N-酰基氨基酸型表面活性剂与离子液体表面活性剂复配体系流变性研究

doi:10.3969/j.issn.1001-1803.2020.10.005

Abstract

Abstract:

The interactions between an ionic liquid surfactant （1-tetradecyl-3-methylimidazolium bromine, [C₁₄Mim][Br]） and three N-acyl amino acid surfactants （sodium lauroyl sarcosinate （SLS）, sodium lauroyl glutamate （SLGLU） and sodium lauroyl glycinate （SLG））, and the rheology of the mixed aqueous systems of [C₁₄Mim][Br]/SLS and [C₁₄Mim][Br]/SLGLU with different mole fractions （x） of [C₁₄Mim][Br] were studied by the determination of surface tension and rheology. Except SLG, the N-acyl amino acid surfactants under investigation showed a good formulation stability when mixed with [C₁₄Mim][Br]. The surface tension of mixed solutions of [C₁₄Mim][Br]/SLS and [C₁₄Mim][Br]/SLGLU were both indicative of synergistic effect. The synergistic effect between [C₁₄Mim][Br] and SLGLU was larger than that between [C₁₄Mim][Br] and SLS, and the optimum x were 0.7 and 0.5, respectively. When a series of aqueous solutions of [C₁₄Mim][Br]/SLS and [C₁₄Mim][Br]/SLGLU were tested by thixotropy, there was no thixotropic loop for the mixed solutions except the solutions of [C₁₄Mim][Br]/SLS at x=0.4-0.5 and the solution of [C₁₄Mim][Br]/SLGLU at x=0.7. The two series of aqueous solutions showed the characteristics of shear thinning, which might be related to the formation of vesicles in the mixed systems. Except for the mixed solution of [C₁₄Mim][Br]/SLS at x=0.5, no significant change was observed in the viscosity of the two mixed systems with shear time, indicative of good shear resistance.

Key words: surfactant, ionic liquid, amino acid, interaction, rheology

CLC Number:

TQ423

HUI Meng-meng,BAI Ya-rong,YANG Xu-zhao,ZHANG Chen-long,WANG Jun. Rheology of the mixed aqueous systems of N-acyl amino acid surfactant and ionic liquid surfactant[J].China Surfactant Detergent & Cosmetics, 2020, 50(10): 681-686.

Figures/Tables 10

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	n（AAS）∶n（[C₁₄Mim][Br]）
	0.8∶0.2	0.7∶0.3	0.6∶0.4	0.5∶0.5	0.4∶0.6	0.3∶0.7	0.2∶0.8	0.1∶0.9
SLS	+	+	+	+	+	+	+	+
SLGLU	+	+	+	+	+	+	+	+
SLG	-	-	-	-	-	-	-	+

Rheology of the mixed aqueous systems of N-acyl amino acid surfactant and ionic liquid surfactant

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