酯基三甲氧基有机硅季铵盐的合成及其表面活性

doi:10.13218/j.cnki.csdc.2014.11.136

Abstract

Abstract: An ester group trimethoxy organosilicon quaternary ammonium salt was synthesized with stearic acid,dimethylethanolamine (DMEA) and γ-chloropropyl trimethoxy siloxane as starting materials.Structure of the product was characterized by FTIR,ESI-MS and ¹HNMR,and the characterization results showed that the product is accord with the target.Via orthogonal designed experiments,the optimum reaction conditions for preparing the intermediate stearic acid dimethylethanolamine ester were obtained as:reaction temperature,180 ℃;reaction time,8 h;mole ratio,n(stearic acid):n(DMEA)=1:1.6;dosage of the catalyst,0.5%;and for the quaternarization,reaction temperature,110 ℃ under nitrogen atmosphere;mole ratio,n(stearic acid dimethylethanolamine ester):n(γ-chloropropyl trimethoxy siloxane)=1:1.4;dosage of the catalyst,0.5%;reaction time,28 h.The cmc of the product under 298 K were determined by steady-state fluorescence analysis as 0.009 3 g·L^-1.

Key words: ester group trimethoxy organosilicon quaternary ammonium salt, synthesis, surface activity, steady-state fluorescence analysis

CLC Number:

TQ423

CHEN Rui-lan, ZHANG Jun-jie, MAO Tao-yan, ZHENG Cheng. Synthesis and surface activity of the ester group trimethoxy organosilicon quaternary ammonium salt[J].China Surfactant Detergent & Cosmetics, 2014, 44(11): 611-614.

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Synthesis and surface activity of the ester group trimethoxy organosilicon quaternary ammonium salt

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