糖基双子阳离子表面活性剂与十二烷基硫酸钠复配性能研究

doi:10.3969/j.issn.1001-1803.2019.01.004

Abstract

Abstract:

The stability and surface activity of the blends of sugar-based cationic Gemini surfactants （SGCS） and sodium dodecyl sulfate （K₁₂） were studied. The results show that the blend systems being composed of K₁₂ and SGCS with different chain length have exhibited good stability in a wide rang of molar ratios of SGCS/K₁₂. For the mixture of C₁₄-SGCS/K₁₂, an obvious synergistic effect has been observed. The critical micelle concentration （cmc）, surface tension at cmc （γ_cmc） and the efficiency of reducing surface tension （pc₂₀） of the mixture of n（C₁₄-SGCS）∶n（K₁₂）=3∶5 are 1.1×10 ^-5 mol/L, 23.69 mN/m and 5.48, respectively, which are obviously superior to the performance of individual C₁₄-SGCS or K₁₂.

Key words: sugar-based surfactant, Gemini surfactant, cation, surface tension, blend

CLC Number:

TQ423.12

Jun WANG,Xu-zhao YANG,Ni-ni LI,Wen-yuan ZOU. Study of the performance of the blends of sugar-based cationic Gemini surfactants and sodium dodecyl sulfate[J].China Surfactant Detergent & Cosmetics, 2019, 49(1): 16-18.

Figures/Tables 5

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Tab. 1

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References 10

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复配体系	透光率/%
复配体系	1∶0	7∶1	3∶1	5∶3	1∶1	3∶5	1∶3	1∶7	0∶1
CTAB/K₁₂ C₁₆-SGCS/K₁₂	99.3 99.1	78.2 94.7	79.7 89.2	47.6 81.0	02.0 75.9	24.0 26.6	68.7 88.2	95.3 99.0	99.7 99.7

复配体系	透光率/%
复配体系	1∶0	7∶1	3∶1	5∶3	1∶1	3∶5	1∶3	1∶7	0∶1
C₁₀-SGCS/K₁₂ C₁₂- SGCS/K₁₂ C₁₄- SGCS/K₁₂ C₁₆- SGCS/K₁₂	100.0 100.0 100.0 099.1	99.8 99.6 99.1 94.7	98.2 97.9 94.3 89.2	92.6 86.4 83.9 81.0	84.8 77.3 76.4 74.9	54.6 53.2 49.2 26.6	99.1 97.3 95.0 88.2	99.6 99.2 99.1 99.0	99.7 99.7 99.7 99.7

	n（C₁₄-SGCS）∶n（K₁₂）
	1∶0	7∶1	5∶3	1∶1	1∶3	3∶5	1∶7	0∶1
cmc/（mmol·L^-1） γ_cmc/（mN·m^-1） pc₂₀	0.060 30.72 4.81	0.057 30.42 4.84	0.030 28.80 5.00	0.018 26.52 5.39	0.018 24.78 5.41	0.011 23.69 5.48	0.029 24.35 5.29	7.73 38.64 2.49

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Study of the performance of the blends of sugar-based cationic Gemini surfactants and sodium dodecyl sulfate

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