醇醚丙酸盐表面活性剂的合成及表面活性

doi:10.13218/j.cnki.csdc.2014.09.107

Abstract

Abstract: Four kinds of fatty alcohol ether propionate were synthesized via addition and saponification with fatty alcohol (octanol,decanol and dodecanol),fatty alcohol polyoxyethylene ether (AEO₇) and tert-butyl acrylate as raw materials.Structure of the products was characterized by FTIR,¹HNMR and ESI-MS methods.The addition reaction parameters were optimized via a series of experiments as follows:n(fatty alcohol (AEO₇)):n(tert-butyl-acrylate):n(sodium methoxide)=1:3:0.02;reaction temperature,50 ℃;reaction time,6 h.The products show good surface activity.With increasing of the carbon chain length,their cmc,γ_cmc and A_min decreases while Γ_max and pc₂₀ increases.However,the results were reversed as the fatty alcohol molecules are ethoxylated.

Key words: alcohol ether propionate, fatty alcohol, fatty alcohol polyoxyethylene ether, tert-butyl acrylate, synthesis, surface activity

CLC Number:

TQ423.11

WANG Jun, YANG Xu-zhao, MIAO Jin-hui, ZOU Wen-yuan, CHEN Xiang. Synthesis and surface activity of alcohol ether propionate surfactants[J].China Surfactant Detergent & Cosmetics, 2014, 44(9): 481-485.

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Synthesis and surface activity of alcohol ether propionate surfactants

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