氟表面活性剂和氟聚合物(Ⅳ) ——PFOS问题的应对策略

doi:10.13218/j.cnki.csdc.2016.04.002

Abstract

Abstract: Some fluorinated alkyl substances are necessary in nowadays many fields because of the special properties of fluorocarbon chains.However,the traditional environmental and toxicity problems of PFOS have to be resolved.Several ways for solving the concerning problems were discussed,including the possibilities for degradation,separation and recycling use,as well as reducing the concentration in the application to be lower than the specified limit.The most reliable one is to obtain substitute for the PFOS.Several kinds of substitute were introduced and their rationality of application was also discussed.

Key words: fluorocarbon surfactant, POPs, PFOA, bioaccumulation, toxicity, sustainability, regulation

CLC Number:

TQ423.4

XING Hang,JIA Xu-hong,XIAO Jin-xin. Fluorinated surfactants and fluoropolymers (Ⅳ) Strategy for PFOS problems[J].China Surfactant Detergent & Cosmetics, 2016, 46(4): 189-194.

References

[1] ZAGGIA A,AMEDURI B.Recent advances on synthesis of potentially non-bioaccumulable fluorinated surfactants [J].Curr Opin Colloid Interface Sci,2012,17(4):188-195.
[2] FROMEL T,KNEPPER T P.Biodegradation of fluorinated alkyl substances [J].Rev Environ Contam Toxicol,2010,208:161-177.
[3] 邢航,陈现涛,肖进新.氟表面活性剂和氟聚合物(Ⅱ):环境与安全问题[J].日用化学工业,2016,46(2):66-74.
[4] WANG Z,COUSINS I T,SCHERINGER M.Comment on “The environmental photolysis of perfluorooctanesulfonate,perfluorooctanoate,and related fluorochemicals” [J].Chemosphere,2015,122(301):301-303.
[5] CAMPBELL T,HOFFMANN M R.Sonochemical degradation of perfluorinated surfactants:Power and multiple frequency effects [J].Sep Purif Technol,2015,156:1019-1027.
[6] KRAFFT M P,RIESS J G.Per-and polyfluorinated substances (PFASs):Environmental challenges [J].Curr Opin Colloid Interface Sci,2015,20(3):192-212.
[7] YOUNG C J,MABURY S A.Atmospheric perfluorinated acid precursors:Chemistry,occurrence,and impacts [J].Rev Environ Contam Toxicol,2010,208:1-109.
[8] 罗梅清,卓琼芳,许振成,等.全氟化合物处理技术的研究进展[J].环境科学与技术,2015,38(8):60-67.
[9] 武晔,海热提.PFOS的禁用及其处理处置技术[J].环境科学与技术,2011,34(S1):352-357.
[10] 王媛,张彭义.全氟辛酸和全氟辛烷磺酸人体暴露途径解析及其污染控制技术[J].化学进展,2010,22(1):210-219.
[11] BAUDEQUIN C,COUALLIER E,RAKIB M,et al.Purification of firefighting water containing a fluorinated surfactant by reverse osmosis coupled to electrocoagulation-filtration [J].Sep Purif Technol,2011,76(3):275-282.
[12] BAUDEQUIN C,MAI Z H,RAKIB M,et al.Removal of fluorinated surfactants by reverse osmosis:Role of surfactants in membrane fouling [J].J Membr Sci,2014,458:111-119.
[13] SENEVIRATHNA S,TANAKA S,FUJII S,et al.Adsorption of perfluorooctane sulfonate (n-PFOS) onto non ion-exchange polymers and granular activated carbon:Batch and column test [J].Desalination,2010,260:29-33.
[14] 杨百勤,陈凯,邢航,等.以全氟丁基为基础的具有高表面活性的氟表面活性剂[J].物理化学学报,2009,25(12):2409-2412.
[15] 杨百勤,陈凯,邢航,等.N-(3-二甲氨基)丙基全氟烷基磺酰胺盐酸盐的表面活性[J].日用化学工业,2010,40(4):242-245.
[16] 陈蔚勤,邢航,肖进新.用于水成膜泡沫灭火剂的PFOS替代品的研究[C]//持久性有机污染物论坛2011暨第六届持久性有机污染物全国学术研讨会论文集.哈尔滨:清华大学持久性有机污染物研究中心,2011:188-189.
[17] LU R C,CAO A N,LAI L H,et al.Effect of anionic surfactant molecular structure on bovine serum albumin (BSA) fluorescence [J].Colloids Surf A,2006,278:67-73.
[18] 肖进新,邢航.氟表面活性剂和氟聚合物(Ⅰ):性能、合成(生产)及应用概述[J].日用化学工业,2016,46(1):13-20.
[19] 肖进新,赵振国.表面活性剂应用原理[M].北京:化学工业出版社,2015.
[20] 肖进新,罗妙宣,胡昌明,等.正、负离子碳氟-碳氢表面活性剂混合水溶液的表面活性[J].化学研究与应用,2000,12(3):304-306.
[21] 肖进新,姚军,高展.碳氟表面活性剂与水成膜泡沫灭火剂[J].化学研究与应用,2002,14(4):391-393.

