高分子表面活性剂在不同洗涤剂中的应用性能

doi:10.3969/j.issn.2097-2806.2024.08.007

日用化学工业（中英文） ›› 2024, Vol. 54 ›› Issue (8): 930-938.doi: 10.3969/j.issn.2097-2806.2024.08.007

高分子表面活性剂在不同洗涤剂中的应用性能

严羽欢¹,潘鹤潮²,鲍红洁³,赵建红^1,^2,^*(),何一波^3,^*()

1.合创（广州）科技研究有限公司，广东广州 510006
2.广东工业大学绿色日用品创新研究院，广东广州 510006
3.纳爱斯集团有限公司浙江省绿色清洁技术及洗涤用品重点实验室，浙江丽水 323000

收稿日期:2023-09-06 修回日期:2024-07-23 出版日期:2024-08-22 发布日期:2024-08-21
通讯作者: 赵建红,何一波
基金资助:
浙江省绿色清洁技术及洗涤用品重点实验室开放课题(Q202207)

Application properties of a polymeric surfactant in different detergents

Yuhuan Yan¹,Hechao Pan²,Hongjie Bao³,Jianhong Zhao^1,^2,^*(),Yibo He^3,^*()

1. HeChuang （Guangzhou） Technology Research Co., Ltd., Guangzhou, Guangdong 510006, China
2. Institute of Green Commodity Innovation, Guangdong University of Technology, Guangzhou, Guangdong 510006, China
3. Key Laboratory of Green Cleaning Technology & Detergent of Zhejiang Province, Nice Group Co., Ltd., Lishui, Zhejiang 323000, China

Received:2023-09-06 Revised:2024-07-23 Online:2024-08-22 Published:2024-08-21
Contact: Jianhong Zhao,Yibo He

摘要/Abstract

摘要：

分别利用凝胶色谱仪、表面张力仪和激光粒度仪表征了聚醚-聚丙烯酸/酯高分子表面活性剂HS-PA的分子量、表面张力以及胶束聚集体的粒径分布。并考察了HS-PA在分别以LAS/AES/AEO₉为主表面活性剂的非结构型/结构型洗涤剂中的增稠性能、去污性能、液晶形态、悬浮性能以及流变行为。性能表征结果表明：HS-PA的重均分子量为4 244，临界胶束浓度为3×10^-7 mol/L，平衡表面张力为42.06 mN/m；当HS-PA分别与LAS、AES、AEO₉形成混合胶束时，聚集体的平均粒径增大；在非结构型洗涤剂中的应用测试结果表明：HS-PA对LAS/AES/AEO₉为主表面活性剂的配方均有提升黏度的作用，同时有利于改善洗涤剂在JB03皮脂污布上的去污力；在结构型洗涤剂中的应用测试结果说明：HS-PA将有助于LAS/AES/AEO₉体系形成球形层状液晶，且HS-PA用量越多，AES体系的液晶数量越多；离心结果表明，含HS-PA的结构型洗涤剂具有稳定悬浮微胶囊的能力；经旋转流变仪测定，HS-PA可提高LAS配方体系的屈服应力。

关键词: 高分子表面活性剂, 结构型洗涤剂, 非结构型洗涤剂

Abstract:

The molecular weight, surface tension, and the particle size distribution of micellar aggregates of a polyether-polyacrylate polymeric surfactant, HS-PA, were characterized on gel permeation chromatograph, surface tension meter, and laser particle size analyzer, respectively. The thickening properties, detergency, liquid crystal morphology, suspension properties, and rheological behaviors of HS-PA in unstructured/structured detergents with LAS/AES/AEO₉ as the main surfactants, respectively, were also investigated. The characterization results showed that, the weight-average molecular weight of HS-PA was 4 244, the critical micelle concentration was 3×10^-7 mol/L, and the equilibrium surface tension was 42.06 mN/m; the average particle size of aggregates was increased when LAS, AES and AEO₉ formed mixed micelles with HS-PA, respectively. The application test in unstructured detergents showed that, HS-PA had viscosity-enhancing effects on all the LAS/AES/AEO₉-based systems, and meanwhile it was beneficial to the improvement of the detergency to sebum. The application test in structured detergents showed that, HS-PA would help the formation of lamellar liquid crystals in the LAS/AES/AEO₉ systems, and the more HS-PA used, the more the liquid crystals in the AES system; the centrifugal separation results showed that the structured detergents containing HS-PA had the ability to stabilize the suspension of microcapsules; HS-PA could increase the yield stress of the LAS formulation system as determined by rotational rheometer.

