基于N-[4-（三乙基铵甲撑）苯酰基]己内酰胺氯化物的活化氧漂体系在纺织品室温洁白洗涤中的应用

doi:10.3969/j.issn.1001-1803.2019.04.004

日用化学工业 ›› 2019, Vol. 49 ›› Issue (4): 224-228.doi: 10.3969/j.issn.1001-1803.2019.04.004

基于N-[4-（三乙基铵甲撑）苯酰基]己内酰胺氯化物的活化氧漂体系在纺织品室温洁白洗涤中的应用

邵冬燕,柴文龙,杜金梅,王鸿博,许长海()

江南大学生态纺织教育部重点实验室,江苏无锡 214122

收稿日期:2018-08-09 修回日期:2018-08-28 出版日期:2019-04-22 发布日期:2019-04-24
通讯作者: 许长海
作者简介:邵冬燕,女,博士研究生,E-mail：dongyan-shao@foxmail.com。
基金资助:
国家自然科学基金面上项目资助(21276106)

Performance of activated peroxide system based on N-[4-（triethylammoniomethyl） benzoyl] caprolactam chloride in room-temperature cleaning of colored contaminants on textiles

SHAO Dong-yan,CHAI Wen-long,DU Jin-mei,WANG Hong-bo,XU Chang-hai()

Key Laboratory of Eco-textiles, Ministry of Education, Jiangnan University, Wuxi, Jiangsu 214122, China

Received:2018-08-09 Revised:2018-08-28 Online:2019-04-22 Published:2019-04-24
Contact: Chang-hai XU

摘要/Abstract

摘要：

使用N-[4-（三乙基铵甲撑）苯酰基]己内酰胺氯化物（TBCC）对过硼酸钠、过碳酸钠和过氧化脲进行活化,对沾染了茶渍、咖啡渍和红酒渍的白色纺织品进行室温洁白洗涤。实验结果表明,活化过硼酸钠体系和活化过碳酸钠体系对污渍纺织品的室温洁白洗涤效果显著,但活化过氧化脲体系对污渍纺织品的室温洁白洗涤效果不佳。研究发现,向活化过氧化脲体系中加入适量碳酸钠可显著改善其对污渍纺织品的室温洁白洗涤性能。阴离子和非离子表面活性剂分别与TBCC活化过氧化物体系组合对污渍纺织品进行室温洁白洗涤,二者均对TBCC活化过氧化物体系的洁白洗涤性能没有显著影响。

关键词: 洁白洗涤, 过氧化物, 漂白活化剂, 活化氧漂体系, 纺织品

Abstract:

N-[4-（triethylammoniomethyl） benzoyl] caprolactam chloride （TBCC） was used for activation of sodium perborate, sodium percarbonate and percarbamide for room-temperature cleaning of white fabrics contaminated with tea, coffee and wine. The experiment results show that the activated perborate and percarbonate systems exhibit outstanding room-temperature cleaning performance, but the activated percarbamide system exhibits poor room-temperature cleaning performance. It is found that the incorporation of sodium carbonate in the TBCC-activated percarbamide system can effectively improve its room-temperature cleaning performance. The TBCC-activated peroxide systems added with anionic and nonionic surfactants have no apparent change in their cleaning performance.

Key words: cleaning, peroxide, bleach activator, activated peroxide system, fabric

中图分类号:

TQ649

邵冬燕,柴文龙,杜金梅,王鸿博,许长海. 基于N-[4-（三乙基铵甲撑）苯酰基]己内酰胺氯化物的活化氧漂体系在纺织品室温洁白洗涤中的应用[J]. 日用化学工业, 2019, 49(4): 224-228.

SHAO Dong-yan,CHAI Wen-long,DU Jin-mei,WANG Hong-bo,XU Chang-hai. Performance of activated peroxide system based on N-[4-（triethylammoniomethyl） benzoyl] caprolactam chloride in room-temperature cleaning of colored contaminants on textiles[J]. China Surfactant Detergent & Cosmetics, 2019, 49(4): 224-228.

