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China Surfactant Detergent & Cosmetics ›› 2020, Vol. 50 ›› Issue (9): 581-587.doi: 10.3969/j.issn.1001-1803.2020.09.001
• Basic research • Next Articles
ZHANG Zhi-dong1(
),FANG Yin-jun2,LIU Xue-feng1()
Received:2019-11-21
Revised:2020-08-27
Online:2020-09-22
Published:2020-09-23
Contact:
Xue-feng LIU
E-mail:zhangzd9409@163.com;xfliu@jiangnan.edu.cn
CLC Number:
ZHANG Zhi-dong,FANG Yin-jun,LIU Xue-feng. Synthesis and properties of sodium dodecyl phthalate monoester[J].China Surfactant Detergent & Cosmetics, 2020, 50(9): 581-587.
Fig. 1
Synthetic route of sodium dodecyl phthalate monoester （PAS12）（A）, 1H NMR spectrum of PAS12 （B）"
Tab. 1
Krafft temperatures of PAS12, SL and SP"
| 表面活性剂 | KT/℃ |
|---|---|
| PAS12 | 16.4±0.2 |
| SL | 15.5±0.3 |
| SP | 57.4±0.3 |
Fig. 2
γ-lg c curves of PAS12 and SL at 25 ℃"
Tab. 2
Surface active parameters of PAS12 and SL"
| 表面活性剂 | cmc/（mmol·L-1） | γcmc/（mN·m-1） | Πcmc/（mN·m-1） | pc20 | cmc/c20 | Гm×106/（mol·m2） | Amin/nm2 |
|---|---|---|---|---|---|---|---|
| PAS12 | 0.76 | 29.36 | 42.54 | 4.50 | 23.73 | 2.96 | 0.56 |
| SL | 20.01 | 35.05 | 36.86 | 2.07 | 2.35 | 7.40 | 0.22 |
Fig. 3
Foam properties of different concentrations of PAS12, SDS and SL"
Tab. 3
Half-life of foams for PAS12, SDS and SL"
| c/（mmol·L-1） | t1/2 （PAS12）/min | t1/2 （SDS）/min | t1/2 （SL）/ min |
|---|---|---|---|
| 1 | 31.5±0.2 | 24.2±0.5 | 0 |
| 8 | 93.5±0.6 | 94.4±0.6 | 71.8±0.8 |
| 23 | 98.2±0.6 | 99.1±0.4 | 66.6±0.4 |
Fig. 4
σ-lg c curves of PAS12 and SL at 25 ℃"
Fig. 5
Appearance of the emulsion stabilized by 3 mmol/L SL （standing for two days） （A）; Appearance of the emulsion stabilized by 3 mmol/L PAS12 （standing for one week） （B）; Microphotograph of the emulsion stabilized by 3 mmol/L PAS12 （C）; Size distribution of emulsion stabilized by 3 mmol/L PAS12 （D）"
Fig. 6
T-cCa curves of aqueous solutions of 25 mmol/L PAS12 and 25 mmol/L SL （A）; γ-cCa curves of aqueous solutions of PAS12 and SL, while curve 1 is PAS12, 0.4 mmol/L; curve 2 is SL, 10 mmol/L; curve 3 is PAS12, 25 mmol/L; curve 4 is SL, 25 mmol/L （B）"
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