氯化钠对包覆维生素C多重乳液的影响

doi:10.3969/j.issn.1001-1803.2019.12.007

Abstract

Abstract:

Water-in-oil-in-water（W₁/O/W₂）multiple emulsion was prepared by two-step method with caprylic/capric triglyceride as oil phase, lauryl PEG-9 polydimethylsiloxyethyl dimethicone as oleophilic emulsifier and the amphiphilic random copolymer as hydrophilic emulsifier. The multiple emulsion was used to encapsulate Vitamin C in internal aqueous phase（W₁）. Sodium chloride（NaCl）regulated the osmotic pressure between the internal and external aqueous phases to improve the stability of the multiple emulsion. The effects of the amount of NaCl on the interfacial tension, droplet size of emulsion and viscosity were investigated. The stability of the multiple emulsion was evaluated by optical microscope and emulsion appearance. The results show that, the addition of NaCl in W₁ lead to significant decrease of W₁/O interfacial tension, smaller size of the emulsion droplets, and higher viscosity of the emulsion. The interfacial tension at O/W₂ interface would be obviously increased if the content of NaCl in W₂ is higher than 0.2%. In contrast to NaCl, the addition of Vitamin C merely slightly decrease the interfacial tension between W₁/O interface. Thus, in this work the amount of NaCl is kept at 0.2% both in internal and external aqueous phases of W₁/O/W₂, and the effects of Vitamin C concentration in W₁ on the microscopic states and appearance of the multiple emulsion are investigated. A homogeneous and stable multiple emulsion could be obtained with the encapsulation of Vitamin C at 0.75%.

Key words: W₁/O/W₂ multiple emulsion, interfacial tension, droplet size, viscosity, encapsulation

CLC Number:

O648.2 +3

CHEN Kai-li,LIU Dong,ZHANG Yun,NI Xin-jiong,CAO Yu-hua,CAO Guang-qun. Effects of sodium chloride on the multiple emulsion encapsulating Vitamin C[J].China Surfactant Detergent & Cosmetics, 2019, 49(12): 805-810.

