Pickering乳液的研究进展

doi:10.13218/j.cnki.csdc.2014.08.103

Abstract

Abstract: Stabilization mechanisms of Pickering emulsion,including mechanical barrier mechanism and three-dimensional viscoelastic particles network mechanism,were introduced.The current research work status about Pickering emulsion covering emulsion stabilized by spherical particles,emulsion stabilized by layered particles as well as various environmental stimuli (such as pH,temperature,electric fields,and magnetic fields et al.) responding type emulsion,were summarized.Meanwhile,the concerning applications of Pickering emulsion such as emulsion polymerization,functional material preparation,drug release,catalyst separation and recycling,were described.At last,the development trend of Pickering emulsion was prospected.

Key words: Pickering emulsion, solid particles, stabilization mechanism, stimulative respond, progress

CLC Number:

O648.2+3

LU Jia, TIAN Xiao-xiao, JIN Ye-ling, CHEN Jing, DING Shi-jie. Progress in research work with respect to Pickering emulsion[J].China Surfactant Detergent & Cosmetics, 2014, 44(8): 460-466.

References

[1] RAMSDEN W.Separation of solids in the surface-layers of solutions and ‘suspensions’ (observations on surface-membranes,bubbles,emulsions,and mechanical coagulation):Preliminary account [J].Proceedings of the Royal Society of London,1903,72:156-164.
[2] PICKERING S U.Emulsions [J].Journal of the Chemical Society,Transactions,1907,91:2001-2021.
[3] BINKS B P.Particles as surfactants:Similarities and differences [J].Current Opinion in Colloid & Interface Science,2002,7(1):21-41.
[4] 易成林,杨逸群,江金强,等.颗粒乳化剂的研究及应用[J].化学进展,2011,23(1):65-79.
[5] LAGALY G,REESE M,ABEND S.Smectites as colloidal stabilizers of emulsions.II:Rheological properties of smectite-laden emulsions [J].Applied Clay Science,1999,14(5):279-298.
[6] LAGALY G,REESE M,ABEND S.Smectites as colloidal stabilizers of emulsions.I:Preparation and properties of emulsions with smectites and nonionic surfactants [J].Applied Clay Science,1999,14(1):83-103.
[7] 陈洪龄,吴玮.颗粒稳定乳液和泡沫体系的原理和应用(Ⅰ):Pickering乳液的稳定机制和影响因素[J].日用化学工业,2013,43(1):10-15.
[8] MADIVALA B,VANDEBRIL S,FRANSAER J,et al.Exploiting particle shape in solid stabilized emulsions [J].Soft Matter,2009,5(8):1717-1727.
[9] DE FOLTER J W J,HUTTER E M,CASTILLO S I R,et al.Particle shape anisotropy in Pickering emulsions:Cubes and peanuts [J].Langmuir,2014,30(4):955-964.
[10] KALASHNIKOVA I,BIZOT H,CATHALA B,et al.New Pickering emulsions stabilized by bacterial cellulose nanocrystals [J].Langmuir,2011,27(12):7471-7479.
[11] TZOUMAKI M V,MOSCHAKIS T,KIOSSEOGLOU V,et al.Oil-in-water emulsions stabilized by chitin nanocrystal particles [J].Food Hydrocolloids,2011,25(6):1521-1529.
[12] HE YONGQIANG,WU FEI,SUN XIYING,et al.Factors that affect Pickering emulsions stabilized by graphene oxide [J].ACS Applied Materials & Interfaces,2013,5(11):4843-4855.
[13] LIU HAO,WANG CHAOYANG,ZOU SHENGWEN,et al.Simple,reversible emulsion system switched by pH on the basis of chitosan without any hydrophobic modification [J].Langmuir,2012,28(30):11017-11024.
[14] 陈浩,张晓优,徐樟浩,等.凹凸棒颗粒稳定的Pickering乳状液的制备条件及形成机理研究[J].非金属矿,2013,36(3):13-17,42.
[15] AVEYARD R,BINKS B P,CLINT J H.Emulsions stabilised solely by colloidal particles [J].Advances in Colloid and Interface Science,2003,100:503-546.
[16] BINKS B P,CLINT J H.Solid wettability from surface energy components:Relevance to Pickering emulsions [J].Langmuir,2002,18(4):1270-1273.
[17] BINKS B P,LUMSDON S O.Stability of oil-in-water emulsions stabilised by silica particles [J].Physical Chemistry Chemical Physics,1999,1(12):3007-3016.
[18] THIEME J,ABEND S,LAGALY G.Aggregation in Pickering emulsions [J].Colloid and Polymer Science,1999,277(2/3):257-260.
[19] ASHBY N P,BINKS B P.Pickering emulsions stabilised by laponite clay particles [J].Physical Chemistry Chemical Physics,2000,2(24):5640-5646.
[20] YANG FEI,LIU SHANGYING,XU JIAN,et al.Pickering emulsions stabilized solely by layered double hydroxides particles:the effect of salt on emulsion formation and stability [J].Journal of Colloid and Interface Science,2006,302(1):159-169.
[21] SAIGAL T,DONG HONGCHEN,MATYJASZEWSKI K,et al.Pickering emulsions stabilized by nanoparticles with thermally responsive grafted polymer brushes [J].Langmuir,2010,26(19):15200-15209.