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参考文献 10

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[3]	Hofmann J, Just G, Pritzkow W , et al. Bleaching activators and the mechanism of bleaching activation[J]. Journal für Praktische Chemie/Chemiker-Zeitung, 1992,334(4) : 293-297.
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[7]	Si Fang, Yan Kelu, Zhang Xuan . Study on H₂O₂/TAED and H₂O₂/TBCC bleaching mechanism related to hydroxyl radical with a fluorescent probe[J]. Carbohydrate Polymers, 2014,103(1) : 581-586. doi: 10.1016/j.carbpol.2013.12.052 pmid: 24528769
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[9]	Wei Dong, Sun Chang, Wang Mengze , et al. Synjournal of N-[4-(dimethylalkylammoniomethyl) benzoyl]caprolactam chlorides as cationic bleach activators for low-temperature bleaching of cotton fabric under near-neutral pH conditions[J]. Coloration Technology, 2015,130(6) : 432-436.
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纺织品	颜色						WI
纺织品	L*	a*	b*	C*	h*	ΔE	WI
原样	94.67	-0.13	4.24	4.24	91.73		67.55
茶渍	88.35	1.79	7.15	7.37	75.93	7.22	38.50
咖啡渍	80.26	3.57	16.79	17.17	78.01	19.46	非白
红酒渍	74.60	10.24	3.38	10.79	18.28	22.61	非白

洗涤配方	WI
洗涤配方	茶渍纺织品	咖啡渍纺织品	红酒渍纺织品
1	46.19	非白	41.36
2	54.79	非白	41.98
3	52.15	34.30	40.43
4	71.43	57.53	65.33
5	43.94	31.69	41.34
6	68.12	56.17	59.09
7	49.86	26.98	28.60
8	54.63	27.26	40.77
9	50.75	非白	39.54
10	50.48	30.07	40.53
11	71.75	55.61	64.55
12	47.98	28.39	38.99
13	68.76	54.15	59.04
14	52.58	24.48	27.63
15	51.92	25.03	42.25

洗涤配方	洗涤前pH			洗涤后pH
洗涤配方	茶渍纺织品	咖啡渍纺织品	红酒渍纺织品	茶渍纺织品	咖啡渍纺织品	红酒渍纺织品
4	8.71	8.84	8.61	7.82	7.99	7.56
6	8.22	8.34	7.91	7.23	7.54	7.32
8	4.39	4.44	4.16	4.40	4.44	4.21
11	8.74	8.72	8.62	7.69	7.84	7.47
13	8.18	8.19	7.76	6.82	7.45	7.04
15	4.15	4.30	4.00	4.15	4.36	3.96

Na₂CO₃/（g·L^-1）	pH		WI
Na₂CO₃/（g·L^-1）	洗涤前	洗涤后	WI
0	4.00	3.96	42.25
0.80	7.68	6.99	57.89
1.00	8.20	7.28	63.94
1.25	8.50	7.40	64.12
1.50	8.71	7.67	65.18
1.75	8.77	8.00	66.38
2.00	9.05	8.38	67.12

基于N-[4-（三乙基铵甲撑）苯酰基]己内酰胺氯化物的活化氧漂体系在纺织品室温洁白洗涤中的应用

Performance of activated peroxide system based on N-[4-（triethylammoniomethyl） benzoyl] caprolactam chloride in room-temperature cleaning of colored contaminants on textiles

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参考文献 10

相关文章 4

Metrics

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推荐阅读 10

洗涤配方	ρ/（g·L^-1）
洗涤配方	SDBS	Triton X-100	EDTA	过硼酸钠	过碳酸钠	过氧化脲	TBCC
1	0	0	0	0	0	0	0
2	1.0	0	0	0	0	0	0
3	1.0	0	1.0	1.50	0	0	0
4	1.0	0	1.0	1.50	0	0	5.51
5	1.0	0	1.0	0	1.57	0	0
6	1.0	0	1.0	0	1.57	0	5.51
7	1.0	0	1.0	0	0	1.41	0
8	1.0	0	1.0	0	0	1.41	5.51
9	0	1.0	0	0	0	0	0
10	0	1.0	1.0	1.50	0	0	0
11	0	1.0	1.0	1.50	0	0	5.51
12	0	1.0	1.0	0	1.57	0	0
13	0	1.0	1.0	0	1.57	0	5.51
14	0	1.0	1.0	0	0	1.41	0
15	0	1.0	1.0	0	0	1.41	5.51

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