自交联丙烯酸酯乳液合成及在水性指甲油中的应用

doi:10.13218/j.cnki.csdc.2017.06.008

Abstract

Abstract: Self-crosslinking polyacrylic ester emulsion was synthesized by pre-emulsification polymerization method and a kind of water-based nail polish was prepared using the emulsion as basic material.Performance indices,such as hydrophilic and hydrophobic property as well as hardness and abrasion-proof etc of the film formed by the emulsion and other nail polish commodities were tested and compared.Results show that the self-crosslinking polyacrylic ester water-based nail polish can meet all the requirements for sensory and physical-chemical indices of QB/T 2287-2011.Its film contact angle reaches to 64.54° that indicating a better hydrophobicity as comparing with other non-crosslinked nail polish films.At the same time,its hardness reaches to HB pencil level,with the abrasion loss (100 r/min) of 34.58 mg and good adhesion level.Its conventional performance is excellent.As comparing with the solvent-based nail polishes,the self-crosslinking nail polish shows no corrosive effect on the nail,and safety in application can be achieved.

Key words: water-based nail polish, polyacrylic ester emulsion, self-crosslinking, hydrophilic and hydrophobic, corrosion

CLC Number:

TQ658.5+5

CHEN Xi-hui, WAN Xiang-long, MIN Fan-fei, HAO Guo-fang. Preparation and properties of self-crosslinking polyacrylic esteremulsion and its application in water-based nail polish[J].China Surfactant Detergent & Cosmetics, 2017, 47(6): 336-340.

References

[1] Iwegbue C M A.Safety evaluation of the metals in some brands of nail polish in Nigeria [J].Journal für Verbraucherschutz und Lebensmittelsicherheit,2016,11(3):271-278.
[2] Baumgardner C A,Maragos C S,Walz M J A,et al.Effects of nail polish on microbial growth of fingernails:dispelling sacred cows [J].AORN Journal,1993,58(1):84-88.
[3] Dimitris R,Ralph D.Management of simple brittle nails [J].Dermatologic Therapy,2012,25(6):569-573.
[4] 许海燕,孙伟,张兴元,等.基于水性聚氨酯分散体的环保无毒型水性指甲油的研制及应用[J].涂料技术与文摘,2016,37(5):34-37.
[5] Erie de La Poterie V.Aqueous nail polish containing as film-forming substance particles of polyester-polyurethane which are anionic in dispersion:US5538717 [P].1996-07-23.
[6] Socci R L,Ismailer A A,Castrogiovanni A.Nail enamel containing silicone-coated pigments:US4832944 [P].1989-05-23.
[7] Koch D,Rassek R.Water-based nail polish:US5120529 [P].1992-06-09.
[8] Ernest H,Michael R.Dictionary of toxicology [M].3rd ed.Boston:Academic Press,2015:263-294.
[9] Nam K H,Seo K,Seo J,et al.Ultraviolet-curable polyurethane acrylate nanocomposite coatings based on surface-modified calcium carbonate [J].Progress in Organic Coatings,2015,85:22-30.
[10] Herrera R,Muszyńska M,Krystofiak T,et al.Comparative evaluation of different thermally modified wood samples finishing with UV-curable and waterborne coatings [J].Applied Surface Science,2015,357:1444-1453.
[11] Pi Pihui,Wang Weixian,Wen Xiufang,et al.Synthesis and characteri-zation of low-temperature self-crosslinkable acrylic emulsion for PE film ink [J].Progress in Organic Coatings,2015,81:66-71.
[12] Nosrati R,Olad A,Nofouzi K.A self-cleaning coating based on commercial grade polyacrylic latex modified by TiO₂/Ag-exchanged-zeolite-A nanocomposite [J].Applied Surface Science,2015,346:543-553.
[13] 万祥龙,陈习惠,张启明,等.一种绿色环保指甲油及其制备方法:CN104473820A [P].2015-04-01.
[14] Koukiotis C G,Karabela M M,Sideridou I D.Mechanical properties of films of latexes based on copolymers BA/MMA/DAAM and BA/MMA/VEOVA-10/DAAM and the corresponding self-crosslinked copolymers using the adipic acid dihydrazide as crosslinking agent [J].Progress in Organic Coatings,2012,75(1):106-115.

Preparation and properties of self-crosslinking polyacrylic esteremulsion and its application in water-based nail polish

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