不同结构表面活性剂在有机非水相中的发泡性能研究

doi:10.3969/j.issn.1001-1803.2019.07.003

Abstract

Abstract:

The foaming properties for various organic solvents in the presence of surfactants with diverse structure were investigated. The foam volume and foam stability were determined by a foam attenuation method. The effects of surface tension, viscosity and solvent polarity on foaming properties were also analyzed. The experimental results showed that the anionic, nonionic and amphoteric surfactants under investigation could not produce foams in n-alkanes and aromatic hydrocarbons, while some of them only form foams in liquid paraffin and glycerin. The volume fractions of gas in foams for liquid paraffin and glycerin range from 66.6% to 83.3% and 72.2% to 83.7%, respectively, while the half-lives range from 0.21 to 1.44 min and 1.79 to 16.69 min, respectively. The best foaming agents are AEO-3 for liquid paraffin and OBS for glycerin. It can be concluded that the greater the polarity of the organic solvent, the better is its foaming capacity. The viscosity is only related to the stability of the foam formed from these solutions, and it is found that the decrease of surface tension of the non-aqueous solutions is not closely related to its foaming performance.

Key words: surfactant, non-aqueous solvent, solvent polarity, foaming properties, stability

CLC Number:

TQ423

YAN Yong-Li. Investigation on the foaming properties of surfactants with different structure in organic solvents[J].China Surfactant Detergent & Cosmetics, 2019, 49(7): 435-440.

Figures/Tables 7

Tab. 1

Fig. 1

Fig. 2

Fig. 3

Tab. 2

Tab. 3

Tab. 4

References 25

[1]	Schramm L L . Emulsions, foams, and suspensions:fundamentals and applications[M]. Weinheim:Wiley-VCH, 2005, 231-357.
[2]	Yan Y L . Advances in the foaming and stabilization mechanisms of non-aqueous systems[J]. Applied Chemical Industry, 2016,45:2135-2138.
[3]	Zuo L L, Xing X K, Ning W Y , et al. Research progress on generation and stability of crude oil foams[J]. Oilfield Chemistry, 2016,33:745-749.
[4]	Ren F X, Sun H J, Hu C H . Heavy oil development technology and practices in Liaohe oilfield[J]. Special Oil and Gas Reservoirs, 2012,19(1) : 17-22.
[5]	Shivhare S, Kuru E . A study of the pore-blocking ability and formation damage characteristics of oil-based colloidal gas aphron drilling fluids[J]. Journal of Petroleum Science and Engineering, 2014,122:257-266.
[6]	Patel A R . Stable ‘arrested’ non-aqueous edible foams based on food emulsifiers[J]. Food & Function, 2017,8:2115-2120.
[7]	Peng N H . The foaming agents for removing water from gas wells[J]. Oilfield Chemistry, 1989,6(1) : 84-89.
[8]	Yang J, Jovancicevic V, Ramachandran S . Foam for gas well deliquification[J]. Colloids Surfaces A:Physicochemical and Engineering Aspects, 2007,309:177-181.
[9]	Dong X, Liu H, Sun P , et al. Air-foam-injection process:an improved-oil-recovery technique for water flooded light-oil reservoirs[J]. SPE Reservoir Evaluation & Engineering, 2012,15:436-444.
[10]	Lin Y M, Xiang L, Huang Y Z . Research and application of new types of foam fracturing fluid[J]. Drilling & Production Technology, 2010,33(4) : 99-102.
[11]	Tan X, Sun J S, Xu X G , et al. A study on the oil-based foam drilling fluid technique[J]. Acta Petrolei Sinica, 2010,31:829-833.
[12]	Xu G Y . Cause analysis and countermeasures of oil foaming in equipment oil tank[J]. Machinery, 1998 ( 9) : 29-31.
[13]	Li R F, Yan W, Liu S , et al. Foam mobility control for surfactant enhanced oil recovery[J]. SPE Journal, 2010,15:934-948.
[14]	Qian Y, Zhang S F, Wu J Z , et al. Foam stability and effecting factors of foam combination flooding[J]. Petroleum Geology & Oilfield Developmentin Daqing, 2001,20(2) : 33-36.
[15]	Zhao J X . Complicated reverse aggregates of surfactants in non-polar organic solvents[J]. Progress in Chemistry, 2015,27:168-173.
[16]	King G E . Foam formation in organic liquids[J]. Journal of Physical Chemistry, 1944,48:141-154.
[17]	Robinson J V, Woods W W . Foaming of mixtures of hydrocarbons[J]. Journal of Physical Chemistry, 1948,52:763-766.
[18]	Liu D J, Ma J M, Cheng H M , et al. Aggregation behavior of mixed surfactants in apolar solvent[J]. Chinese Journal of Applied Chemistry, 1997,14(6) : 51-53.
[19]	Jia X G, Yan Y L, Qu C T , et al. Progress in study of effect of crude oil on stability of aqueous foam[J]. China Surfactant Detergent & Cosmetics, 2010,40(1) : 54-59.
[20]	Hu X Y, Song X W, Li Q W , et al. Molecular simulation study of foam formation ability[J]. Acta Chimica Sinica, 2009,67:1691-1694.
[21]	Blázquez C, Emond E, Schneider S , et al. Non-aqueous and crude oil foams[J]. Oil & Gas Science and Technology, 2014,69:467-479.
[22]	Friberg S E . Foams from non-aqueous systems[J]. Current Opinion Colloid & Interface Science, 2010,15:359-364.
[23]	Binks B P, Garveya E J, Vieira J . Whipped oil stabilised by surfactant crystals[J]. Chemical Science, 2016,7(4) : 2621-2632.
[24]	Fameau A, Saint J A . Non-aqueous foams:current understanding on the formation and stability mechanisms[J]. Advances in Colloid and Interface Science, 2017,247:454-464.
[25]	Cheng N L. Solvent manual[M]. Beijing: Chemical Industry Press, 2007,1221.

