氨基有机硅表面活性剂的合成及性能研究

doi:10.13218/j.cnki.csdc.2014.01.007

Abstract

Abstract: Hydrogen containing silicone fluid was synthesized by using octamethylcyclotetrasiloxane and 1,1,3,3-tetramethyldisiloxane as starting materials under the action of concentrated sulfuric acid.Then hydrosilylation between allyl glycidyl ether and the hydrogen containing silicone fluid was carried out with chloroplatinic acid as catalyst to produce epoxy modified silicone.Finally,ring opening reaction of the epoxy modified silicone was processed with diethanolamine to obtain amino silicone surfactant as the product.Structure of the product was characterized by FTIR and ¹HNMR.Wetting power of the amino silicone product was investigated,and its cmc was determined as 0.102 g·L^-1.Performance of the product was compared with that of block silicone oil 9906 and co-modified block silicone oil.Results showed that wetting power increases with the increase of content of amino silicone.Under the same content of amino silicone,the higher ammonia value of the amino silicone,the stronger wetting power to canvas sample.All the performance in application of the amino silicone surfactant such as stability of microemulsion prepared by amino silicone,hydrophilicity and hand feeling softness of cotton fabrics finished with amino silicone are better than that of block silicone oil 9906 and co-modified block silicone oil.

Key words: amino silicone, stability, wettability, hydrophilicity, hand feeling

CLC Number:

TQ423.4

XIE Fei-jun, CHENG Xiao-ling, YU Lin, YU Pei-rong, ZHANG Zhao-hong. Synthesis and performance of amino silicone surfactant[J].China Surfactant Detergent & Cosmetics, 2014, 44(1): 26-30.

References

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Synthesis and performance of amino silicone surfactant

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