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日用化学工业（中英文）

日用化学工业 ›› 2014, Vol. 44 ›› Issue (12): 714-717.doi: 10.13218/j.cnki.csdc.2014.12.159

• 生产与技术 • 上一篇    

喷雾法生产石油磺酸盐技术研究

方新湘, 牛春革, 白云, 周华   

  1. 中国石油克拉玛依石化公司 炼油化工研究院,新疆 克拉玛依 834000
  • 收稿日期:2014-08-12 出版日期:2014-12-22 发布日期:2019-04-08
  • 作者简介:方新湘(1968-),女,浙江人,本科,工程师,电话:(0990)6885733,E-mail:fxx@petrochina.com.cn。
  • 基金资助:
    克拉玛依油田复合驱用表面活性剂产品的研究与开发资助项目(2009A-4006-01)

Technology for production of petroleum sulfonate via spray method

FANG Xin-xiang, NIU Chun-ge, BAI Yun, ZHOU Hua   

  1. Refining & Petrochemical Researching Institute,Karamay Petrochemical Branch Co.of CNPC,Karamay,Xinjiang 834000,China
  • Received:2014-08-12 Online:2014-12-22 Published:2019-04-08

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摘要： 介绍了喷雾法生产石油磺酸盐的研究情况。根据石油组分的特点,采用喷雾磺化技术大幅度增加了石油组分与三氧化硫的气液接触面积,使得磺化效率得到了很大的提高,磺化反应接触时间从几小时缩短到几十秒,减少了石油组分过磺化现象的发生,小试研究结果表明,与传统釜式磺化技术相比,采用改造后的喷雾磺化工艺使得石油磺酸盐的收率提高了3%以上,酸性油收率提高10%以上,酸渣收率降低35%以上,可实现连续化生产,并为工业化应用提供参考。

关键词: 石油磺酸盐, 磺化, 喷雾, 工业化

Abstract: Technology for production of petroleum sulfonate via spray method was introduced.Based upon the characteristics of the petroleum fraction,the adoption of spray sulfonation technology increases the contacting surface area between the petroleum fraction and SO3 substantially and results in a great improvement of the sulfonation efficiency.Contacting time for sulfonation reduces from several hours to several ten seconds and thus reduces the happening of over-sulfonation.Results of laboratory tests showed that as comparing with the conventional reaction kettle sulfonation,the spray sulfonation causes more than 3% increase of yield of the petroleum sulfonate and more than 10% increase of yield of the raffinate oil;while the yield of the acid residue decreases for more than 35%.Continuous process can be realized and the laboratory test results can be used as reference for industrial operation.

Key words: petroleum sulfonate, sulfonation, spray, industrialization

中图分类号: 

  • TQ423.11