Figures/Tables 9

Fig. 1

Fig. 2

Fig. 3

Fig. 4

Fig. 5

Fig. 6

Fig. 7

Fig. 8

Fig. 9

References 22

[1]	Garti Nissim . Double emulsions——scope, limitations and new achievements[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 1997,123:233-246.
[2]	Muschiolik Gerald, Dickinson Eric . Double emulsions relevant to food systems[J]. Comprehensive Reviews in Food Science and Food Safety, 2017,16(3) : 532-555. doi: 10.1039/c9fo01266d pmid: 31495859
[3]	Tang S Y, Sivakumar M . Design and evaluation of aspirin-loaded water-in-oil-in-water submicron multiple emulsions generated using two-stage ultrasonic cavitational emulsification technique[J]. Asi-pacific Journal of Chemical Engineering, 2012,7(Supplement S1) : 145-156.
[4]	Neumann S M, Scherbej I, Van Der Schaaf U S , et al. Investigations on the influence of osmotic active substances on the structure of water in oil emulsions for the application as inner phase in double emulsions[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2018,538:56-62. doi: 10.1016/j.colsurfa.2017.10.073
[5]	Florence A T, Whitehill D . Some features of breakdown in water-in-oil-in-water multiple emulsions[J]. Journal of Colloid and Interface Science, 1981,79(1) : 243-256. doi: 10.1016/j.jcis.2008.05.066 pmid: 18632110
[6]	Pal Rajinder . Viscosity models for multiple emulsions[J]. Food Hydrocolloids, 2008,22(3) : 428-438. doi: 10.1016/j.foodhyd.2006.12.012
[7]	Su Jiahong, Flanagan John, Hemar Yacine , et al. Synergistic effects of polyglycerol ester of polyricinoleic acid and sodium caseinate on the stabilisation of water-oil-water emulsions[J]. Food Hydrocolloids, 2004,20(2) : 261-268. doi: 10.1016/j.foodhyd.2004.03.010
[8]	Benichou A, Aserin A, Garti N . Double emulsions stabilized with hybrids of natural polymers for entrapment and slow release of active matters[J]. Advances in Colloid and Interface Science, 2004,108:29-41. doi: 10.1016/j.cis.2003.10.013 pmid: 15072926
[9]	Liu Wenli, Jiao Weizhou, Liu Youzhi , et al. Progress in study of stability and application of W/O/W multiple emulsion[J]. China Surfactant Detergent & Cosmetics, 2012,42(5) : 366-370. doi: 10.1016/j.chemosphere.2019.125559 pmid: 31841794
[10]	Lamba Heena, Sathish Kumar, Sabikhi Latha . Double Emulsions: emerging delivery system for plant bioactives[J]. Food and Bioprocess Technology, 2015,8(4) : 709-728. doi: 10.1007/s11947-014-1468-6
[11]	Gu Chengyu, Hu Caibiao, Ma Chaolong , et al. Development and characterization of solid lipid microparticles containing Vitamin C for topical and cosmetic use[J]. European Journal of Lipid Science and Technology, 2016,118(7) : 1093-1103. doi: 10.1002/ejlt.v118.7
[12]	Devi Nirmala, Kakati Dilip-Kumar . Smart porous microparticles based on gelatin/sodium alginate polyelectrolyte complex[J]. Journal of Food Engineering, 2013,117(2) : 193-204. doi: 10.1016/j.jfoodeng.2013.02.018
[13]	Chen Tingting, Cao Guangqun, Yang Cheng . Preparation and property of peg-coated Vitamin C-containing liposome[J]. Soybean Science, 2008,27(3) : 505-508.
[14]	Kawai T, Saito K, Sugita K , et al. Immobilization of ascorbic acid oxydase in multilayers onto porous hollow-fiber membrane[J]. Journal of Membrane Science, 2001,191(1) : 207-213. doi: 10.1016/S0376-7388(01)00465-3
[15]	Kheynoor Najme, Hosseini Seyed-Mohammad-Hashem, Yousefi Gholam-Hosseini , et al. Encapsulation of Vitamin C in a rebaudioside-sweetened model beverage using water in oil in water double emulsions[J]. LWT - Food Science and Technology, 2018,96:419-425. doi: 10.1016/j.lwt.2018.05.066
[16]	Liu Lixian, Jiang Ligang, Shen Fengshou , et al. Advanced progress in encapsulation technologies for ascorbic acid[J]. Flavour Fragrance Cosmetics, 2015,6:56-61.
[17]	Zhuo Xiaolu, Ni Xinjiong, Xu Xiaojin , et al. Encapsulation of Vitamin A with amphiphilic poly (methyl methacrylate - co - methacrylic acid)micelles[J]. China Surfactant Detergent & Cosmetics, 2014,44(2) : 61-65. doi: 10.1016/j.chemosphere.2019.125559 pmid: 31841794
[18]	Kanouni M, Rosano H-L, Naouli N . Preparation of a stable double emulsion[J]. Advances in Colloid and Interface Science, 2002,99(3) : 229-254. doi: 10.1016/s0001-8686(02)00079-9 pmid: 12509116
[19]	Sapei Lanny, Naqvi Muhammad-Ali, Rousseau Derick . Stability and release properties of double emulsions for food applications[J]. Food Hydrocolloids, 2012,27(2) : 316-323. doi: 10.1016/j.foodhyd.2011.10.008
[20]	Maxime Nollet, Eric Laurichesse, Samantha Besse , et al. Determination of formulation conditions allowing double emulsions stabilized by PGPR and sodium caseinate to be used as capsules[J]. Langmuir: The ACS journal of Surfaces and Colloids, 2018,8(34) : 2823-2833. doi: 10.1021/acs.langmuir.7b04085 pmid: 29406736
[21]	Liu Hongjing . The stability of W/O/W multiple emulsion and its application in loading insulin[D]. Dalian:Dalian University of Technology, 2001.
[22]	Iqbal Shahid, Baloch Musa Kaleem, Hameed Gulzar , et al. Controlling W/O/W multiple emulsion microstructure by osmotic swelling and internal protein gelation[J]. Food Research International, 2013,54(2) : 1613-1620. doi: 10.1016/j.foodres.2013.09.035

Effects of sodium chloride on the multiple emulsion encapsulating Vitamin C

RichHTML

PDF (PC)