Key words: polymeric surfactant, structured detergent, unstructured detergent

中图分类号:

TQ423

严羽欢,潘鹤潮,鲍红洁,赵建红,何一波. 高分子表面活性剂在不同洗涤剂中的应用性能[J]. 日用化学工业（中英文）, 2024, 54(8): 930-938.

Yuhuan Yan,Hechao Pan,Hongjie Bao,Jianhong Zhao,Yibo He. Application properties of a polymeric surfactant in different detergents[J]. China Surfactant Detergent & Cosmetics, 2024, 54(8): 930-938.

图/表 12

图1

图2

图3

表1

图4

表2

图 5

图6

表3

表4

图7

表5

参考文献 15

[1]	Lai Xiaojuan. Synthesis of polymer surfactants and their applications[J]. China Cleaning Industry, 2007 (1) : 41-44.
[2]	Zhou Meng. Development and application of high efficiency compound liquid crystal emulsifier[J]. East China University of Science and Technology, 2018.
[3]	Du Zhiping, Wang Wan Xu, Tai Xiumei. Liquid detergent for textile[J]. Detergent & Cosmetics, 2011, 34 (10) : 13-16, 20.
[4]	Zhu Haiyang. Structured heavy duty liquid detergents[J]. Detergent & Cosmetics, 1999 (S1) : 68-71.
[5]	Yang Shan, Xu Yang, Gao Yunlong. Preparation and surface activity of random copolymer P(AA-co-BA)[J]. China Surfactant Detergent & Cosmetics, 2020, 50 (6) : 387-391.
[6]	Oikonomou E K, Bethani A, Bokias G, et al. Poly(sodium styrene sulfonate)-b-poly(methyl methacrylate) diblock copolymers through direct atom transfer radical polymerization: Influence of hydrophilic-hydrophobic balance on self-organization in aqueous solution[J]. European Polymer Journal, 2011, 47 (4) : 752-761.
[7]	Wu Xiaoli. Study of synthesis, solution properties and application in emulsion about copolymerization of methacrylate[D]. Suzhou: Soochow University, 2007.
[8]	Liu Bao, Guo Xiaodan, Lu Zhimin. Research of isopropyl amine salt of linear alkylbenzene sulfonic acid and its application in dishwashing liquid detergent[J]. Detergent & Cosmetics, 2017, 40 (8) : 21-25.
[9]	Hu Donghui, Chen Lihua, Sun Lina, et al. Purification of sodium laureth sulfate[J]. Technology innovation and application, 2016, 170 (22) : 65.
[10]	Zhang Dianlong. The dynamic adsorption spreading of typical non-ionic surfactants and wetting mechanism of coal dust[D]. Taiyuan: Taiyuan University of Technology, 2016.
[11]	Cao Ya, Li Huilin, Zuo Ju, et al. Studies on micellar conformation of polymeric surfactants based on carboxy methyl cellulose in aqueous solutions[J]. Acta Polymerica Sinica, 2000, 1 (3) : 345-349.
[12]	Zhang Haibo, Huang Xianzhi, Jin Ji, et al. Research on the system of amino acid transparent cleansing gel[J]. Detergent & Cosmetics, 2022, 45 (1) : 37-42.
[13]	Liu Huimin, Ma Xiaoyuan, Zhao Yonghong. Preparation of liquid crystal emulsion and its application in cosmetics[J]. China Surfactant Detergent & Cosmetics, 2022, 52 (7) : 762-769.
[14]	Fan Fan, Quan Yan, Pan Wei, et al. Preparation and properties of layered liquid crystal emulsion with different emulsification systems[J]. China Cleaning Industry, 2023 (3) : 7-14.
[15]	Lu Ximing. Lubrication and dynamic controlled drug release properties of Tween 85/Tween 80/H₂O composite lamellar liquid crystals[D]. Yangzhou: Yangzhou University, 2021.

