一类反应型两性表面活性剂的合成及性能研究

doi:10.13218/j.cnki.csdc.2018.04.001

Abstract

Abstract: Three reactive zwitterionic surfactants (M10,M12 and M14) with different alkyl chain lengths had been synthesized by using N,N-dimethyl-1,3-propanediamine,maleic anhydride and alkyl bromide as principal raw materials.The compounds had been characterized by FT-IR,ESI-MS and ¹H-NMR.The critical micelle concentration (cmc) and the corresponding surface tension (γ_cmc) of M10,M12 and M14 in aqueous solution were measured at 25 ℃ by surface tensiometer.The foam properties,wetting properties,emulsifying properties and solubility were also determined.Results show that the cmc of M10,M12 and M14 at 25 ℃ are 5.89×10^-4,2.63×10^-4 and 1.35×10^-4 mol/L,and their γ_cmc values are 31.26,28.79 and 26.87 mN/m,respectively.The foam properties,emulsifying properties and wetting properties of M14 are better than those of M10 and M12,while the solubility of M14 is slightly worse than that of M10 and M12.

Key words: reactive, zwitterionic, surface properties, application performance

CLC Number:

TQ423

LI Ke, XU Jin, XU Hu-jun. Synthesis and properties of a series of reactive zwitterionic surfactants[J].China Surfactant Detergent & Cosmetics, 2018, 48(4): 183-187.

References

[1] Ge H,Shao H F,Zhang Z Q,et al.Research progress of reactive surfactants [J].China Surfactant Detergent & Cosmetics,2007,37(2):112-114.
[2] Huang Y H,Zheng C,Lin J,et al.Progress in research work on synthesis and application of reactive quaternary ammonium salt cationic surfactants [J].China Surfactant Detergent & Cosmetics,2014,44(3):155-162.
[3] Hou Y Q,Li Z,Gao X Y,et al.Reactive emulsifiers and their applications in emulsion polymerization [J].Modern Paint and Finishing,2008,11(4):11-14.
[4] Wan B,Wang D N.Synthesis of reactive emulsifier and its application in emulsion polymerization [J].China Synthetic Rubber Industry,2003,26(2):94-97.
[5] Zhu M Y,Qiao W H,Bi G C,et al.Reactive emulsifiers for emulsion polymerization [J].Chemical Industry and Engineering Progress,2006,25(5):490-492.
[6] Yang J H,Zhu Y H.Influences of maleic reactive surfactants with different EO chain lengths on the properties of the acrylate lattices [J].Journal of Coatings Technology and Research,2015,12(6):1041-1052.
[7] Zicmanis A,Hamaide T,Abele S,et al.Synthesis of new alkyl maleates ammonium derivatives and their uses in emulsion polymerization [J].Colloid and Polymer Science,1997,275(1):1-8.
[8] Suresh K I,Foerst G,Schubert R,et al.Synthesis and micellization properties of new anionic reactive surfactants based on hydrogenated cardanol [J].Journal of Surfactants and Detergents,2012,15(2):207-215.
[9] Fang C,Jing Y,Lin Z.The application research of environment-friendly reactive surfactants in acrylate emulsion pressure sensitive adhesives [J].International Journal of Adhesion & Adhesives,2017,73:1-7.
[10] Wang B,Wang H,Wang E,et al.Isolation and structure characterization of related impurities in Sodium Tanshinone IIA Sulfonate by LC/ESI-MS(n) and NMR [J].Journal of Pharmaceutical and Biomedical Analysis,2012,67-68(3):36-41.
[11] Li P,Zhou Z P,Ma W W.Synthesis of sodium maleic hemihexadecylester propylsulfonate and its application in surface sizing of fiber [J].Journal of Functional Materials,2016,47(6):214-218.[12] Gong T,Lu D P.Synthesis of novel cationic maleic diester polymerizable surfactant [J].Journal of Hubei University (Natural Science Edition),2004,26(1):52-56.
[13] Deng J R,Shen H G,Yu H G,et al.Study of the synthesis of reactive emulsifier dodecanol maleic anhydride sodium and its properties [J].Journal of Hunan University (Natural Sciences Edition),2008,35(10):55-59.
[14] Zhu M Y,Qiao W H,Liu H Z,et al.Maleate-based polymerizable emulsifier [J].Fine and Specialty Chemicals,2007,15(11):10-14.
[15] Gong T,Lu D P.Synthesis of novel cationic maleic diester polymeri-zable surfactant [J].Journal of Hubei University (Natural Science Edition),2004,26(1):52-54.
[16] Yang J Z,Wang W P,Kuang D Y,et al.A research on the composition of the maleic acid bi-cationic ester surface active agent [J].Knitting Industries,2008,10:48-51.
[17] Mao J M,Xu H J,Liu B N,et al.Synthesis and properties of ammonium nonylphenol polyoxyethylene ether sulfate [J].Speciality Petrochemicals,2014,31:6-10.

Synthesis and properties of a series of reactive zwitterionic surfactants

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