Like

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 9

References 22

Related Articles 15

Metrics

Comments

Recommended 10

[1]	Xiaojie Zhang, Mingzhe Zhang, Zhicheng Xu, Qingtao Gong, Lei Zhang, Lu Zhang. Study on oil displacement mechanism of alkyl carboxyl betaine [J]. China Surfactant Detergent & Cosmetics, 2024, 54(2): 123-130.
[2]	Xiong Jie, Yang Dan, Meng Hong, He Yifan, Pei Xiaojing. Research progress in skin physiological effects and its cosmetic encapsulation technology of ferulic acid [J]. China Surfactant Detergent & Cosmetics, 2023, 53(9): 1073-1079.
[3]	Chang Shiteng, Cai Xiaojun, Zheng Yancheng, Liu Xuejin, Yi Xiao, Jiang Zhuyang. Physicochemical properties of ethoxylated sulfosuccinate surfactants and their interfacial properties when mixed with a betaine surfactant [J]. China Surfactant Detergent & Cosmetics, 2023, 53(9): 989-998.
[4]	Yi Xiao, Tian Fuquan, Zheng Yancheng, Wang Shuaidong, Cai Xiaojun, Luo Fangcao, Chang Shiteng. Properties of mixtures of tetradecanoic acid monoethanolamide ether sulfonate and tetradecanoic acid diethanolamide [J]. China Surfactant Detergent & Cosmetics, 2023, 53(6): 609-616.
[5]	Yang Bin. Study on rheological and interfacial properties of a synergistic mixture of hydrophobically associating polymer HAWP and erucamidopropyl allyl ammonium bromide [J]. China Surfactant Detergent & Cosmetics, 2023, 53(4): 365-372.
[6]	Guo Fang. Influence of emulsifiers and thickener on formation of low-viscosity liquid crystal emulsions [J]. China Surfactant Detergent & Cosmetics, 2023, 53(1): 16-23.
[7]	Zhao Yilu,Cheng Hongxiao,Xu Lina,Wang Xiaodong,Zhao Changxi,Li Xindan,Ren Hong. Optimization and emulsification mechanism of emulsified viscosity reducer with high temperature resistance for heavy oil in Henan Oilfield [J]. China Surfactant Detergent & Cosmetics, 2022, 52(7): 724-730.
[8]	Xie Zhihui,Liu Jianzhong,Ning Haoliang,Yu Yuanhao,Chen Yamin,Peng Shuge. Preparation of an O/W microemulsion nano-carrier and its performance in cannabidiol encapsulation [J]. China Surfactant Detergent & Cosmetics, 2022, 52(5): 514-520.
[9]	Zhang Yun,Li Chen,Yu Sihan,Liu Dong. Study on preparation and performances of high suspension ability detergent [J]. China Surfactant Detergent & Cosmetics, 2022, 52(3): 253-257.
[10]	Xiao Sa,Sun Yubao,Wang Shaohua,Wu Chunzhou,Shu Zhan. Preparation and performance evaluation of oil soluble viscosity reducer for heavy oil fields in Canada [J]. China Surfactant Detergent & Cosmetics, 2021, 51(9): 832-838.
[11]	CHEN Si-jia,YI Ya,ZHANG Da-wei. Effects of glycerol on the storage stability of the chitosan solution [J]. China Surfactant Detergent & Cosmetics, 2021, 51(4): 306-311.
[12]	LI Jin-feng,GAO Ying,NING Ke-gong,ZHANG Qiu-xia,LIU Ping,WU Peng,LI Li-xian. Development and research of a low-viscosity suspension [J]. China Surfactant Detergent & Cosmetics, 2021, 51(2): 132-138.
[13]	Wang Qihao,Guo Haiyan,Wang Yuyi,Huang Xiaohe,Zhang Ya,Long Yunqian. Evaluation of enhanced oil recovery of the binary composite flooding system based on the sulfonate of kitchen waste oil and polyacrylamide [J]. China Surfactant Detergent & Cosmetics, 2021, 51(10): 932-938.
[14]	ZHANG Ran-ran,DU Yu-lan,FAN Pei-hao,ZHANG Yun-xian. Study and analysis on the stability of water-in-oil emulsions [J]. China Surfactant Detergent & Cosmetics, 2020, 50(8): 566-571.
[15]	WANG You,ZUO Shi-xiang,LI Xia-zhang,LIU Wen-jie,XU Rong,ZHONG Jing,YAO Chao. Rheological and UV protective properties of ultrafine TiO₂ in silicone oil [J]. China Surfactant Detergent & Cosmetics, 2020, 50(2): 112-117.