阴/阳离子表面活性剂自发囊泡的氧化还原响应行为研究

doi:10.3969/j.issn.1001-1803.2019.11.001

Abstract

Abstract:

Spontaneous vesicles were formed by the combination of sodium dodecylselanylpropyl sulfate （SDSePS）, a redox-responsive anionic surfactant, and a cationic surfactant dodecyltrimethylammonium bromide （DTAB）. Then the redox reversible response behavior of the vesicles was explored. The results show that, under the action of H₂O₂, the divalent selenide group （-Se-） in the SDSePS can be oxidized to a tetravalent selenium sulfoxide group （-Se=O）, and the spontaneous vesicles formed by SDSePS/DTAB are disintegrated into spherical micelles; and then under the action of Na₂SO₃, the tetravalent selenium sulfoxide group is reduced to a divalent selenide group, and the spontaneous vesicles formed by SDSePS/DTAB are regenerated; under the alternating action of H₂O₂ and Na₂SO₃, the spontaneous vesicles formed by SDSePS/DTAB can switch between the two states of micelles and vesicles over 10 times at least. The average radius of the regenerated vesicles formed by SDSePS/DTAB remained in the range of 115-130 nm.

Key words: sodium dodecylselanylpropyl sulfate, spontaneous vesicles, redox, reversible response

CLC Number:

TQ423

LI Ying,LIU Lian,LIU Xue-feng. Study on redox response behaviors of spontaneous vesicles formed by anionic/cationic surfactants[J].China Surfactant Detergent & Cosmetics, 2019, 49(11): 699-704.

Figures/Tables 7

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References 24

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Study on redox response behaviors of spontaneous vesicles formed by anionic/cationic surfactants

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