一种新型吡啶Gemini表面活性剂的合成及表面活性

doi:10.13218/j.cnki.csdc.2016.04.003

Abstract

Abstract: The intermediate 1,3-di(3-pyridyl)urea was synthesized by the reaction of 3-aminopyridine and triphosgene.The optimized conditions for the reaction were found as follows:reaction solvent,methylene chloride;reaction time,5 h;mole ratio of 3-aminopyridine and triphosgene,5∶1.The yield is 78%.Then the intermediate reacted with bromododecane to produce a new type of Gemini pyridinium surfactant.The optimized conditions were identified as follows:reaction time,5 h;reaction temperature,110 ℃;mole ratio of the intermediate and bromododecane,1∶10.The yield is 90 %.The structure of the target product was characterized by FT-IR,¹H NMR,¹³C NMR and ESI-MS.The surface tension of the product was measured as cmc value of 1.67×10^-4 mol/L and γ_cmc of 30.7 mN/m.

Key words: cationic Gemini surfactant, pyridine, synthesis, surface tension

CLC Number:

TQ423.12

HAO Jun-sheng,WANG Pan,ZHANG Yue,ZHANG Yong-bin. Synthesis and surface activity of a novel Gemini pyridinium surfactant[J].China Surfactant Detergent & Cosmetics, 2016, 46(4): 195-199.

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Synthesis and surface activity of a novel Gemini pyridinium surfactant

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