[C₁₀TA][GdCl₃Br]	48	/	[22]
[C₁₀MIM][FeCl₄]	40.6	/	[4]
[C₁₂TA][FeCl₃Br]	13.6	/	[4]
[2C₁₂DA][FeCl₃Br]	0.06	/	[4]
[ProC₁₀][FeCl₃Br]	0.02	33.9	[16]
[C₁₄TA][FeCl₃Br]	2.46	39.57	[17]
[C₁₄TA][CeCl₃Br]	2.52	40.67	[17]
[C₁₄TA][GdCl₃Br]	3.27	40.48	[17]
[C₁₆TA][FeCl₃Br]	0.713	39.89	[17]
[C₁₆TA][CeCl₃Br]	0.797	39.69	[17]
[C₁₆TA][GdCl₃Br]	0.698	39.11	[22]
[C₁₈TA][FeCl₃Br]	0.188	38.97	[17]
[C₁₈TA][CeCl₃Br]	0.231	38.62	[17]
[C₁₈TA][GdCl₃Br]	0.240	39.79	[17]
[14-2-14][Br]₂	0.140	31.42	[17]
[14-2-14][FeCl₃Br]₂	0.106	31.14	[17]
[14-2-14][CeCl₃Br]₂	0.109	31.58	[17]
[14-2-14][GdCl₃Br]₂	0.146	30.65	[17]
[16-2-16][Br]₂	0.020 9	38.26	[17]
[16-2-16][FeCl₃Br]₂	0.019 4	34.95	[17]
[16-2-16][CeCl₃Br]₂	0.014 9	33.77	[17]
[16-2-16][GdCl₃Br]₂	0.015 4	31.07	[17]

表面活性剂	无磁场时γ_cmc/（mN·m^-1）	有磁场时γ_cmc/（mN·m^-1）	表面张力变化率/%	文献
[C₁₂TA][Br]	37.3	38.6	+3.5	[14]
[C₁₂TA][HoCl₃Br]	32.6	31.3	-4.0	[14]
[C₁₂TA][GdCl₃Br]	33.2	29.9	-9.4	[14]
[C₁₂TA][CeCl₃Br]	28.8	29.3	+1.7	[14]
[C₁₀MIM][Cl]	39.8	41.0	+3.0	[14]
[C₁₀MIM][FeCl₄]	38.4	34.8	-9.4	[4]
[C₁₀MIM][HoCl₄]	33.1	29.1	-12.1	[14]
[C₁₀MIM][GdCl₄]	37.8	35.1	-7.1	[14]
[C₁₀MIM][CeCl₄]	39.1	40.3	+3.1	[14]

表面活性剂阳离子	表面活性剂阴离子	χ_mT/（emu·K·mol^-1·Oe^-1）	μ_eff/μ_B	θ_cw/K	T_c/K	T_N/K	文献
[C₁₂TA]⁺	[HoCl₃Br]^-	10.15	9.05	4.09	5.1		[14]
[C₁₂TA]⁺	[GdCl₃Br]^-	6.89	7.45	0.06			[14]
[C₁₂TA]⁺	[CeCl₃Br]^-	0.43	1.86	-60		12.2	[14]
[C₁₀MIM]⁺	[HoCl₄]^-	8.55	8.41	2.78			[14]
[C₁₀MIM]⁺	[GdCl₄]^-	6.41	7.19	-0.78			[14]
[C₁₀MIM]⁺	[CeCl₄]^-	0.32	1.61	-72		12.2	[14]
[C₁₀MIM]⁺	[FeCl₄]^-	4.01		-3.3			[15]
[C₁₄PC6₃]⁺	[FeCl₄]^-	4.34		-0.8			[15]
[C₁₄PC6₃]⁺	[CoCl₄]^2-	2.48		-3.7			[15]
[C₁₄PC6₃]⁺	[MnCl₄]^2-	4.22		-0.1			[15]
[C₁₄PC6₃]⁺	[Co（NCS）₄]^{2 -}	2.06		-0.2			[15]
[C₁₄PC6₃]⁺	[GdCl₆]^3-	7.72		-0.2			[15]

Research progress of magnetic surfactants

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