表面活性剂和二氧化硅纳米颗粒协同稳定的Pickering乳液用于提高花青素稳定性

doi:10.3969/j.issn.2097-2806.2026.06.002

日用化学工业（中英文） ›› 2026, Vol. 56 ›› Issue (6): 706-716.doi: 10.3969/j.issn.2097-2806.2026.06.002

表面活性剂和二氧化硅纳米颗粒协同稳定的Pickering乳液用于提高花青素稳定性

周澍¹,罗致勇¹,王艺越¹,万玉垚¹,曾飒²,孟涛^1,^*()

¹ 西南交通大学生命科学与工程学院，四川成都 610031
² 广州栋方生物科技股份有限公司，广东广州 510800

收稿日期:2025-11-20 修回日期:2026-06-16 出版日期:2026-06-22 发布日期:2026-07-22
基金资助:
国家自然科学基金资助项目(22378336);国家自然科学基金资助项目(22204130);四川省科技厅重点研发项目(2020YFG0092);四川省科技厅重点研发项目(2021YFN0129);企业联合项目(R111322H01008)

Pickering emulsions stabilized by silica nanoparticles in combination with surfactant for the enhancement of the stability of anthocyanins

Shu Zhou¹,Zhiyong Luo¹,Yiyue Wang¹,Yuyao Wan¹,Sa Zeng²,Tao Meng^1,^*()

¹ School of Life Sciences & Engineering, Southwest Jiaotong University, Chengdu, Sichuan 610031, China
² Guangzhou Ridgepole Biological Technology Co., Ltd., Guangzhou, Guangdong 510800, China

Received:2025-11-20 Revised:2026-06-16 Online:2026-06-22 Published:2026-07-22
Contact: ^*E-mail: taomeng@swjtu.edu.cn

摘要/Abstract

摘要：

针对花青素等活性物在使用中易失活的应用瓶颈，该研究构建了二氧化硅纳米颗粒（SiO₂ NPs）与司盘80 （Span 80）借助静电吸附来共同稳定Pickering乳液体系以提高花青素稳定性。共稳定型Pickering乳液的花青素包封率为98.5%。在紫外光照射实验中，共稳定型Pickering乳液中花青素保留率分别为SiO₂乳液组、Span 80乳液组及花青素水溶液的1.4倍、3.3倍及36.9倍。该共稳定型Pickering乳液体系展现出良好的稳定性，37 ℃储存21天后粒径仅增大38.2 μm，远小于SiO₂组乳液（94.6 μm）和Span 80组乳液（263.3 μm）的变化量。实验结果表明，SiO₂ NPs和Span 80协同作用提高了Pickering乳液的稳定性，同时增强了花青素的光稳定性。为日用化学工业中活性物稳定性保护提供了新平台。

关键词: Pickering乳液, 花青素, 纳米颗粒, 表面活性剂, 稳定性

Abstract:

To address the practical challenge of activity loss in anthocyanins and other bioactive compounds in application, a Pickering emulsion system co-stabilized by silica nanoparticles （SiO₂ NPs） and Span 80 via electrostatic adsorption is developed to enhance anthocyanin stability. The co-stabilized Pickering emulsion achieves an anthocyanin encapsulation efficiency of 98.5%. Under ultraviolet irradiation, the anthocyanin retention rate in the co-stabilized emulsion is 1.4 times, 3.3 times, and 36.9 times higher than that in the SiO₂ NP-stabilized Pickering emulsion, Span 80-stabilized emulsion, and free anthocyanin solution, respectively. The co-stabilized Pickering emulsion also demonstrates excellent storage stability, with a minimal increase in droplet size of only 38.2 μm after 21 days of storage at 37 ℃, significantly lower than the increases of the SiO₂ NP-stabilized Pickering emulsion （94.6 μm） and the Span 80-stabilized emulsion （263.3 μm）. These results indicate that the synergistic interaction between SiO₂ NPs and Span 80 not only improves the stability of the Pickering emulsion but also enhances the photostability of anthocyanins. This study provides a promising platform for improving the stability of active ingredients in the daily chemical industry.

Key words: Pickering emulsion, anthocyanins, nanoparticles, surfactant, stability

中图分类号:

TQ423

周澍, 罗致勇, 王艺越, 万玉垚, 曾飒, 孟涛. 表面活性剂和二氧化硅纳米颗粒协同稳定的Pickering乳液用于提高花青素稳定性[J]. 日用化学工业（中英文）, 2026, 56(6): 706-716.

Shu Zhou, Zhiyong Luo, Yiyue Wang, Yuyao Wan, Sa Zeng, Tao Meng. Pickering emulsions stabilized by silica nanoparticles in combination with surfactant for the enhancement of the stability of anthocyanins[J]. China Surfactant Detergent & Cosmetics, 2026, 56(6): 706-716.

图/表 7

参考文献 24

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表面活性剂和二氧化硅纳米颗粒协同稳定的Pickering乳液用于提高花青素稳定性

Pickering emulsions stabilized by silica nanoparticles in combination with surfactant for the enhancement of the stability of anthocyanins

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