十六烷基三甲基溴化铵-珍珠粉相互作用及其稳定乳液的双重相转变

doi:10.3969/j.issn.1001-1803.2022.05.002

Abstract

Abstract:

The effect of cationic surfactant cetyltrimethyl ammonium bromide （CTAB） on the type and microstructure of Pickering emulsions prepared with biomass-based pearl powder were systematically studied. The double phase inversion from O/W type to W/O type and then to O/W type of emulsions stabilized by CTAB/pearl powder was analyzed. The interaction between CTAB and pearl powder particles was analyzed by dispersion observation, Zeta potential determination, the three-phase contact angles characterization and fluorescent labeling of pearl powder. The results show that pearl powder can stabilize O/W Pickering emulsions when CTAB is not added or the concentration of CTAB is low （0.01 mmol/L）, and the emulsion droplets are not spherical and have coalescence. When the concentration of CTAB increases to 0.05 mmol/L and 0.20 mmol/L, the adsorption of CTAB on the surface of pearl powder enhances the hydrophobicity of the particles, and the change of wettability leads to the phase inversion of the emulsion from O/W type to W/O type. At the same time, the microstructure of the emulsions is spherical and the size distribution is narrow. As the concentration of CTAB increases to 0.90 mmol/L, CTAB replaces the pearl powder particles at the oil-water interface. Fluorescence microscope observation verifies that the O/W emulsion formed is stabilized by excessive CTAB. That is, by simply increasing the concentration of CTAB, the emulsion can realize the double phase inversion from O/W type to W/O type, and then to O/W type.

Key words: cetyltrimethyl ammonium bromide, pearl powder, adsorption, Pickering emulsions, double phase inversion

CLC Number:

TQ423

Zhang Qianjie,Shen Xingliang,Sheng Taotao,Zhang Wanping,Xu Jianying. The interaction of cetyltrimethyl ammonium bromide-pearl powder and its stabilization of the double phase inversion in emulsions[J].China Surfactant Detergent & Cosmetics, 2022, 52(5): 468-475.

Figures/Tables 8

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References 21

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The interaction of cetyltrimethyl ammonium bromide-pearl powder and its stabilization of the double phase inversion in emulsions

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