[22] READ E S,FUJII S,AMALVY J I,et al.Effect of varying the oil phase on the behavior of pH-responsive latex-based emulsifiers:Demulsification versus transitional phase inversion [J].Langmuir,2004,20(18):7422-7429.
[23] BINKS B P,MURAKAMI R,ARMES S P,et al.Effects of pH and salt concentration on oil-in-water emulsions stabilized solely by nanocomposite microgel particles [J].Langmuir,2006,22(5):2050-2057.
[24] NGAI T,BEHRENS S H,AUWETER H.Novel emulsions stabilized by pH and temperature sensitive microgels [J].Chemical Communications,2005(3):331-333.
[25] TSUJI S,KAWAGUCHI H.Thermosensitive Pickering emulsion stabilized by poly (N-isopropylacrylamide)-carrying particles [J].Langmuir,2008,24(7):3300-3305.
[26] LI ZIFU,NGAI T.Stimuli-responsive gel emulsions stabilized by microgel particles [J].Colloid and Polymer Science,2011,289(5/6):489-496.
[27] HWANG K,SINGH P,AUBRY N.Destabilization of Pickering emulsions using external electric fields [J].Electrophoresis,2010,31(5):850-859.
[28] KIM E G,STRATFORD K,CLEGG P S,et al.Field-induced breakup of emulsion droplets stabilized by colloidal particles [J].Physical Review E,2012,85(2):020403.
[29] ZHOU JUN,QIAO XIUYING,BINKS B P,et al.Magnetic Pickering emulsions stabilized by Fe₃O₄ nanoparticles [J].Langmuir,2011,27(7):3308-3316.
[30] QIAO XIUYING,ZHOU JUN,BINKS B P,et al.Magnetorheological behavior of Pickering emulsions stabilized by surface-modified Fe₃O₄ nanoparticles [J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2012,412:20-28.
[31] CHEN J H,CHENG C Y,CHIU W Y,et al.Synthesis of ZnO/polystyrene composites particles by Pickering emulsion polymerization [J].European Polymer Journal,2008,44(10):3271-3279.
[32] YANG YONGFANG,ZHANG JIAN,LIU LI,et al.Synthesis of PS and PDMAEMA mixed polymer brushes on the surface of layered silicate and their application in Pickering suspension polymerization [J].Journal of Polymer Science Part A:Polymer Chemistry,2007,45(24):5759-5769.
[33] CAUVIN S,COLVER P J,BON S A F.Pickering stabilized miniemulsion polymerization:Preparation of clay armored latexes [J].Macromolecules,2005,38(19):7887-7889.
[34] AKARTUNA I,STUDART A R,TERVOORT E,et al.Macroporous ceramics from particle-stabilized emulsions [J].Advanced Materials,2008,20(24):4714-4718.
[35] IKEM V O,MENNER A,HOROZOV T S,et al.Highly permeable macroporous polymers synthesized from Pickering medium and high internal phase emulsion templates [J].Advanced Materials,2010,22(32):3588-3592.
[36] HE YONGJUN,YU XIANGYANG.Preparation of silica nanoparticle-armored polyaniline microspheres in a Pickering emulsion [J].Materials Letters,2007,61(10):2071-2074.
[37] DUAN LINGLI,CHEN MIN,ZHOU SHUXUE,et al.Synthesis and characterization of poly (N-isopropylacrylamide)/silica composite microspheres via inverse Pickering suspension polymerization [J].Langmuir,2009,25(6):3467-3472.
[38] SUZUKI D,TSUJI S,KAWAGUCHI H.Janus microgels prepared by surfactant-free Pickering emulsion-based modification and their self-assembly [J].Journal of the American Chemical Society,2007,129(26):8088-8089.
[39] LI DONG,HE YONGJUN,WANG SHA.On the rotation of the janus CuO/CuS colloids formed at a Pickering emulsion interface [J].The Journal of Physical Chemistry C,2009,113(30):12927-12929.
[40] BON S A F,CHEN TAO.Pickering stabilization as a tool in the fabrication of complex nanopatterned silica microcapsules [J].Langmuir,2007,23(19):9527-9530.
[41] GAO QUANXING,WANG CHAOYANG,LIU HONGXIA,et al.Suspension polymerization based on inverse Pickering emulsion droplets for thermo-sensitive hybrid microcapsules with tunable supracolloidal structures [J].Polymer,2009,50(12):2587-2594.
[42] YANG HENGQUAN,ZHOU TING,ZHANG WENJUAN.A strategy for separating and recycling solid catalysts based on the pH-triggered Pickering-emulsion inversion [J].Angewandte Chemie International Edition,2013,52(29):7455-7459.
[43] PRESTIDGE C A,SIMOVIC S.Nanoparticle encapsulation of emulsion droplets [J].International Journal of Pharmaceutics,2006,324(1):92-100.
[44] SIMOVIC S,PRESTIDGE C A.Nanoparticle layers controlling drug release from emulsions [J].European Journal of Pharmaceutics and Biopharmaceutics,2007,67(1):39-47.
[45] FRELICHOWSKA J,BOLZINGER M A,VALOUR J P,et al.Pickering W/O emulsions:Drug release and topical delivery [J].International Journal of Pharmaceutics,2009,368(1):7-15.

Progress in research work with respect to Pickering emulsion

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