主表面活性剂	w/%						纯水
主表面活性剂	LAS	AES	AEO₉	NaOH	HS-PA	NaCl	纯水
LAS	10.2	2.7	2.7	1.25	0	1.0	余量
LAS	10.0	2.5	2.5	1.23	2.0	1.0	余量
AES	2.7	10.2	2.7	0.33	0	3.5	余量
AES	2.5	10.0	2.5	0.31	2.0	3.5	余量
AEO₉	2.7	2.7	10.2	0.33	0	4.5	余量
	2.5	2.5	10.0	0.31	2.0	4.5	余量
	2.4	2.5	9.9	0.70	3.0	4.5	余量
	2.3	2.4	9.8	0.80	4.0	4.5	余量

主表面活性剂	w（总活性物）/%	w/%							纯水
主表面活性剂	w（总活性物）/%	LAS	AES	AEO₉	HS-PA	NaOH	NaCl	丙二醇	纯水
LAS	15	7.5	5.2	2.7	0	1	4.5	0	余量
	15	7.3	5	2.5	2	1.2	4.5	0	余量
	25	12.5	6.5	6.5	0	1.6	4	0	余量
	25	12	6	6	5	2.2	4	0	余量
AES	15	5.2	7.5	2.7	0	0.7	9	0	余量
	15	5	7.3	2.5	2	0.9	9	0	余量
	25	6.5	12.5	6.5	0	0.8	8	3	余量
	25	6	12	6	5	1.4	8	3	余量
AEO₉	15	5.2	2.7	7.5	0	0.7	10	0	余量
	15	5	2.5	7.3	2	0.9	10	0	余量
	25	6.5	6.5	12.5	0	0.8	9.5	0	余量
	25	6	6	12	5	1.4	9.5	0	余量
LAS/AEO₉/AES	15	5.2	5.2	5.2	0	0.7	8.5	0	余量
	15	5	5	5	2	0.9	8.5	0	余量
	25	8.5	8.5	8.5	0	1.1	7.5	2	余量
	25	8	8	8	5	1.7	7.5	2	余量

w/%						纯水
LAS	AES	AEO₉	NaOH	HS-PA	NaCl	纯水
5.2	7.5	2.7	0.7	0.0	9.0	余量
5.0	7.3	2.5	0.9	2.0	9.0	余量
5.0	7.1	2.4	1.0	3.0	9.0	余量
4.9	6.9	2.3	1.1	4.0	9.0	余量

主表面活性剂	w（总活性物）/%	HS-PA	离心后状态	45 ℃烘箱2个月后离心
LAS	15	0.0	均一不分层	有颗粒轻微上浮
	15	2.0	均一不分层	均一不分层
	25	0.0	均一不分层	有颗粒轻微上浮
	25	5.0	均一不分层	均一不分层
AES	15	0.0	轻微分层	分层
	15	2.0	均一不分层	均一不分层
	25	0.0	轻微分层	分层
	25	5.0	均一不分层	均一不分层
AEO₉	15	0.0	分层	分层
	15	2.0	均一不分层	均一不分层
	25	0.0	轻微分层	分层
	25	5.0	均一不分层	均一不分层
LAS/AEO₉/AES	15	0.0	均一不分层	有颗粒上浮
	15	2.0	均一不分层	均一不分层
	25	0.0	轻微分层	分层
	25	5.0	均一不分层	均一不分层

样品	屈服应力/Pa	回归方程	R²
LAS₁₅-0% HS-PA	2.78	τ=2.78+0.85γ^0.56	0.999 0
LAS₁₅-2% HS-PA	4.19	τ=4.19+4.57γ^0.43	0.999 5
LAS₂₅-0% HS-PA	3.85	τ=3.85+5.87γ^0.46	0.999 2
LAS₂₅-5% HS-PA	25.5	τ=14.9+12.93γ^0.41	0.999 0

高分子表面活性剂在不同洗涤剂中的应用性能

Application properties of a polymeric surfactant in different detergents

RichHTML

PDF (PC)

赞

可视化

摘要/Abstract

引用本文

使用本文

图/表 12

参考文献 15

相关文章 4

Metrics

本文评价

推荐阅读 0

[1]	杨珊,徐洋,高云龙. 无规共聚物P（AA-co-BA）的制备及表面活性研究[J]. 日用化学工业, 2020, 50(6): 387-391.
[2]	吕斌,刘慧慧,李鹏飞,高党鸽,马建中. 反应型高分子表面活性剂的研究进展[J]. 日用化学工业, 2019, 49(9): 601-608.
[3]	谭福能, 隋卫平. O-羟丙基-N-月桂酰基壳聚糖的制备及其表面性能研究[J]. 日用化学工业, 2015, 45(5): 252-256.
[4]	周建华, 王海龙, 贺仁妍. 含十二烷基的聚甲基丙烯酸N,N-二甲氨基乙酯的合成及性能研究[J]. 日用化学工业, 2014, 44(11): 601-604.