Fluorinated surfactants and fluoropolymers (Ⅳ) Strategy for PFOS problems

PDF (PC)

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Metrics

Comments

Recommended 10

[1]	He Miao, Su Zhe, Hu Kang, Zhang Fenglan, Wang Gangli, Lu Yong. Discussion of cosmetic ingredient management and regulatory system of cosmetic ingredient safety information submission [J]. China Surfactant Detergent & Cosmetics, 2023, 53(9): 1080-1086.
[2]	Li Yitong, Sun Yanyan, Qiao Shaojun, Hou Lili, Li Manqin, Yu Yufeng. Effect of disinfectants on cell adhesion activity of recombinant type Ⅲ humanized collagen [J]. China Surfactant Detergent & Cosmetics, 2023, 53(7): 789-895.
[3]	Zhu Ting, Shen Qiruonan, Xu Yujuan, Li Chunmei. Application of chestnut shell pigment in hair dyes [J]. China Surfactant Detergent & Cosmetics, 2023, 53(5): 493-502.
[4]	Zhou Xinyu,Fan Meimei,Wen Xuehua,Dong Yinmao,Meng Hong,Guo Miaomiao. Research progress of the detection methods for cosmetic risk substances [J]. China Surfactant Detergent & Cosmetics, 2022, 52(4): 431-437.
[5]	Cao Xi,Chen Jiansheng,Liu Zuoren,Xie Zhijie,Chen Min. Comparative analysis and enlightenment of international cosmetics supervision modes [J]. China Surfactant Detergent & Cosmetics, 2022, 52(2): 190-198.
[6]	Su Zhe,Gao Jiamin,Li Lin,Niu Zhengrui,Li Yaping,Zhang Fenglan,Wang Gangli. A review on international regulatory progress and technical supervision of spray-sunscreen [J]. China Surfactant Detergent & Cosmetics, 2022, 52(1): 69-76.
[7]	Xue Wanting,Li Li,Dong Yinmao,Guo Miaomiao. Status and new development tendency of cosmetics whiteningefficacy evaluation [J]. China Surfactant Detergent & Cosmetics, 2021, 51(9): 890-896.
[8]	Qin Meirong,Xian Jingwen,Wu Xi,Zhang Gaofei,Wu Xiaoou,Wang Ping,Wang Xiaowei. Study on risk assessment and use regulation of nitromethane in cosmetics [J]. China Surfactant Detergent & Cosmetics, 2021, 51(8): 768-774.
[9]	LIU Lei,KONG Xue,TANG Ying. Application of a modified photo hen’s egg test to assess the phototoxicity of ultrafine titanium dioxide particles used in cosmetics [J]. China Surfactant Detergent & Cosmetics, 2021, 51(2): 115-120.
[10]	Xiao Zibing,Xing Hang,Dou Zengpei,Xiao Jinxin. Analysis about whether microorganisms that can effectively degrade fluorocarbon chains would appear in the natural environment [J]. China Surfactant Detergent & Cosmetics, 2021, 51(12): 1242-1249.
[11]	YUAN Huan,TANG Lin,CHEN Chao,ZHANG Feng-lan,WANG Gang-li. Comparative study of the new and old “Regulations on Supervision and Administration of Cosmetics” on the administration of cosmetics registration and notification [J]. China Surfactant Detergent & Cosmetics, 2020, 50(12): 879-884.
[12]	XING Hang,DOU Zeng-pei,XIAO Zi-bing,XIAO Jin-xin. Do we need to regard PFAS as evil? Our points of view [J]. China Surfactant Detergent & Cosmetics, 2020, 50(1): 49-53.
[13]	QIN Mei-rong,WANG Xiao-wei,WANG Ping. Progress and thought on the research of cosmetic genetic toxicity tests [J]. China Surfactant Detergent & Cosmetics, 2018, 48(10): 595-600.
[14]	YIN Yue-xuan, ZHAO Hua. Efficacy evaluation of cosmetics (Ⅰ) Scientific support for cosmetic efficacy claims [J]. China Surfactant Detergent & Cosmetics, 2018, 48(1): 8-13.
[15]	HAO Shan-shan, ZHAI Qiao-ya, ZHAO Li, XU Bao-cai. Self-assembly and photo regulation of a supra-amphiphile based on host-guest interaction [J]. China Surfactant Detergent & Cosmetics, 2017, 47(1): 1-6.