含硒表面活性剂n-庚基-硒-n-辛基硫酸酯钠的合成与性质

doi:10.3969/j.issn.1001-1803.2020.10.003

Abstract

Abstract:

The selenium-containing surfactants are functional surfactants with a redox-switchable divalent selenide group （-Se-） embedded in the hydrophobic tail. In order to further enrich the research of Se-containing surfactants, an anionic surfactant of sodium n-heptylselanyloctyl sulfate （C₇SeC₈SO₄Na） was synthesized. Its water solubility, reduction of gas-liquid and liquid-liquid interfacial tensions, foaming properties and emulsifying properties were studied. The reversible redox-response behavior of C₇SeC₈SO₄Na was investigated. The results showed that, the Krafft temperature of C₇SeC₈SO₄Na was （21.7±0.3） ℃, and its critical micelle concentration was 7.3×10^-4 mol/L （30 ℃, ring method）. C₇SeC₈SO₄Na was transformed into C₇SeOC₈SO₄Na after oxidation with H₂O₂because the selenide group in C₇SeC₈SO₄Na was oxidized to the selenoxide group. Compared with C₇SeC₈SO₄Na, C₇SeOC₈SO₄Na had better water solubility, but the abilities of reducing surface and/or interfacial tensions, foaming and emulsification were obviously worse. After reduction with Na₂SO₃, C₇SeOC₈SO₄Na was restored to its reduced form （C₇SeC₈SO₄Na）, and then the abilities of reducing surface and/or interfacial tensions, foaming and emulsification were recovered.

Key words: sodium n-heptylselanyloctyl sulfate, redox, reversible response

CLC Number:

TQ423

LIU De-qiong,ZHANG Yong-min,FAN Ye,LIU Xue-feng,FANG Yin-jun. Synthesis and properties of sodium n-heptylselanyloctyl sulfate[J].China Surfactant Detergent & Cosmetics, 2020, 50(10): 669-675.

Figures/Tables 6

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References 21

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Synthesis and properties of sodium n-heptylselanyloctyl sulfate

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