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日用化学工业（中英文）

日用化学工业 ›› 2014, Vol. 44 ›› Issue (7): 375-378.doi: 10.13218/j.cnki.csdc.2014.07.083

• 开发与应用 • 上一篇    下一篇

驱油用磺化聚丙烯酰胺的制备及溶液性能研究

杨雪, 王江红, 卢琼   

  1. 华鼎鸿基采油技术服务(北京)有限公司,北京 100191
  • 收稿日期:2014-01-14 出版日期:2014-07-22 发布日期:2019-04-08
  • 作者简介:杨 雪(1986-),女,硕士,研发工程师,电话:(010)88593266。

Synthesis of oil-displacing agent sulfonated polyacrylamide and performance of its aqueous solutions

YANG Xue, WANG Jiang-hong, LU Qiong   

  1. Holding Energy Petroleum Engineering Technology (Beijing),Co.,Ltd.,Beijing 100191,China
  • Received:2014-01-14 Online:2014-07-22 Published:2019-04-08

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摘要： 采用NaHSO3-K2S2O8和偶氮二异丁脒盐酸盐(AIBA)复合引发剂体系及高低温分段引发法合成了丙烯酰胺/2-丙烯酰胺基-2-甲基丙磺酸(AM/AMPS)共聚物,通过单因素实验与正交试验考察了单体质量分数、引发剂质量分数、引发温度、pH、单体配比、引发剂配比等因素对共聚物表观黏度的影响,筛选出共聚物的最佳制备条件,即单体质量分数为25%,引发剂质量分数为0.015%,引发温度为10 ℃,pH=7,m(AM):m(AMPS)=5:1,m(K2S2O8):m(NaHSO3)=2:1,m(NaHSO3-K2S2O8):m(AIBA)=1:1,引发时间为1.5 h。耐温抗盐及热稳定性评价实验结果表明AM/AMPS共聚物的综合耐温抗盐性较好。

关键词: 共聚物, 磺化, 复合引发剂, 表观黏度, 耐温抗盐性

Abstract: Copolymer acrylamide/2-acrylamide-2-methyl propylsulfonate was synthesized by using acrylamide (AM) and 2-acrylamide-2-methylpropane sulfonic acid (AMPS) as starting materials,and adopting high/low temperature two-step initiating method,with a complex initiator system which composed of NaHSO3-K2S2O8 and azo diisobutyl amidine hydrochloride (AIBA).Factors that affect the apparent viscosity of the product,such as mass fraction of reacting monomers,mass fraction of initiator,temperature,pH,ratio of monomers,ratio of initiator et al were studied by single factor experiment and orthogonal designed experiment.The optimal preparation conditions of polymers were screened as:monomer mass fraction,25%;initiator mass fraction,0.015%;initiation temperature,10 ℃;pH,7;m(AM):m(AMPS)=5:1;m(K2S2O8):m(NaHSO3)=2:1;m(NaHSO3-K2S2O8):m(AIBA)=1:1;initiating time,1.5 h.Temperature tolerance,salt resistance and thermal stability evaluation experiment results showed that the AM/AMPS copolymer product acts good comprehensive performance.

Key words: copolymer, sulfonation, complex initiator, apparent viscosity, temperature tolerance and salt resistance

中图分类号: 

  • TQ423