α-蒎烯催化环氧化研究进展

doi:10.13218/j.cnki.csdc.2016.06.011

摘要/Abstract

摘要： 从使用不同氧化剂的角度,综述了近年来国内外α-蒎烯环氧化反应的研究进展,列举了α-蒎烯环氧化中分别以过氧乙酸、烃基过氧化氢、非金属氧酸盐、H₂O₂和O₂作为氧化剂时的优缺点,重点介绍了以环境友好的H₂O₂和O₂为氧化剂的α-蒎烯环氧化反应。

关键词: 香料, α-蒎烯, 环氧化, 2,3-环氧蒎烷

Abstract: In view of different oxidants,the advances of the catalytic epoxidation of α-pinene in recent years were summarized.The advantages and disadvantages of various oxidants such as acetic acid peroxide,hydrocarbonyl hydrogen peroxide,nonmetallic oxygen acid salt,H₂O₂ and O₂ respectively as an oxidizing agent in the α-pinene epoxidation were listed.The epoxidation of α-pinene conducted by environmentally friendly oxidant H₂O₂ and O₂ was emphatically introduced.

Key words: spice, α-pinene, epoxidation, 2,3-epoxypinane

中图分类号:

TQ655

王中天,于凤丽,袁冰,解从霞,于世涛. α-蒎烯催化环氧化研究进展[J]. 日用化学工业, 2016, 46(6): 353-358.

WANG Zhong-tian,YU Feng-li,YUAN Bing,XIE Cong-xia,YU Shi-tao. Progress of catalytic α-pinene epoxidation[J]. China Surfactant Detergent & Cosmetics, 2016, 46(6): 353-358.

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