正/负离子双子表面活性剂复配体系的油/水界面性能研究

doi:10.13218/j.cnki.csdc.2015.12.008

Abstract

Abstract: The oil/water interfacial properties of binary blended systems of sulfonate Gemini surfactant (SGS-12) with single cationic surfactants (DTAC and CTAB),bis-quaternary ammonium salts (CD2N-12 and CD2N-16),and multiple quaternary ammonium salt (CD3N-12) were investigated.Results showed that the blended systems of SGS-12/DTAC,SGS-12/CTAB and SGS-12/CD2N-12 display synergism in oil/water interface tension reduction effectiveness.When the blending ratio of SGS-12 to DTAC is 3∶5,the interfacial tension between the aqueous system and crude oil can be decreased to 2.29×10^-3 mN/m as the minimum.The lowest interfacial tension of the blended system of SGS-12/CTAB can achieve 1.84×10^-3 mN/m at a 9∶5 blend ratio.When the blending ratio of SGS-12 to CD2N-12 is 6∶5,the interfacial tension can be reduced to 4.3×10^-3 mN/m as the minimum.However,the blended systems of SGS-12/CD2N-16 and SGS-12/CD3N-12 exhibit no obvious synergism.

Key words: Gemin surfactant, anionic/cationic surfactant, blended system, interfacial property

CLC Number:

TQ423

HOU Cong, WU Xiao-mei, LAI Lu, CHENG Li, MEI Ping. Studies on the oil/water interfacial properties of anionic/cationic blended Gemini surfactant systems[J].China Surfactant Detergent & Cosmetics, 2015, 45(12): 697-701.

References

[1] KOEHLER R D,RAGHAVANS R,KALERHH E W.Microstructure and dynamics of wormlike micellar solutions formed by mixing cationic and anionic surfactants[J].The Journal of Physical Chemistry B,2000,104(47):11035-11044.
[2] 姜蓉. 含Gemini成分的正/负离子表面活性剂复配体系中分子
间相互作用及协调效应研究:气/液界面吸附及溶液体相聚集[D].福州:福州大学,2006.
[3] ROSEN M J,ZHU Z H,GAO T.Synergism in binary mixture of surfactants:11.mixtures containing mono-and disulfonated alkyl-and dialkyldiphenylethers[J].Journal of Colloid and Interface Science,1993,157(1):254-259.
[4] LIU L,ROSEN M J.The interaction of some novel diquaternary gemini surfactants with anionic surfactants[J].Journal of Colloid and Interface Science,1996,179(2):454-459.
[5] 阮科,张翎,肖进新,等.正负离子混合表面活性剂双水相界面张力的研究[J].物理化学学报,2006,22(12):1451-1455.
[6] 黄绪龙,赵海娜,黄建滨,等.阴阳离子表面活性剂混合体系对原油的乳化及增粘行为[J].物理化学学报,2014,30(7):1297-1302.
[7] 赵海娜,程新皓,黄建滨,等.阴阳离子表面活性剂混合体系在克拉玛依油田中获得超低界面张力[J].物理化学学报,2014,30(4):693-698.
[8] ESUMI K,MIYAZAKI M,ARAI T,et al.Mixed micellar properties of a cationic gemini surfactant and a nonionic surfactant[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,1998,135(1):117-122.
[9] DANINO D,TALMON Y,ZANA R.Vesicle-to-micelle transformation in systems containing dimeric surfactants[J].Journal of Colloid and Interface Science,1997,185(1):84-93.
[10] BEMHEIM-GROSWASSER A,ZANA R,TALMONn Y.Sphere-to-cylinder transition in aqueous micellar solution of a dimeric (Gemini) surfactant[J].The Journal of Physical Chemistry B,2000,104(17):4005-4009.
[11] 梅平,侯聪,赖璐,等.新型磺酸盐型Gemini表面活性剂的合成及其与聚合物相互作用[J].化学通报,2013,76(11):1034-1039.
[12] 赖璐,汪小宇,梅平.季铵盐型Gemini表面活性剂的合成及性能研究[J].化学与生物工程,2014,31(3):18-20.
[13] 戈仁刚,赵琳,赖璐,等.三头基双链季铵盐Gemini表面活性剂合成研究[J].长江大学学报,2010,7(2):17-20.
[14] 韩霞,程新皓.阴阳离子表面活性剂体系超低油/水界面张力的应用[J].物理化学学报,2012,28(1),146-153.
[15] 肖进新,罗妙宣,吴树森.孪连表面活性剂[J].自然杂志,1997,19(6):335-338.
[16] 肖进新,罗妙宣,胡昌明,等.正、负离子碳氟-碳氢表面活性剂混合水溶液的表面活性[J].化学研究与应用,2006,3(12):304-306.
[17] ROSEN M J,TRACY D J.Gemini surfactants[J].Journal of Surfactants and Detergents,1998,4(1):547-554.

Studies on the oil/water interfacial properties of anionic/cationic blended Gemini surfactant systems

PDF (PC)

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 2

Metrics

Comments

Recommended 10

[1]	ZHANG Guo-rui,SONG Yong-ting,BAO Mu-tai,WANG Wei-dong,LI Xi-ming. Study of the performance of mixed whey protein-rhamnolipid bioemulsifier [J]. China Surfactant Detergent & Cosmetics, 2019, 49(12): 783-789.
[2]	LONG Yun-qian, HUANG Xiao-he, WANG Yong-zheng, WANG Yong, SONG Xing-xing, SONG Fu-quan. Interfacial properties of compounded system of alkali and bio-oil sulfonate synthesized from waste cooking oil [J]. China Surfactant Detergent & Cosmetics, 2018, 48(5): 266-271.