水热辅助相转移催化水解十二烷基苄氯的研究

doi:10.13218/j.cnki.csdc.2017.12.003

Abstract

Abstract: Hydrolysis of n-dodecylbenzyl chloride was preliminarily tested separately by means of ultrasonic wave,microwave,hydrothermal and phase transfer catalysis,and finally the hydrothermal-assisted phase transfer catalysis succeeded.Based upon the test results,the conclusion is to use dodecyldimethylbenzyl- ammonium chloride as the phase transfer catalyst and the reaction is conducted under alkaline condition with hydrothermal assistance at 130 ℃ for 16 h.The yield achieves 93.6%.

Key words: dodecylbenzyl chloride, hydrolysis, hydrothermal, phase transfer catalysis

CLC Number:

TQ423

SUN Mei-ling, HU Xue-yi, FANG Yun, FANG Yin-jun. Investigation for hydrolysis of dodecylbenzyl chloride by hydrothermal-assisted phase transfer catalysis[J].China Surfactant Detergent & Cosmetics, 2017, 47(12): 673-676.

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Investigation for hydrolysis of dodecylbenzyl chloride by hydrothermal-assisted phase transfer catalysis

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