无患子皂苷-十二烷基苯磺酸钠复配体系表面活性及在制备氢氧化镍复合材料中的应用

doi:10.13218/j.cnki.csdc.2016.05.005

Abstract

Abstract: Surface activity of Sapindus mukurossi saponin and sodium dodecyl benzene sulfonate (SBDS) blend system was examined,and the blends were used to prepare nickel hydroxide composites.The composites were characterized with X-ray diffraction (XRD) and scanning electron microscope (SEM).Influence of the surfactant on morphology of the composites was investigated.Results revealed that the critical micelle concentration (cmc) and the surface tension (γ_cmc) of the extracted Sapindus mukurossi saponin are 0.200 g/L and 38.3 mN/m respectively.The blend system displays synergic effect when mass fraction of SDBS achieves 5%,while confrontation effect when mass fraction of SDBS is more than 20%.Using the blend system composed of 5% SDBS as additive at dosage of 0.83 g/L,homogeneous morphological microspheres of nickel hydroxide composites with average diameter of 3 μm can be successfully prepared.

Key words: Sapindus mukurossi saponin, sodium dodecyl benzene sulfonate, blend system, nickel hydroxide, composites

CLC Number:

TQ423

ZHAN Shu-hui,LI Juan,LIU Ze-xue,XU Yong-xia,LI Bao-tong,HAN Chun-rui. Surface activity of sapindoside-dodecyl benzene sulfonate blend system and its application for preparation of nickel hydroxide composites[J].China Surfactant Detergent & Cosmetics, 2016, 46(5): 264-266.

References

[1] 刘红芹,李飞,徐博,等.特种表面活性剂和功能性表面活性剂(Ⅸ):天然表面活性剂的性能与应用[J].日用化学工业,2012,42(2):135-140.
[2] PENG Q X,ZHANG Q,XIAO W,et al.Protective effects of Sapindus mukorossi Gaertn against fatty liver disease induced by high fat diet in rats [J].Biochemical and Biophysical Research Communications,2014,450(1):685-691.
[3] WU H,ZHANG L,WANG N,et al.Analysis of the bioactive components of Sapindus saponins [J].Industrial Crops and Products,2014,61:422-429.
[4] SCHMITT C,GRASSL B,LESPES G,et al.Saponins:A renewable and biodegradable surfactant from its microwave-assisted extraction to the synthesis of monodisperse lattices [J].Biomacromolecules,2014,15(3):856-862.
[5] BERGSTR M L M,BRAMER T.Synergistic effects in mixtures of oppositely charged surfactants as calculated from the Poisson-Boltzmann theory:A comparison between theoretical predictions and experiments [J].Journal of Colloid and Interface Science,2008,322(2):589-595.
[6] NEGM N A,MISHRIF M R,MOHAMED D E.Vanillin based cationic surfactants mixed systems:Micellization and interfacial interaction behaviors in presence of nonionic conventional surfactant [J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2015,480:122-129.
[7] 伍恒,王娜,翁震,等.无患子皂苷及复配体系表面活性的研究[J].精细化工,2013(2):149-154.
[8] BISWAL N R,PARIA S.Interfacial and wetting behavior of natural-synthetic mixed surfactant systems [J].RSC Advances,2014,4(18):9182-9188.
[9] 孙洁如,陈孔常,周鸣方,等.无患子表面活性物及其复配体系的性质研究[J].日用化学工业,2002,32(4):16-18.
[10] 王正武,李干佐,李英,等.皂荚素及其复配体系表面活性的研究[J].日用化学工业,2000,30(6):1-4.
[11] 宋金梅,张玉秀,朱书全,等.表面活性剂在电池材料中的应用[J].现代化工,2011(1):28-31.
[12] 吴志韵,程建华.无患子皂苷及其复配体系的泡沫性能研究[J].香料香精化妆品,2013(2):60-63.
[13] XU Y X,LI B T,LI J,et al.Controlled hydrothermal synthesis of ball-flower Ni(OH)₂/NiOOH composites assisted by rosin-based betaine zwitterionic surfactant [J].Journal of Materials Science:Materials in Electronics,2015,26(10):8040-8046.
[14] HAN C R,WU X Y,LIN Y S,et al.Preparation and characterization of Y₂O₃ hollow spheres [J].Journal of Materials Science,2006,41:1212,3679-3682.

Surface activity of sapindoside-dodecyl benzene sulfonate blend system and its application for preparation of nickel hydroxide composites

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