起泡剂	有机非水相溶剂
起泡剂	正辛烷	正癸烷	正十二烷	苯	甲苯	二甲苯	液体石蜡	甘油
SDS	无	无	无	无	无	无	有	稳定泡沫
AOS	无	无	无	无	无	无	有	稳定泡沫
AES	无	无	无	无	无	无	有	稳定泡沫
AOT	无	无	无	无	无	无	有	稳定泡沫
OBS	无	无	无	无	无	无	有	稳定泡沫
Tween 20	无	无	无	无	无	无	有	无
Tween 40	无	无	无	无	无	无	有	无
Tween 80	无	无	无	无	无	无	有	无
Span 20	无	无	无	无	无	无	有	无
Span 60	无	无	无	无	无	无	有	无
Span 80	无	无	无	无	无	无	有	无
AEO-3	无	无	无	无	无	无	有	有
AEO-9	无	无	无	无	无	无	有	无
BS-12	无	无	无	无	无	无	有	有

起泡剂	AEO-3	BS-12	SDS
η/（mPa·s）	22.8	22.3	22.0
泡沫含气率/%	72.0	77.7	76.7
半衰期/min	0.63	0.62	0.52

起泡剂	SDS	BS-12	AEO-3
η/（mPa·s）	913.0	906.4	895.2
泡沫含气率/%	71.8	75.9	69.2
半衰期/min	15.09	6.70	1.90

溶剂	正辛烷	正癸烷	正十二烷	苯	甲苯	二甲苯	液体石蜡	甘油
介电常数	2	2	2	1.0~2.3	2.4	2.3~2.4	1.9~2.5	47~68
发泡性能	无	无	无	无	无	无	有	稳定泡沫

Investigation on the foaming properties of surfactants with different structure in organic solvents

RichHTML

PDF (PC)

Like

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 7

References 25

Related Articles 15

Metrics

Comments

Recommended 10

[1]	Zhisheng Zhang, Chanliang Shen, Jianxun Li, Yanqiang Liu, Weiwei Han, Sanbao Dong. Preparation and performance of betaine/AOS/Gemini ternary surfactant foam for gas well deliquification [J]. China Surfactant Detergent & Cosmetics, 2024, 54(3): 239-249.
[2]	Guofeng Li, Kainan Liu, Wenlong Mo, Teng Ma. Performance evaluation of a system of imbibition oil displacement agent in shale reservoir [J]. China Surfactant Detergent & Cosmetics, 2024, 54(3): 250-258.
[3]	Hongmei Zhang, Yongmin Zhang. Synthesis and properties of a choline-fatty-acid-based ionic liquid surfactant [J]. China Surfactant Detergent & Cosmetics, 2024, 54(2): 149-155.
[4]	Xiaohong Pan, Ziqi Gao, Zhen Chen, Shuai Yin, Haiping Huang, Bin Hu. Discussion on the current situation of research and management on the stability of cosmetic products in China [J]. China Surfactant Detergent & Cosmetics, 2024, 54(2): 201-208.
[5]	Pei Liu, Ting Pan, Xiaomei Pei, Binglei Song, Jianzhong Jiang, Zhenggang Cui, Bernard P. Binks. Dual-responsive oil-in-water emulsions co-stabilized by a nonionic-anionic Bola surfactant and silica nanoparticles [J]. China Surfactant Detergent & Cosmetics, 2024, 54(1): 1-15.
[6]	Haokang Ai, Yajie Jiang, Yakui Wang, Lu Zhang, Tao Geng. Synthesis and properties of Gemini quaternary ammonium surfactant based on stearate [J]. China Surfactant Detergent & Cosmetics, 2024, 54(1): 16-23.
[7]	Wanping Zhang, Yanzhong Lin, Qianjie Zhang, Dongmei Zhang, Wen Jiang. Study on the phase behavior of sodium lauroyl methyltaurate mediated by Ca²⁺ [J]. China Surfactant Detergent & Cosmetics, 2024, 54(1): 32-37.
[8]	Yaru Wang, Tingyuan Mo, Hongxia Lai, Yue Zhou, Jiaying Xie, Jianhua Tan. Analysis of the causes of skin irritation of niacinamide cosmetics based on patch test and stability test [J]. China Surfactant Detergent & Cosmetics, 2024, 54(1): 51-56.
[9]	Chang Shiteng, Cai Xiaojun, Zheng Yancheng, Liu Xuejin, Yi Xiao, Jiang Zhuyang. Physicochemical properties of ethoxylated sulfosuccinate surfactants and their interfacial properties when mixed with a betaine surfactant [J]. China Surfactant Detergent & Cosmetics, 2023, 53(9): 989-998.
[10]	Xu Derong,Lian Wei,Xiong Jinzhao,Kang Wanli. Research on the influence factors of surfactant imbibition in tight reservoirs [J]. China Surfactant Detergent & Cosmetics, 2023, 53(8): 857-864.
[11]	Niu Qiqi,Lv Qichao,Dong Zhaoxia,Zhang Fengfan,Wang Hongbo. Research progress on the properties of foam systems containing wormlike micelles [J]. China Surfactant Detergent & Cosmetics, 2023, 53(8): 915-924.
[12]	Wang Jiarui,Wei Xiaocheng,Zhang Chunxue,Chen Peizhen,Zheng Xiangqun,Wang Qiang. Research progress on detection methods of surfactants in water samples from environment [J]. China Surfactant Detergent & Cosmetics, 2023, 53(8): 925-934.
[13]	Qiang Xuefeng, Zhang Li, Zheng Bin, Hou Qianqian, Yan Kun. Study on the inf luence of KCl on the evolution of foam of an anionic surfactant [J]. China Surfactant Detergent & Cosmetics, 2023, 53(7): 733-741.
[14]	Xing Huanyu, Jia Lihua, Zhao Zhenlong, Yang Rui, Guo Xiangfeng. Synthesis and properties of novel surfactants containing naphthalimide and alkyl segments [J]. China Surfactant Detergent & Cosmetics, 2023, 53(7): 742-747.
[15]	Wang Huazheng, Zhang Liang, Kang Xin, Kang Wanli, Li Zhe, Yang Hongbin. Effect of CO₂ on physical properties of produced oil and water in Changqing and emulsion stabilization mechanism [J]. China Surfactant Detergent & Cosmetics, 2023, 53(6): 617-624.